scholarly journals Recent Advances and Challenges of Nanomaterials-Based Hydrogen Sensors

Micromachines ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1429
Author(s):  
Bei Wang ◽  
Ling Sun ◽  
Martin Schneider-Ramelow ◽  
Klaus-Dieter Lang ◽  
Ha-Duong Ngo

Safety is a crucial issue in hydrogen energy applications due to the unique properties of hydrogen. Accordingly, a suitable hydrogen sensor for leakage detection must have at least high sensitivity and selectivity, rapid response/recovery, low power consumption and stable functionality, which requires further improvements on the available hydrogen sensors. In recent years, the mature development of nanomaterials engineering technologies, which facilitate the synthesis and modification of various materials, has opened up many possibilities for improving hydrogen sensing performance. Current research of hydrogen detection sensors based on both conservational and innovative materials are introduced in this review. This work mainly focuses on three material categories, i.e., transition metals, metal oxide semiconductors, and graphene and its derivatives. Different hydrogen sensing mechanisms, such as resistive, capacitive, optical and surface acoustic wave-based sensors, are also presented, and their sensing performances and influence based on different nanostructures and material combinations are compared and discussed, respectively. This review is concluded with a brief outlook and future development trends.

Sensors ◽  
2019 ◽  
Vol 19 (21) ◽  
pp. 4775 ◽  
Author(s):  
Gaopeng Wang ◽  
Shiwen Yang ◽  
Jixiang Dai ◽  
Yutang Dai ◽  
Tong Zou ◽  
...  

α-MoO3 has been used as a hydrogen sensing material due to its excellent properties and unique crystalline layer structure. However, the low repeatability of α-MoO3 based hydrogen sensor restricts its practical application. In this paper, the effect of intercalated ion species and the amount in α-MoO3 is experimentally investigated and discussed. It is concluded that the repeatability of the sensor depends on the radius of intercalated ions and amount of ionic bonds. The optimal ion species is Na+ and the optimal amount of precursor is 1 mmol.


2019 ◽  
Vol 803 ◽  
pp. 120-123
Author(s):  
Xiong Bang Wei ◽  
Guo Dong Lv ◽  
Xiao Hui Yang ◽  
Tao Wu ◽  
Dong Shi ◽  
...  

In this paper, a kind of novel TiO2 nanotube arrays (TNTs) hybrid structure was presented to improve the performance of hydrogen sensors. In this novel structure, palladium functionalized TNTs hybrid nanostructure supported on titanium wire. TNTs arrays was prepared by anodizing Ti wire using a standard electrochemical procedure. Pd nanomaterials were deposited on TNTs. Optimized experiments showed the hydrogen sensor supported on titanium wire showed a good response time of 8 s and high sensitivity of 94.8% at 1.9 vol% H2 at room temperature (25 °C). The research work revealed potential good hydrogen sensitivity of this kind of hybrid nanostructure.


2020 ◽  
Vol 90 (19-20) ◽  
pp. 2198-2211
Author(s):  
Sung-Ho Hwang ◽  
Young Kwang Kim ◽  
Soon Moon Jeong ◽  
Changsoon Choi ◽  
Ka Young Son ◽  
...  

A colorimetric hydrogen sensor has great potential for accurately detecting and monitoring the leakage of hydrogen gas on account of its fast color change in contact with hydrogen gas. However, for the practical application of the sensor, such as in gas detection systems in clothing, the flexibility and stability of the sensor need to be improved. Here, we present a novel method to fabricate a flexible colorimetric hydrogen sensor with the stable embedment of sensing material. To improve the flexibility and stability of the sensor, polyacrylonitrile nanofiber containing palladium oxide and zinc oxide hybrid nanoparticles was prepared by electrospinning. The flexible colorimetric hydrogen sensor can detect 1000 ppm hydrogen gas with excellent selectivity within 2 min. We also suggest film and yarn-type flexible colorimetric hydrogen sensors for industrial and wearable applications. A laminating process was used to prepare the film. In contrast, twisting and polydimethylsiloxane coating were used to prepare the yarn-type flexible colorimetric hydrogen sensor. Compared with a flexible colorimetric hydrogen-sensing nanofiber, the film and yarn show identical sensitivity for detecting a hydrogen leakage. These applications of hydrogen sensors could be a new insight into the design of a flexible sensor for detecting hydrogen leakage with the naked eye.


Nanoscale ◽  
2021 ◽  
Author(s):  
Zhengyou Zhu ◽  
Xiaxia Xing ◽  
Dongliang Feng ◽  
Zhenxu Li ◽  
Yingying Tian ◽  
...  

Hydrogen sensing simultaneously endowed with fast response, high sensitivity and selectivity are highly desired in detecting hydrogen leakages such as in those hydrogen-driven vehicles and space rockets. Here, hydrogen sensing...


Author(s):  
Peng Zhang ◽  
Satyajit Shukla ◽  
Larry Ludwig ◽  
Hyoung J. Cho ◽  
Sudipta Seal

Micro hydrogen sensor with interdigitated electrodes and indium doped nanopolycrystalline SnO2 particles was fabricated and tested. Giant sensitivity as high as 105 with good repeatability and recovery was observed. The sensor showed an excellant selectivity of hydrogen (H2) sensing over helium (He).


2014 ◽  
Vol 5 ◽  
pp. 1261-1267 ◽  
Author(s):  
Anh-Thu Thi Do ◽  
Hong Thai Giang ◽  
Thu Thi Do ◽  
Ngan Quang Pham ◽  
Giang Truong Ho

The effect of palladium doping of zinc oxide nanoparticles on the photoluminescence (PL) properties and hydrogen sensing characteristics of gas sensors is investigated. The PL intensity shows that the carrier dynamics coincides with the buildup of the Pd-related green emission. The comparison between the deep level emission and the gas sensing response characteristics allows us to suggest that the dissociation of hydrogen takes place at PdZn-vacancies ([Pd 2+(4d9)]). The design of this sensor allows for a continuous monitoring in the range of 0–100% LEL H2 concentration with high sensitivity and selectivity.


Author(s):  
Minu Mathew ◽  
Chandra Sekhar Rout

This review details the fundamentals, working principles and recent developments of Schottky junctions based on 2D materials to emphasize their improved gas sensing properties including low working temperature, high sensitivity, and selectivity.


2019 ◽  
Vol 11 (10) ◽  
pp. 1405-1409 ◽  
Author(s):  
Haoshuang Shen ◽  
Baoxia Liu ◽  
Daosheng Liu ◽  
Xu Zhu ◽  
Xiuhua Wei ◽  
...  

GMP ligand based LCP sensor for Cit with high sensitivity and selectivity was constructed.


2020 ◽  
Vol 12 (8) ◽  
pp. 1122-1130
Author(s):  
Yan Liu ◽  
Lu-Lu Peng ◽  
Wei-Xiong Huang ◽  
Hui-Zhuo Zhou ◽  
Li Xu

A luminescent nucleotide/Tb3+ coordination polymer (CP) was synthesized using adenosine triphosphate (ATP) molecules as a bridge ligand and Phen as a sensitizer, which showed high sensitivity and selectivity for Fe2+.


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