scholarly journals Surface Engineering of Carbon-Based Microelectrodes for High-Performance Microsupercapacitors

Micromachines ◽  
2019 ◽  
Vol 10 (5) ◽  
pp. 307 ◽  
Author(s):  
Liang He ◽  
Tianjiao Hong ◽  
Yue Huang ◽  
Biao Xiong ◽  
Xufeng Hong ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Surface Modification ◽  
Electrochemical Performance ◽  
High Performance ◽  
Surface Engineering ◽  
Electrically Conductive ◽  
Scan Rate ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Glycol Methyl Ether

In this research, the enhancement in electrochemical performance of pyrolyzed carbon microelectrodes by surface modification is investigated. For the proposed microfabrication process, pyrolyzed carbon microelectrodes with multi-walled carbon nanotubes (MWCNTs) on their surface are obtained by developing GM-1060 photoresist in mixture of propylene glycol methyl ether acetate (PGMEA) and CNTs, and following pyrolysis of a micropatterned photoresist. Polyvinyl alcohol (PVA)/H2SO4 electrolyte (1 M) was applied to assemble this carbon/CNT microelectrode-based all-solid-state microsupercapacitor (carbon/CNT-MSC). The carbon/CNT-MSC shows a higher electrochemical performance compared with that of pyrolyzed carbon microelectrode-based MSC (carbon-MSC). The specific areal and volumetric capacitances of carbon/CNT-MSC (4.80 mF/cm2 and 32.0 F/cm3) are higher than those of carbon-MSC (3.52 mF/cm2 and 23.4 F/cm3) at the scan rate of 10 mV/s. In addition, higher energy density and power density of carbon/CNT-MSC (2.85 mWh/cm3 and 1.98 W/cm3) than those of carbon-MSC (2.08 mWh/cm3 and 1.41 W/cm3) were also achieved. This facile surface modification and optimization are potentially promising, being highly compatible with modern microfabrication technologies and allowing integration of highly electrically conductive CNTs into pyrolyzed carbon to assemble MSCs with improved electrochemical performance. Moreover, this method can be potentially applied to other high-performance micro/nanostructures and microdevices/systems.

scholarly journals The effect of the surface modification of carbon nanotubes on their dispersion in the epoxy matrix

2011 ◽  
Vol 13 (2) ◽  
pp. 62-69 ◽  
Author(s):  
Maria Wladyka-Przybylak ◽  
Dorota Wesolek ◽  
Weronika Gieparda ◽  
Anna Boczkowska ◽  
Ewelina Ciecierska
Keyword(s):  
Carbon Nanotubes ◽  
Surface Modification ◽  
Epoxy Resin ◽  
Epoxy Matrix ◽  
Mechanical Mixing ◽  
Weight Percentage ◽  
Homogeneous Dispersion ◽  
Multi Walled Carbon Nanotubes ◽  
Mixing Method ◽  
Walled Carbon Nanotubes

The effect of the surface modification of carbon nanotubes on their dispersion in the epoxy matrix Functionalization of multi-walled carbon nanotubes (MWCNTs) has an effect on the dispersion of MWCNT in the epoxy matrix. Samples based on two kinds of epoxy resin and different weight percentage of MWCNTs (functionalized and non-functionalized) were prepared. Epoxy/carbon nanotubes composites were prepared by different mixing methods (ultrasounds and a combination of ultrasounds and mechanical mixing). CNTs modified with different functional groups were investigated. Surfactants were used to lower the surface tension of the liquid, which enabled easier spreading and reducing the interfacial tension. Solvents were also used to reduce the liquid viscosity. Some of them facilitate homogeneous dispersion of nanotubes in the resin. The properties of epoxy/nanotubes composites strongly depend on a uniform distribution of carbon nanotubes in the epoxy matrix. The type of epoxy resin, solvent, surfactant and mixing method for homogeneous dispersion of CNTs in the epoxy matrix was evaluated. The effect of CNTs functionalization type on their dispersion in the epoxy resins was evaluated on the basis of viscosity and microstructure studies.

Surface modification and application of multi-walled carbon nanotubes in fire-retardant coatings

Carbon ◽  
2010 ◽  
Vol 48 (5) ◽  
pp. 1694-1695 ◽  
Author(s):  
Jun Qiu ◽  
Shi-hong Zhang ◽  
Guo-jian Wang ◽  
Yi-lei Gong
Keyword(s):  
Carbon Nanotubes ◽  
Surface Modification ◽  
Fire Retardant ◽  
Multi Walled Carbon Nanotubes ◽  
In Fire ◽  
Walled Carbon Nanotubes

Surface modification of multi-walled carbon nanotubes by O2 plasma

2007 ◽  
Vol 253 (22) ◽  
pp. 8945-8951 ◽  
Author(s):  
Tao Xu ◽  
Jinghui Yang ◽  
Jiwei Liu ◽  
Qiang Fu
Keyword(s):  
Carbon Nanotubes ◽  
Surface Modification ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
O2 Plasma

Novel ionic bioartificial muscles based on ionically crosslinked multi-walled carbon nanotubes-mediated bacterial cellulose membranes and PEDOT:PSS electrodes

2021 ◽  
Author(s):  
Yaofeng Wang ◽  
Fan Wang ◽  
Yang Kong ◽  
Lei Wang ◽  
Qinchuan Li
Keyword(s):  
Carbon Nanotubes ◽  
Bacterial Cellulose ◽  
Specific Capacitance ◽  
High Performance ◽  
Low Cost ◽  
Actuation Voltage ◽  
Fast Response ◽  
Bending Deformation ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Abstract High-performance bioartificial muscles with low-cost, large bending deformation, low actuation voltage, and fast response time have drawn extensive attention as the development of human-friendly electronics in recent years. Here, we report a high-performance ionic bioartificial muscle based on the bacterial cellulose (BC)/ionic liquid (IL)/multi-walled carbon nanotubes (MWCNT) nanocomposite membrane and PEDOT:PSS electrode. The developed ionic actuator exhibits excellent electro-chemo-mechanical properties, which are ascribed to its high ionic conductivity, large specific capacitance, and ionically crosslinked structure resulting from the strong ionic interaction and physical crosslinking among BC, IL, and MWCNT. In particular, the proposed BC-IL-MWCNT (0.10 wt%) nanocomposite exhibited significant increments of Young's modulus up to 75% and specific capacitance up to 77%, leading to 2.5 times larger bending deformation than that of the BC-IL actuator. More interestingly, bioinspired applications containing artificial soft robotic finger and grapple robot were successfully demonstrated based on high-performance BC-IL-MWCNT actuator with excellent sensitivity and controllability. Thus, the newly proposed BC-IL-MWCNT bioartificial muscle will offer a viable pathway for developing next-generation artificial muscles, soft robotics, wearable electronic products, flexible tactile devices, and biomedical instruments.

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