scholarly journals Effect of C Addition on as-Cast Microstructures of High Nb Containing TiAl Alloys

Metals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1201 ◽  
Author(s):  
Liu ◽  
Zhang ◽  
Nan ◽  
Feng ◽  
Ding
Keyword(s):  
Lamellar Structure ◽  
Volume Fraction ◽  
Eutectic Structure ◽  
Carbon Addition ◽  
Tial Alloys ◽  
Β Phase ◽  
Graphite Mold ◽  
Mold Casting ◽  
The Matrix ◽  
High Level

Two high Nb-containing TiAl alloys, Ti46.6Al7.5Nb0.5Si0.2B (Alloy A) and Ti46.1Al7.4Nb5C0.5Si0.2B (Alloy B), were prepared by graphite mold casting. As-cast microstructures of the two alloys were characterized to clarify the effect of carbon addition. The results show that 5 at.% carbon addition can change the primary solidification phase from β phase to α phase. The as-cast microstructure of Alloy A consists of a fully α2 + γ lamellar structure and interdendritic eutectic silicide with a volume fraction of 2.3%. However, in Alloy B, the lamellar structure only forms in the dendritic stem and the massive γ is observed in the interdendritic regions. Two types of carbides, Ti2AlC and TiC, are produced in Alloy B. A large number of randomly distributed primary Ti2AlC particles with volume fraction of 14.9% are observed in both the dendritic and interdendritic regions. Irregularly shaped TiC remains inside of the large Ti2AlC particle, suggesting TiC carbides transformed to Ti2AlC during cooling. The addition of carbon also changes the morphology of the silicides from a eutectic structure to a blocky structure in the massive γ matrix or at the interface of the Ti2AlC and the γ matrix. High level of niobium greatly increases the solid solution limit of carbon, since C content in the matrix is much higher than the solid solubility of that in the TiAl binary system. The hardness of the matrix increases from 325 HV to 917 HV caused by the addition of carbon.

scholarly journals Phase Transition and Ordering Temperatures of TiAl-Mo Alloys Investigated by In Situ Diffraction Experiments

2010 ◽  
Vol 654-656 ◽  
pp. 456-459 ◽  
Author(s):  
Thomas Schmoelzer ◽  
Svea Mayer ◽  
Frank Haupt ◽  
Gerald A. Zickler ◽  
Christian Sailer ◽  
...  
Keyword(s):  
Ternary Phase ◽  
Elevated Temperatures ◽  
Volume Fraction ◽  
Ternary Phase Diagram ◽  
High Energy ◽  
The Body ◽  
Alloying Element ◽  
Tial Alloys ◽  
Β Phase

Intermetallic TiAl alloys with a significant volume fraction of the body-centered cubic β-phase at elevated temperatures have proven to exhibit good processing characteristics during hot-working. Being a strong β stabilizer, Mo has gained importance as an alloying element for so-called β/γ-TiAl alloys. Unfortunately, the effect of Mo on the appearing phases and their temperature dependence is not well known. In this work, two sections of the Ti-Al-Mo ternary phase diagram derived from experimental data are shown. These diagrams are compared with the results of in-situ high-temperature diffraction experiments using high-energy synchrotron radiation.

Microstructure Observation of AM60 Magnesium Alloy Solidified by Rapidly Quench

2011 ◽  
Vol 409 ◽  
pp. 339-342 ◽  
Author(s):  
Tatsuya Maekawa ◽  
Mitsuaki Furui ◽  
Susumu Ikeno ◽  
Tomoyasu Yamaguchi ◽  
Seiji Saikawa
Keyword(s):  
Cooling Rate ◽  
Volume Fraction ◽  
Solidus Temperature ◽  
Sand Mold ◽  
Slow Cooling ◽  
Microstructure Observation ◽  
Β Phase ◽  
Mold Casting ◽  
Contradictory Behavior ◽  
Permanent Mold Castings

In solidification theory, with a slow cooling rate such as sand mold casting, it is easy to segregate the solute aluminum near the grain boundary of primary α-Mg phase under the solidification in Mg-Al system alloys. Thus, volume fraction of none-equilibrium crystallized β-Mg17Al12 phase showed the higher value compared with metal mold casting with faster cooling rate. However, in our microstructure observation results, the volume fraction of β phase in permanent mold castings was larger than that of sand mold castings. In the present study, these contradictory behavior was investigated by observation of as-solidified microstructure obtained from rapid cooling castings at the just below the solidus temperature of 723, 773 and 823K.

Effect of Addition of Al & Ca and Heat Treatment on the Cast Mg-6Zn Alloy

2013 ◽  
Vol 765 ◽  
pp. 33-37 ◽  
Author(s):  
S.S. Joshi ◽  
M.S. Mohan ◽  
S. Seshan ◽  
S. Kumar ◽  
S. Suwas
Keyword(s):  
Heat Treatment ◽  
Grain Size ◽  
Grain Boundary ◽  
Tensile Properties ◽  
Volume Fraction ◽  
Corrosion Behaviour ◽  
Boundary Phase ◽  
Al Content ◽  
Β Phase ◽  
The Matrix

In the present investigation, the effect of addition of Al and small amounts of Ca as well as the effect of heat treatment has been investigated on microstructure, tensile properties and corrosion behaviour of Mg-6Zn alloy produced by squeeze casting. The Mg-6Zn-1Al (ZA61) alloy consisted of α-Mg grains and MgZn (β) phase at the grain boundaries with a much higher strength and ductility than pure Mg. The addition of 0.1 and 0.5 wt% Ca to the ZA61 alloy refined the grain size and increased the volume fraction of the grain boundary phase but did not change the nature of the phase. Consequently, strength increased without much reduction in ductility. The increase in Al content of the alloy to 4 wt% (ZA64) changed the grain boundary phase to Al5Mg11Zn4 (Φ) phase, increased its volume fraction and refined the grain size as compared to ZA61 alloy. Consequently, strength increased with a reduction in ductility. On heat treatment of ZA61+0.5Ca and ZA64 alloys, the volume fraction of grain boundary phases decreased, fine precipitates were obtained in the matrix and the grain size increased. Thus, higher strength with a lower ductility was obtained on heat treatment but the ductility of both the alloys was still higher than that of pure Mg. Thus, 130 MPa 0.2%PS, 225 MPa UTS and 4.9% elongation to fracture could be obtained for the squeeze cast ZA64 alloy in the T6 condition, which are very good tensile properties for a cast Mg alloy. Increase in Al content and heat treatment reduced the corrosion resistance and addition of Ca improved it. The highest corrosion rate was observed to be 0.85 mm/year for the ZA64 alloy in the T6 condition.

Microstructure Design for Enhancement of Room-temperature Ductility in Multi-component TiAl Alloys

MRS Advances ◽  
2019 ◽  
Vol 4 (25-26) ◽  
pp. 1523-1529 ◽  
Author(s):  
Ryosuke Yamagata ◽  
Yotaro Okada ◽  
Hideki Wakabayashi ◽  
Hirotoyo Nakashima ◽  
Masao Takeyama
Keyword(s):  
Room Temperature ◽  
Single Phase ◽  
Significant Contribution ◽  
Volume Fraction ◽  
Microstructure Design ◽  
Tial Alloys ◽  
Volume Fractions ◽  
Β Phase ◽  
Room Temperature Ductility

AbstractEffects of microstructure constituents of α2-Ti3Al/γ-TiAl lamellae, β-Ti grains and γ grains, with various volume fractions on room-temperature ductility of γ-TiAl based alloys have been studied. The ductility of the alloys containing β phase of about 20% in volume increases to more than 1% as the volume fraction of γ phase increases to 80%. However, γ single phase alloys show very limited ductility of less than 0.2%. The present results, thus, confirmed the significant contribution of β phase to enhancement of the room-temperature ductility in multi-component TiAl alloys.

High Temperature Oxidation Protection of Multi-Phase Mo-Containing TiAl-Alloys by the Fluorine Effect

2012 ◽  
Vol 1516 ◽  
pp. 95-100 ◽  
Author(s):  
Alexander Donchev ◽  
Raluca Pflumm ◽  
Svea Mayer ◽  
Helmut Clemens ◽  
Michael Schütze
Keyword(s):  
High Temperature ◽  
Oxidation Resistance ◽  
Titanium Aluminides ◽  
Elevated Temperatures ◽  
Volume Fraction ◽  
Temperature Oxidation ◽  
Tial Alloys ◽  
Β Phase ◽  
Multi Phase ◽  
The Impact

ABSTRACTIntermetallic titanium aluminides are potential materials for application in high temperature components. In particular, alloys solidifying via the β-phase are of great interest because they possess a significant volume fraction of the disordered body-centered cubic β-phase at elevated temperatures ensuring good processing characteristics during hot-working. Nevertheless, their practical use at temperatures as high as 800°C requires improvements of the oxidation resistance. This paper reports on the fluorine effect on a multi-phase TiAl-alloy in the cast and hot-isostatically pressed condition at 800°C in air. The behavior of the so-called TNM material (Ti-43.5Al-4Nb-1Mo-0.1B, in at %) was compared with that of two other TiAl-alloys which are Nb-free and contain different amounts of Mo (3 and 7 at%, respectively). The oxidation resistance of the fluorine treated samples was significantly improved compared to the untreated samples. After fluorine treatment all alloys exhibit slow alumina kinetics indicating a positive fluorine effect. Results of isothermal and thermocyclic oxidation tests at 800°C in air are presented and discussed in the view of composition and microstructure of the TiAl-alloys investigated, along with the impact of the fluorine effect on the oxidation resistance of these materials.

Effect of Heat Treatment on the Microstructure of Cu-Cr-Zr Alloy

2017 ◽  
Vol 727 ◽  
pp. 166-170 ◽  
Author(s):  
Li Jun Peng ◽  
Hao Feng Xie ◽  
Gao Lei Xu ◽  
Guo Jie Huang ◽  
Zhen Yang
Keyword(s):  
Electron Microscope ◽  
Transmission Electron Microscope ◽  
Volume Fraction ◽  
Homogenization Temperature ◽  
Eutectic Structure ◽  
Optical Microscope ◽  
Heat Treatments ◽  
Transmission Electron ◽  
The Matrix ◽  
Zr Alloy

Effect of Heat treatments on microstructure in a Cu-0.71Cr-0.12Zr alloy (in wt.%) have been investigated. The microstructures are analyzed by optical microscope, scanning electron microscope, transmission electron microscope and high-resolution transmission electron microscope after each step of heat treatments. The results show that the as-cast microstructure of Cu-Cr-Zr alloy is Cu matrix, Cr dendrite and eutectic structure which is composed of Cu and Cu5Zr phase with a fine lamellar structure. By increasing the homogenization temperature or prolonging the holding time, the eutectic structure is dissolved into the matrix gradually and the volume fraction of the Cr phases is obviously reduced. The precipitation of Cr phase prevents from Zr-rich phases dissolving in the matrix. And the proper homogenizing process is 900°C×12 h. When the alloy aged at 450°C for 24 h, the crystallography of Cr precipitates and the orientation relationship between Cr precipitates and Cu matrix is bcc structure and KS-OR, respectively. The disk-shaped precipitate is identified as Cu5Zr phase and their habit plane is parallel to {111}Cu plane.

scholarly journals The Difference of Lamellar Structure Formation between Ti-45Al-5.4V-3.6Nb-Y Alloy and Ti-44Al-4Nb-4V-0.3Mo-Y Alloy

Metals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 566
Author(s):  
Jianchao Han ◽  
Shuzhi Zhang ◽  
Changjiang Zhang ◽  
Fantao Kong ◽  
Yuyong Chen ◽  
...  
Keyword(s):  
Structure Formation ◽  
Phase Field ◽  
Lamellar Structure ◽  
Annealing Temperature ◽  
Volume Fraction ◽  
Common Factor ◽  
Β Phase ◽  
The Common ◽  
The Difference ◽  
Stabilizing Element

In this study, the effect factors on the formation of lamellar structure for Ti-45Al-5.4V-3.6Nb-Y alloy and Ti-44Al-4Nb-4V-0.3Mo-Y alloy is discussed in detail. During heat treatment in different procedures, temperature was the common factor influencing the formation of lamellar structures of Ti-45Al-5.4V-3.6Nb-Y and Ti-44Al-4Nb-4V-0.3Mo-Y alloys. In the range of 1230 °C and 1300 °C, the volume fraction of lamellar structure in Ti-45Al-5.4V-3.6Nb-Y alloy was proportional to the annealing temperature. However, between 1210 °C and 1260 °C, the volume fraction of lamellar structure in Ti-44Al-4Nb-4V-0.3Mo-Y alloy deceased when temperature was located in the α + γ + β triple phase field and then increased when temperature was in the α + β binary phase field. Besides the influence of temperature, the lamellar structure formation of Ti-44Al-4Nb-4V-0.3Mo-Y alloy was also affected by the β-phase stabilizing element.

Hot-die Forging of a β-stabilized γ-TiAl Based Alloy

2008 ◽  
Vol 1128 ◽  
Author(s):  
Wilfried Wallgram ◽  
Helmut Clemens ◽  
Sascha Kremmer ◽  
Andreas Otto ◽  
Volker Güther
Keyword(s):  
Mechanical Properties ◽  
Elevated Temperatures ◽  
Volume Fraction ◽  
Small Deformation ◽  
High Volume ◽  
Compression Tests ◽  
Tial Alloys ◽  
Β Phase ◽  
Heat Treated ◽  
Hot Die Forging

AbstractBecause of the small “deformation window” hot-working of γ-TiAl alloys is a complex and difficult task and, therefore, isothermal forming processes are favoured. In order to increase the deformation window a novel Nb and Mo containing γ-TiAl based alloy (TNM™ alloy) was developed. Due to a high volume fraction of β-phase at elevated temperatures the alloy can be hot-die forged under near conventional conditions, which means that conventional forging equipment with minor and inexpensive modifications can be used. With subsequent heattreatments balanced mechanical properties can be achieved. This paper summarizes our progress in establishing a “near conventional” forging route for the fabrication of γ-TiAl components. The results of lab scale compression tests and forging trials on an industrial scale are included. In addition, the mechanical properties of forged and heat-treated TNM™ material are presented.

scholarly journals Characterisation of Microstructure of We43 Magnesium Matrix Composites Reinforced with Carbon Fibres

2016 ◽  
Vol 61 (2) ◽  
pp. 1075-1081
Author(s):  
A. Gryc ◽  
T. Rzychoń
Keyword(s):  
Heat Treatment ◽  
Volume Fraction ◽  
Solution Treatment ◽  
Hot Water ◽  
Matrix Composites ◽  
Carbon Fibres ◽  
Magnesium Matrix Composites ◽  
T6 Heat Treatment ◽  
Β Phase ◽  
The Matrix

Abstract In the paper the microstructures of WE43 matrix composites reinforced with carbon fibres have been characterised. The influence of reinforcement type and T6 heat treatment (a solution treatment at 525°C for 8 h, a hot water quench and a subsequent ageing treatment at 250°C for 16 h) on microstructure have been evaluated. The light microscope and scanning electron microscope investigations have been carried out. No significant differences in samples reinforced with non-coated textiles have been reported. The substantial changes in sample reinforced with nickel-coated textile have been observed. The segregation of alloying elements to the matrix-reinforcement layer has been identified. The T6 heat treatment caused the appearance of disperse precipitates of β phase, but the process cannot be considered as satisfactory (irregular distribution, low volume fraction, relatively large size).

scholarly journals Phase Equilibria and Phase Transformations in Molybdenum-Containing TiAl Alloys

2011 ◽  
Vol 1295 ◽  
Author(s):  
Svea Mayer ◽  
Christian Sailer ◽  
Hirotoyo Nakashima ◽  
Thomas Schmoelzer ◽  
Thomas Lippmann ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Elevated Temperatures ◽  
Volume Fraction ◽  
Ternary Phase Diagram ◽  
Isothermal Heat Treatment ◽  
Transition Temperatures ◽  
Scanning Calorimetry ◽  
Tial Alloys ◽  
Β Phase ◽  
The Individual

ABSTRACTMolybdenum, being a strong β stabilizer, is an important alloying element in TiAl alloys, since a significant volume fraction of the disordered bcc β-phase at elevated temperatures improves the processing characteristics during hot-working. Unfortunately, the effect of Mo on the individual phases and their transition temperatures is not completely known but is necessary for designing engineering applications. In this paper, sections of the Ti-Al-Mo ternary phase diagram derived from thermodynamic calculations as well as experimental data are presented. Further, the phase transition temperatures given by the phase diagrams are compared with results from isothermal heat treatment studies, differential scanning calorimetry measurements and in-situ high-temperature diffraction experiments. Combining all of these results, a revised phase diagram is proposed.

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