scholarly journals On the Development Concept for a New 718-Type Superalloy with Improved Temperature Capability

Metals ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1130
Author(s):  
Joachim Rösler ◽  
Tatiana Hentrich ◽  
Bodo Gehrmann

The superalloy 718 stands out for its excellent manufacturability and strength at ambient temperature. However, its application temperature is limited to about 650 °C due to the instability of the γ’’ precipitates. Here, we provide an in-depth account of an alloy development concept, allowing for the design of superalloys with 718-type properties, yet with a significantly improved microstructural stability. The article begins with a detailed discussion on how the microstructural and chemical composition must be altered to achieve this objective. Then, model alloys were used to explore and validate the outlined strategy. Finally, it is shown how these considerations ultimately led to a new 718-type superalloy with far more improved microstructural stability— namely, VDM Alloy 780. The introduction of a large amount of Co as a substitute for Fe (and partially Ni) is the most important element of our alloy development concept in terms of chemical composition. The most important microstructural feature is the introduction of low solvus temperature, high misfit γ´-strengthening, replacing γ´´-hardening.

2009 ◽  
Vol 618-619 ◽  
pp. 601-605 ◽  
Author(s):  
L. Wang ◽  
Diran Apelian ◽  
M.M. Makhlouf

Selecting an aluminum die casting alloy for a particular application often poses a challenge to designers and engineers. It is often difficult and sometimes not possible to find an alloy that meets all the requirements of the application; and in other times the alloy can be found, but it has a wide specified compositional range, and thus it exhibits a large variation in properties. Therefore, there is always a need to optimize existing alloys or to develop new alloys so that they meet the requirements of a given application. In order to help with the alloy selection and alloy development processes, we developed an electronic database for aluminum die casting alloys – i-Select-Al. This software can help its user to quickly select an alloy for a specific application from a comprehensive list of commercial alloys. Alternatively, it can help its user with the design of a new alloy to meet the requirements of the application. This paper presents a study in optimizing A380 alloy with the help of i-Select-Al. A380 alloy is the most commonly used die casting alloy, but it has a wide compositional range and therefore a wide range of properties. In this study, we optimized the mechanical properties of A380 alloy by optimizing its chemical composition. The Quality Index was used to quantify the changes in the alloys’ properties in response to changes in chemical composition. Two alloys were designed: one has a composition within the A380 alloy specification, and the other has a composition slightly outside the A380 alloy specification. Both alloys showed significant improvements in room temperature tensile properties and a substantial increase in the Quality Index over a commercially available A380 alloy.


2021 ◽  
Vol 1161 ◽  
pp. 13-25
Author(s):  
Stephan Koß ◽  
Simon Ewald ◽  
Marie-Noemi Bold ◽  
Jan Hendrik Koch ◽  
Maximilian Voshage ◽  
...  

Additive Manufacturing (AM) processes are becoming more and more important for production of parts with increasing geometrical complexity and functionality. However, to draw on the full potential of AM technologies, alloys that exploit process inherent particularities such as extremely high cooling rates (ca. 106 K/s) have to be developed. One of most important AM-processes is Laser Powder Bed Fusion (LPBF), a batch-wise process. This complicates experimental alloy development and increases the use of powder resources since only one chemical composition can be tested within one test job and the process chamber has to be cleaned carefully in between. The process Extreme High-Speed Laser Material Deposition (EHLA) has been found to have similar cooling rates as LPBF, however it uses an in situ supply of powders which allows an easy switching between materials and has potential for rapid alloy development methods. Since the mechanical properties of materials primarily depend on chemical composition and microstructure, which in turn depends heavily on the cooling rates in the production process, the EHLA-process could be used as a means for an accelerated alloy development for LPBF. However, to explore this possibility, a thorough comparison of the two processes has to be performed.In this work, EHLA and LPBF processes are compared and evaluated regarding the following characteristics: process parameters, laser intensities and volume energy densities, resulting microstructure (primary dendrite arm spacing, DAS), melt pool size and shape. The reference samples were manufactured using one set of LPBF process parameters and EHLA samples were manufactured using three different sets of process parameters.The volume energy densities Ev [J/mm³] of the processes were found to differ by a factor 2.4 with higher Ev observed in LPBF. However, considering that approximately 2 to 3 layers are remelted with each pass of the laser beam, the introduced Ev per pass approximates the Ev introduced in the EHLA process. The melt pool size as seen in a cross section in the EHLA-manufactured samples is approximately 25 times larger than in the LPBF-manufactured samples and its depth to width ratio (d/w ratio) can be attributed to a heat conduction welding process while the d/w ratio observed in the LPBF-manufactured sample suggests a transition process between heat conduction welding and deep welding. The observed DAS is in the same order of magnitude for both processes ranging from 0.55 to 1.15 µm in EHLA-manufactured samples and 0.73 µm in the LPBF-manufactured reference sample. Since the resulting microstructures of samples manufactured with both processes show this common feature and EHLA process parameters can be adjusted to control the cooling rates, the transferability between EHLA- and LPBF-processes is supported in this first investigation. Research for a more efficient alloy development for LPBF using EHLA will be continued by e.g. examining chemical compositions and performing mechanical testing.


2012 ◽  
Vol 12 (3) ◽  
pp. 323-333 ◽  
Author(s):  
Marek Babicz ◽  
Ewa Skrzypczak ◽  
Barbara Rejduch ◽  
Anna Kozubska-Sobocińska ◽  
Anna Chmielowiec-Korzeniowska ◽  
...  

Effect of Thermal Stress on Reproductive Performance Parameters of Sows with Defined Genotype at the RYR1 locusThe objective of the present research was to determine the influence of ambient air temperature in the farrowing section of a pig facility on chemical composition, colostrum and milk somatic cell counts (SCC), and rearing efficiency of piglets from Polish Landrace (PL) sows with identified genotype at the RYR1 locus. Subjects were 60 PL sows in the second and third reproductive cycle. Polymorphism at the RYR1 locus was analysed using the PCR-RFLP method. The proportion of RYR1 C/C and RYR1 C/T genotypes in each group was 1:1. Three groups of experimental temperatures were established: I - 22°C, II - 25°C, III - 28°C. The present study demonstrated that sows kept in periodic high ambient temperature (25°C, 28°C) showed a relatively long period of farrowing, more aggressive behaviour and overlying. Variability was also found between the groups with respect to litter size and litter weight, chemical composition and SCC of colostrum and milk. The results indicate that elevated ambient temperature during the perinatal period may adversely affect the utility value of sows.


Author(s):  
S. R. Baruah ◽  
U. Kotoky

Assam lemon is one of the most important fruit of Assam and it is used for culinary purpose due to its fragrance and acidic content. Though Citrus fruits are non-climacteric in nature, depending on the temperature and storage duration, chemical composition of fruits may change. In this experiment different treatments viz T0: Control, T1: Chlorination (4%), T2: Chlorination (4%) + Polyethylene (300 gauge thickness), T3: Chlorination (4%) + perforated polythene (with pinholes), T4: Chlorination (4%) + individual shrink wrapping, T5: Chlorination (4%) + tray packaging used to study the storage life and post harvest quality of Assam Lemon fruits. The effect of these treatments on citric acid, respiration, fruit texture and colour were studied. Among all the treatments, individual shrink wrapping (T4) of Assam Lemon fruit stored at ambient temperature (30-320C and 80–85% RH) was found to be beneficial because it helped to extend the shelf life without deterioration in quality of fruit. Shrink wrap packaging retained the freshness, colour and firmness of the fruit up to 1 month without any decay


2016 ◽  
Vol 124 ◽  
pp. 77-84 ◽  
Author(s):  
Akihiro Fushimi ◽  
Yoshinori Kondo ◽  
Shinji Kobayashi ◽  
Yuji Fujitani ◽  
Katsumi Saitoh ◽  
...  

2009 ◽  
Vol 618-619 ◽  
pp. 127-134 ◽  
Author(s):  
Phill Doorbar ◽  
Mark Dixon ◽  
Amit Chatterjee

The aero-engine has provided the major drive for the development of new improved titanium alloys in recent years. This paper covers these developments from the workhorse alloy Titanium 6/4 and it’s higher temperature stable mates through to the more exotic intermetallic materials and on to their reinforcement with ceramics. The use of Ti6/4 alloy is now widespread throughout the aero space industry providing a good combination of strength at moderate temperatures (~300°C) a relatively low density and a wide range of processing options ranging from castings to forgings to powder HIP and diffusion bonding. Alloy development for the aero-engine essentially concentrated on either increasing the temperature capability and creep resistance or increasing the strength at intermediate temperatures. Alloys such as Ti 6242 and IMI 834 were aimed at compressor disc applications with operation up to around 600°C. Improvements resulted from compositional control and thermal processing to optimize the microstructure for creep and fatigue. High strength intermediate temperature capability (~500°C) alloys were also developed (Ti6246) where higher levels of molybdenum balance the alpha strengthening additions. The drive for lighter weight led to the development of titanium intermetallic systems. Alloys such as 45-2-2XD and Alloy 7 have been the subject of much research and manufacturing development over the last 20 years, demonstrating that they are capable of operating at temperatures well above those of conventional titanium. More recently, alloys with higher additions of Nb and Ta have shown improved mechanical properties and offer promise to extend the application of TiAl above 700°C. In parallel with intermetallic developments combining titanium alloys with the extreme high strength of ceramic fibres has proved irresistible and many ways to produce titanium composites have been developed. The majority of application development has focused on Ti6/4 alloy as the matrix although other matrix alloys have been investigated and tested in U.S. engine demonstrators. Recently a combination of Ti-22Al-26Nb disks reinforced with orthorhombic MMC ran for over 100 hours in an engine test. However, none of these niche composite systems has yet made the transition into large volume production and the fibre reinforced Ti6/4 system probably offers the greatest potential for implementation. The main barrier to the take up of both advanced intermetallics and titanium composites is the cost of raw materials and processing. The challenge still exists to produce net shape components and provide weight savings at an acceptable cost. This will be the key to future exploitation.


2007 ◽  
Vol 263 ◽  
pp. 195-200 ◽  
Author(s):  
Bronislav Zlámal ◽  
Rudolf Foret ◽  
Jiří Buršík ◽  
Milan Svoboda

The structural changes taking place in the dissimilar laboratory welds of 6CrMoV 8-3-2 (T25), being under development, and modified X12CrMoVNb 10-1 (P91) nitrided steels annealed at temperatures of 500 – 900 °C have been subject of study. Carbon and nitrogen redistribution measurement by the EPMA method was complemented with detailed structural analysis aimed at the phase profiles and chemical composition of coexisting carbides and carbonitrides in particular regions of the weld joint. Results of experimental work were compared with thermodynamic and kinetic modeling using the DICTRA software. A very good agreement between the modeling and the experiments was observed.


1970 ◽  
Vol 16 ◽  
pp. 125-127 ◽  
Author(s):  
MOH Helali ◽  
M Ibrahim ◽  
MZ Shafique ◽  
MM Rahman ◽  
SK Biswas ◽  
...  

Lemon cordial was prepared and its storage conditions were studied. The prepared cordial was kept in 250 ml sterilized glass bottles, sealed and stored at ambient temperature (22°- 37°C) for 360 days. The chemical composition, keeping quality and consumers acceptability of the product was analyzed at an interval of 15 days up to 120 days and then at an interval of 30 days upto360 days. Except vitamin C content, no noticeable change was observed during the storage. Key words: Lemon, Cordial, Citric acid, Ascorbic acid, Reducing sugar, Non-reducing sugar   DOI:10.3329/jbs.v16i0.3755 J. bio-sci. 16: 125-127, 2008


Author(s):  
Jacqueline B. Wahl ◽  
Ken Harris

Single crystal (SX) superalloys have wide application in the high pressure turbine section of aero and industrial gas turbine engines due to the unique combination of properties and performance. Since introduction of single crystal casting technology, SX alloy development has focused on increased temperature capability, and major improvements in alloy performance have been associated with the introduction of new alloying elements, including rhenium (Re) and ruthenium (Ru). 3% Re-containing second generation alloys, such as CMSX-4®, PWA 1484 and Rene’ N5 have seen the greatest market utilization and have become the benchmark alloys for comparing new alloy developments. However, Re and Ru are rare elements with limited production/availability and corresponding high costs. This has resulted in significant escalation of SX alloy costs, and consequently, there has been much interest in the development of improved SX superalloys with lower Re or no Re content compared to second generation alloys. Cannon-Muskegon® has developed two new SX superalloys: 1.5% Re CMSX®−8 alloy and CMSX®−7 alloy, which contains no Re, as alternatives to first and second generation alloys for applications which require slightly less ultra high temperature capability compared to CMSX-4 alloy or the improved CMSX-4(SLS) alloy. This paper provides an overview of development and characterization of these SX alloys and alloy modifications, CMSX-8 (SLS) and CMSX-8[B/C](SLS).


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