scholarly journals Extraction of Palladium(II) from Hydrochloric Acid Solutions by Solvent Extraction with Mixtures Containing Either Cyanex 301 or LIX 63

Metals ◽  
2017 ◽  
Vol 7 (12) ◽  
pp. 541 ◽  
Author(s):  
Hoai Truong ◽  
Man Lee ◽  
Seong Son
Author(s):  
Hoai Thanh Truong ◽  
Man Seung Lee ◽  
Seong Ho Son

Cyanex 301 and LIX 63 can seletively extract Pd(II) over Pt(IV) from strong hydrochloric acid solutions. Therefore, solvent extraction experiments have been performed by extractant mixtures containing either Cyanex 301 or LIX 63 and the extraction behavior of Pd(II) was compared. Among the mixture of Cyanex 301, the highest synergistic enhancement coefficient was achieved by mixing Cyanex 301 and TOPO. However, it was very diffiuclt to strip the Pd(II) from the loaded mixture. Among the mixture of LIX 63, the mixture of LIX 63 and Alamine 336/TOPO enhanced the extraction of Pt(II). Although the synergistic coefficient by Cyanex 301 + TOPO was higher than that by LIX 63 + Alamine 336, the Pd(II) in the loaded mixture of LIX 63 and Alamine 336 was easily stripped by thiourea.


1986 ◽  
Vol 17 (1) ◽  
pp. 1-13 ◽  
Author(s):  
Chih-Chien Chang ◽  
Tai-Ming Chiu ◽  
Ying-Chu Hoh ◽  
Wei-Ko Wang

2007 ◽  
Vol 95 (5) ◽  
Author(s):  
K. Janardhan Reddy ◽  
A. Varada Reddy ◽  
B. S. Shaibu ◽  
M. L. P. Reddy

Various 3-phenyl-4-aroyl-5-isoxazolones, namely, 3-phenyl-4-benzoyl-5-isoxazolone (HPBI), 3-phenyl-4-(4-fluorobenzoyl)-5-isoxazolone (HFBPI) and 3-phenyl-4-(4-toluoyl)-5-isoxazolone (HTPI) were synthesized and examined with regard to the solvent extraction behavior of Zr(IV) and Hf(IV) from hydrochloric acid solutions. The results demonstrated that Zr(IV) and Hf(IV) extracted into chloroform with 3-phenyl-4-aroyl-5-isoxazolones (HA), as ZrOA


2013 ◽  
Vol 774-776 ◽  
pp. 1342-1345 ◽  
Author(s):  
Shao Ping Feng ◽  
Zhao Long Huang ◽  
Wei Liu ◽  
Zi Jing Li ◽  
Yan Jiang ◽  
...  

In this study, the solvent extraction of Pd(II) from hydrochloric acid solutions was investigated using the new synthesized material, 2-ethylhexyl benzothiazolyl sulfide (EHBTS) which was dissolved in xylene. Pd(II) was strongly extracted by 7% EHBTS in a lower concentration hydrochloric acid solution. Extraction parameters of Pd(II), including EHBTS concentration in different diluents, contact time of aqueous and organic phases, organic/aqueous (O/A) phase ratio and HCl concentration of aqueous phase, were studied. Quantitative extraction of Pd(II) occurred at 0.1 mol.L-1 of HCl concentration, 7% of EHBTS concentration, 1.0 of O/A, 40 min of contact time. In addition,the percentage stripping of Pd(II) could be more than 98% when thiourea concentration was 0.8 mol.L-1. EHBTS can be used more than 8 as extractant to extract of Pd(II) from hydrochloric acid solutions.


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