scholarly journals Effects of Iron Oxidation State and Chromium Distribution on the Corrosion Resistance of High Interstitial Stainless Steel for Down-Hole Application

Metals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1302
Author(s):  
Hyunju Lee ◽  
Cheolmin Ahn ◽  
Walid Khalfaoui ◽  
Brajendra Mishra ◽  
Ilguk Jo ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Iron Sulfide ◽  
Cast Steel ◽  
Iron Oxidation ◽  
Corrosion Properties ◽  
Iron Oxidation State ◽  
Solution Treated ◽  
Cast Steels ◽  
Cast Alloys ◽  
Fast Cooling

The corrosion properties of Fe-Cr-Mn-C-N high interstitial austenitic stainless cast steels were investigated for down-hole application in sour environments. The two cast alloys contained 0.66% and 0.71% of total nitrogen and carbon. The corrosion properties of the alloys that were solution-treated and fast-cooled were directly responsible for high corrosion resistance in NaCl solution, including resistance to pitting corrosion resulting from a better distribution of chromium chemical compound in the high interstitial stainless cast steel. However, the sour corrosion resistance of the alloys decreased with the fast cooling rate, which can be attributed to the increased amount of ferrite containing Fe2+, which causes iron sulfide precipitate formation in H2S.

Research on Mechanical and Corrosion Properties of Ti-Microalloyed Biomedical Cobalt-Based Alloy

2016 ◽  
Vol 852 ◽  
pp. 1168-1174
Author(s):  
Ya Ting Cao ◽  
Feng Wang ◽  
Qing Xuan Ran ◽  
Yu Lai Xu ◽  
Jun Li ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Corrosion Resistance ◽  
Phase Transformation ◽  
Aging Treatment ◽  
Physiological Saline ◽  
Corrosion Properties ◽  
Solution Treated ◽  
Cast Specimen ◽  
Mechanical And Corrosion Properties ◽  
Stable Passive

0.15 wt. % Ti-microalloyed Co-28.5Cr-5.9Mo-0.27C alloy has been developed by examining the effect of solution and aging treatment on microstructure, mechanical and corrosion properties. The results showed that elongation of the cast specimen were lower than 8%, while reached 18% after solution-treated at 1220 °C for 4 h. Phase transformation from austenite to martensite was observed after aging at 800°C and the amount of transformed martensite increased with aging time. Polarization tests of the samples after solution and aging treatment were carried out in physiological saline at 37 °C, which showed a stable passive film formed on the surface and no apparent pitting phenomenon occurred on the specimens, which indicated that heat treatment has not significant influence on the corrosion resistance of Co-Cr-Mo-0.27C-0.15Ti alloy.

NICROFER 7216 H

Alloy Digest ◽  
1997 ◽  
Vol 46 (1) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Stress Corrosion Cracking ◽  
Iron Alloy ◽  
Heat Treating ◽  
Good Resistance ◽  
Nickel Chromium ◽  
Solution Treated ◽  
Resistance To Oxidation ◽  
Resistance To Stress

Abstract Nicrofer 7216 H is a solution-treated nickel-chromium-iron alloy with good resistance to oxidation, carburization, and nitriding; good resistance to stress-corrosion cracking; and good resistance to dry chlorine and hydrogen chloride. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-520. Producer or source: VDM Technologies Corporation.

BOFORS 2RM2

Alloy Digest ◽  
1965 ◽  
Vol 14 (5) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
Low Temperature ◽  
Mechanical Strength ◽  
Physical Properties ◽  
Tensile Properties ◽  
Cast Steel ◽  
Heat Treating ◽  
High Mechanical Strength ◽  
Temperature Performance

Abstract BOFORS 2RM2 is a hardenable stainless cast steel having good weldability, high mechanical strength and improved corrosion resistance. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on low temperature performance and corrosion resistance as well as casting, forming, heat treating, machining, and joining. Filing Code: SS-169. Producer or source: Aktiebolaget Bofors.

ALLOY STEEL 1.8 Cu-1.0 Mn-1.2 Si

Alloy Digest ◽  
1976 ◽  
Vol 25 (10) ◽  
Keyword(s):  
Tensile Strength ◽  
Corrosion Resistance ◽  
Yield Strength ◽  
Physical Properties ◽  
Tensile Properties ◽  
Alloy Steel ◽  
Cast Steel ◽  
Heat Treating ◽  
Low Carbon ◽  
Steel Mills

Abstract Alloy Steel 1.8 Cu-1.0 Mn-1.2 Si is a low-carbon (0.20% max.) cast steel designed to provide intermediate tensile and yield strength. Copper lowers the ductility and toughness of cast steel but, for a given increase in tensile strength, the loss of ductility and toughness is less if copper is added than if carbon is increased. This steel has many uses such as booms, long shafting and gears. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on corrosion resistance as well as casting, heat treating, machining, and joining. Filing Code: SA-325. Producer or source: Alloy steel mills and foundries.

scholarly journals Electrodeposition of Copper and Brass Coatings with Olive-Like Structure

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1762
Author(s):  
Artur Maciej ◽  
Natalia Łatanik ◽  
Maciej Sowa ◽  
Izabela Matuła ◽  
Wojciech Simka
Keyword(s):  
Corrosion Resistance ◽  
Cathodic Current Density ◽  
Bath Composition ◽  
Cathodic Current ◽  
Corrosion Properties ◽  
Fine Grained ◽  
Electrodeposited Coating ◽  
Copper Zinc ◽  
New Generation ◽  
First Time

One method of creating a brass coating is through electrodeposition, which is most often completed in cyanide galvanic baths. Due to their toxicity, many investigations focused on the development of more environmentally friendly alternatives. The purpose of the study was to explore a new generation of non-aqueous cyanide-free baths based on 1-ethyl-3-methylimidazolium acetate ionic liquids. The study involved the formation of copper, zinc, and brass coatings. The influence of the bath composition, cathodic current density, and temperature was determined. The obtained coatings were characterized in terms of their morphology, chemical composition, phase composition, roughness, and corrosion resistance. It was found that the structure of the obtained coatings is strongly dependent on the process parameters. The three main structure types observed were as follows: fine-grained, porous, and olive-like. To the best knowledge of the authors, it is the first time the olive-like structure was observed in the case of an electrodeposited coating. The Cu-Zn coatings consisted of 19–96 at. % copper and exhibited relatively good corrosion resistance. A significant improvement of corrosion properties was found in the case of copper and brass coatings with the olive-like structure.

scholarly journals Influence of Rust Inhibitor on the Corrosion Resistance of Reinforcement in Cement Paste with Chloride

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 606
Author(s):  
Linchun Zhang ◽  
Ailian Zhang ◽  
Ke Li ◽  
Qian Wang ◽  
Junzhe Liu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Cement Paste ◽  
Photoelectron Spectroscopy ◽  
Electrical Resistance ◽  
Corrosion Properties ◽  
Passivation Film ◽  
Steel Bars ◽  
Assembly Unit ◽  
Chloride Environment ◽  
Rust Inhibitor

The electrical resistance and polarization effect of cement paste containing reinforcement were tested to research the anti-corrosion properties of steel bars in cement paste. Moreover, the microstructure and composition of passivation film and rust on the steel bars were studied. The water–cement ratio of the cement paste in this study was 0.3, with 0.5% NaCl, 1% NaNO2, and 1% Benzotriazole, and an assembly unit of 0.5% NaNO2 + 0.5% Benzotriazole by mass of cement was added to the cement to provide a chloride environment. X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM) were applied to research the composition of the passivation film and the microstructure of the cement paste, respectively. The results indicated that the samples with the assembly unit of 0.5% NaNO2 + 0.5% Benzotriazole showed the highest electrical resistance and polarization electrical resistance, while the specimens with 1.0% Benzotriazole showed the lowest electrical resistance and polarization electrical resistance. Moreover, the passivation film of steel bars weakened with increasing distance from the surface of the steel bars. Therefore, the corrosion of steel bars becomes more serious with increasing distance. Finally, the influence of the rust inhibitor on the corrosion resistance of steel bars in the specimens decreased in the following order: 0.5% NaNO2 + 0.5% Benzotriazole >1.0% NaNO2>1.0% Benzotriazole.

scholarly journals Development of Al–Mg–Si alloy performance by addition of grain refiner Al–5Ti–1B alloy

2021 ◽  
Vol 104 (2) ◽  
pp. 003685042110294
Author(s):  
Khaled Abd El-Aziz ◽  
Emad M Ahmed ◽  
Abdulaziz H Alghtani ◽  
Bassem F Felemban ◽  
Hafiz T Ali ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Corrosion Resistance ◽  
Testing Machine ◽  
Dendritic Structure ◽  
Grain Refiner ◽  
Corrosion Properties ◽  
Average Grain Size ◽  
Structural Applications ◽  
Alloy Addition

Aluminum alloys are the most essential part of all shaped castings manufactured, mainly in the automotive, food industry, and structural applications. There is little consensus as to the precise relationship between grain size after grain refinement and corrosion resistance; conflicting conclusions have been published showing that reduced grain size can decrease or increase corrosion resistance. The effect of Al–5Ti–1B grain refiner (GR alloy) with different percentages on the mechanical properties and corrosion behavior of Aluminum-magnesium-silicon alloy (Al–Mg–Si) was studied. The average grain size is determined according to the E112ASTM standard. The compressive test specimens were made as per ASTM: E8/E8M-16 standard to get their compressive properties. The bulk hardness using Vickers hardness testing machine at a load of 50 g. Electrochemical corrosion tests were carried out in 3.5 % NaCl solution using Autolab Potentiostat/Galvanostat (PGSTAT 30).The grain size of the Al–Mg–Si alloy was reduced from 82 to 46 µm by the addition of GR alloy. The morphology of α-Al dendrites changes from coarse dendritic structure to fine equiaxed grains due to the addition of GR alloy and segregation of Ti, which controls the growth of primary α-Al. In addition, the mechanical properties of the Al–Mg–Si alloy were improved by GR alloy addition. GR alloy addition to Al–Mg–Si alloy produced fine-grained structure and better hardness and compressive strength. The addition of GR alloy did not reveal any marked improvements in the corrosion properties of Al–Mg–Si alloy.

The Corrosion Resistance of Hard Anodised EN AW 7075 T6 Alloy

2021 ◽  
Vol 105 (1) ◽  
pp. 329-337
Author(s):  
David Kusmič ◽  
Lenka Klakurková ◽  
Martin Julis ◽  
Pavel Gejdoš ◽  
Jindrich Vilis ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Bulk Material ◽  
Surface Hardness ◽  
Hot Water ◽  
Initial Surface ◽  
Corrosion Properties ◽  
Resistance Surface ◽  
Hard Anodizing ◽  
Deaerated Solution ◽  
7075 Alloy

In this paper, commercially cold-rolled and artificial aged EN AW 7075 T6 alloy has been used. To ensure increased corrosion resistance, surface hardness, scratching resistance, and aesthetic features, this aluminium alloy was subsequently hard anodised and hot-water sealed (AC-A). The hard anodizing and sealing process increased surface hardness up to 304±13 HV 1 from an initial surface hardness of 194±3 HV 1. Also, the microhardness of the anodised layer and bulk material has been documented. Scanning electron microscopy (SEM) was used for microstructure and trapped precipitates investigation in the 42.9±1.4 thick formed anodised layer investigation. The T6 treated (AC) and hard anodised together with sealed (AC-A) EN AW 7075 alloy corrosion properties were evaluated using the anodic potentiodynamic polarisation tests (PPT) in a neutral 2.5% NaCl deaerated solution. The corrosion rate CR (mm/y) decreased approx. 39-times for the hard anodised and sealed EN AW 7075 alloy (AC-A), associated with the shift of the Ecorr (mV) to more positive values, degreased Icorr (µA) and increased Rp (Ohm) values compared to the artificial aged (AC) alloy. Additionally, the pitting was evaluated using laser confocal microscopy, and the pitting coefficient was also calculated.

Corrosion behavior of new type Co-based superalloys with different Ni contents

2017 ◽  
Vol 35 (6) ◽  
pp. 455-462 ◽  
Author(s):  
Bo Gao ◽  
Lei Wang ◽  
Yang Liu ◽  
Xiu Song ◽  
Shu-Yu Yang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Hot Corrosion ◽  
Corrosion Layer ◽  
Corrosion Process ◽  
Corrosion Properties ◽  
Oxidation Processes ◽  
Ni Content ◽  
Ni Addition ◽  
New Type

AbstractThe corrosion properties of γ′-strengthened Co-xNi-Al-W-Cr (where x=15, 20, 25, and 30 at.%) superalloys were investigated in the mixture of 75 wt.% Na2SO4+25 wt.% NaCl at 900°C. The results showed that the corrosion behavior is associated with both sulfuration and oxidation processes. It was demonstrated that increasing the addition of Ni effectively promoted the formation of continuous Al2O3 scales, so that the hot corrosion resistance could be improved. When Ni content is more than 20 at.%, a large amount of Ni3S2 precipitates during the corrosion process. Sulfuration can destroy the integrity of the corrosion layer and increase the activity of oxygen. In this way, the internal oxidation of the alloys becomes more serious. Therefore, it is recommended that the optimum Ni addition is about 20 at.% for new type Co-Ni-Al-W-Cr superalloys.

scholarly journals Effect of Plasma Nitriding Process Conditions on Corrosion Resistance of 440B Martensitic Stainless Steel

2014 ◽  
Vol 8 (3) ◽  
pp. 156-159 ◽  
Author(s):  
Magdalena Łępicka ◽  
Małgorzata Grądzka-Dahlke
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Degradation Products ◽  
Plasma Nitriding ◽  
Electrochemical Corrosion ◽  
Industrial Applications ◽  
Process Conditions ◽  
Corrosion Properties ◽  
Dental Instruments ◽  
Increased Risk

Abstract Martensitic stainless steels are used in a large number of various industrial applications, e.g. molds for plastic injections and glass moldings, automotive components, cutting tools, surgical and dental instruments. The improvement of their tribological and corrosion properties is a problem of high interest especially in medical applications, where patient safety becomes a priority. The paper covers findings from plasma nitrided AISI 440B (PN-EN or DIN X90CrMoV18) stainless steel corrosion resistance studies. Conventionally heat treated and plasma nitrided in N2:H2 reaction gas mixture (50:50, 65:35 and 80:20, respectively) in two different temperature ranges (380 or 450°C) specimens groups were examined. Microscopic observations and electrochemical corrosion tests were performed using a variety of analytical techniques. As obtained findings show, plasma nitriding of AISI 440B stainless steel, regardless of the process temperature, results in reduction of corrosion current density. Nevertheless, applying thermo-chemical process which requires exceeding temperature of about 400°C is not recommended due to increased risk of steel sensitization to intergranular and stress corrosion. According to the results, material ion nitrided in 450°C underwent leaching corrosion processes, which led to significant disproportion in chemical composition of the corroded and corrosion-free areas. The authors suggest further research into corrosion process of plasma nitrided materials and its degradation products.

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