scholarly journals Hydrogen Ironmaking: How It Works

Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 922 ◽  
Author(s):  
Fabrice Patisson ◽  
Olivier Mirgaux

A new route for making steel from iron ore based on the use of hydrogen to reduce iron oxides is presented, detailed and analyzed. The main advantage of this steelmaking route is the dramatic reduction (90% off) in CO2 emissions compared to those of the current standard blast-furnace route. The first process of the route is the production of hydrogen by water electrolysis using CO2-lean electricity. The challenge is to achieve massive production of H2 in acceptable economic conditions. The second process is the direct reduction of iron ore in a shaft furnace operated with hydrogen only. The third process is the melting of the carbon-free direct reduced iron in an electric arc furnace to produce steel. From mathematical modeling of the direct reduction furnace, we show that complete metallization can be achieved in a reactor smaller than the current shaft furnaces that use syngas made from natural gas. The reduction processes at the scale of the ore pellets are described and modeled using a specific structural kinetic pellet model. Finally, the differences between the reduction by hydrogen and by carbon monoxide are discussed, from the grain scale to the reactor scale. Regarding the kinetics, reduction with hydrogen is definitely faster. Several research and development and innovation projects have very recently been launched that should confirm the viability and performance of this breakthrough and environmentally friendly ironmaking process.

Energies ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 758 ◽  
Author(s):  
Abhinav Bhaskar ◽  
Mohsen Assadi ◽  
Homam Nikpey Somehsaraei

Production of iron and steel releases seven percent of the global greenhouse gas (GHG) emissions. Incremental changes in present primary steel production technologies would not be sufficient to meet the emission reduction targets. Replacing coke, used in the blast furnaces as a reducing agent, with hydrogen produced from water electrolysis has the potential to reduce emissions from iron and steel production substantially. Mass and energy flow model based on an open-source software (Python) has been developed in this work to explore the feasibility of using hydrogen direct reduction of iron ore (HDRI) coupled with electric arc furnace (EAF) for carbon-free steel production. Modeling results show that HDRI-EAF technology could reduce specific emissions from steel production in the EU by more than 35 % , at present grid emission levels (295 kgCO2/MWh). The energy consumption for 1 ton of liquid steel (tls) production through the HDRI-EAF route was found to be 3.72 MWh, which is slightly more than the 3.48 MWh required for steel production through the blast furnace (BF) basic oxygen furnace route (BOF). Pellet making and steel finishing processes have not been considered. Sensitivity analysis revealed that electrolyzer efficiency is the most important factor affecting the system energy consumption, while the grid emission factor is strongly correlated with the overall system emissions.


2012 ◽  
Vol 19 (8) ◽  
pp. 2291-2296 ◽  
Author(s):  
Ling-yun Yi ◽  
Zhu-cheng Huang ◽  
Hu Peng ◽  
Tao Jiang

Author(s):  
Hamzeh Hamadeh ◽  
Olivier Mirgaux ◽  
Fabrice Patisson

This paper addresses the modeling of the iron ore direct reduction process in the context of the reduction in CO2 emissions from the steel industry. The shaft furnace is divided into three sections (reduction, transition, and cooling), and the model is two-dimensional (cylindrical geometry for the upper sections and conical geometry for the lower one) to correctly describe the lateral gas feed and the cooling gas outlet. This model relies on a detailed description of the main physical-chemical and thermal phenomena using a multi-scale approach. The moving bed is assumed to be comprised of pellets of grains and crystallites. Eight heterogeneous and two homogeneous chemical reactions are taken into account. The local mass, energy and momentum balances are numerically solved using the finite volume method. This model was successfully validated by simulating the shaft furnaces of two direct reduction plants of different capacities. The calculated results reveal the detailed interior behavior of the shaft furnace operation. Eight different zones can be distinguished according to their predominant thermal and reaction characteristics. An important finding is the presence of a central zone of lesser temperature and conversion.


Author(s):  
Hamzeh Hamadeh ◽  
Olivier Mirgaux ◽  
Fabrice Patisson

This paper addresses the modeling of the iron ore direct reduction process, a process likely to reduce CO2 emissions from the steel industry. The shaft furnace is divided into three sections (reduction, transition, and cooling), and the model is two-dimensional (cylindrical geometry for the upper sections and conical geometry for the lower one), to correctly describe the lateral gas feed and cooling gas outlet. This model relies on a detailed description of the main physical–chemical and thermal phenomena, using a multi-scale approach. The moving bed is assumed to be comprised of pellets of grains and crystallites. We also take into account eight heterogeneous and two homogeneous chemical reactions. The local mass, energy, and momentum balances are numerically solved, using the finite volume method. This model was successfully validated by simulating the shaft furnaces of two direct reduction plants of different capacities. The calculated results reveal the detailed interior behavior of the shaft furnace operation. Eight different zones can be distinguished, according to their predominant thermal and reaction characteristics. An important finding is the presence of a central zone of lesser temperature and conversion.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1865 ◽  
Author(s):  
Hamzeh Hamadeh ◽  
Olivier Mirgaux ◽  
Fabrice Patisson

This paper addresses the modeling of the iron ore direct reduction process, a process likely to reduce CO2 emissions from the steel industry. The shaft furnace is divided into three sections (reduction, transition, and cooling), and the model is two-dimensional (cylindrical geometry for the upper sections and conical geometry for the lower one), to correctly describe the lateral gas feed and cooling gas outlet. This model relies on a detailed description of the main physical–chemical and thermal phenomena, using a multi-scale approach. The moving bed is assumed to be comprised of pellets of grains and crystallites. We also take into account eight heterogeneous and two homogeneous chemical reactions. The local mass, energy, and momentum balances are numerically solved, using the finite volume method. This model was successfully validated by simulating the shaft furnaces of two direct reduction plants of different capacities. The calculated results reveal the detailed interior behavior of the shaft furnace operation. Eight different zones can be distinguished, according to their predominant thermal and reaction characteristics. An important finding is the presence of a central zone of lesser temperature and conversion.


2018 ◽  
Vol 42 (3) ◽  
pp. 453-466
Author(s):  
Wei WANG ◽  
Pengfei YE ◽  
Xiaoli ZHOU ◽  
C WANG ◽  
Zekun HUO ◽  
...  

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