scholarly journals Removal of Dyes Using Graphene Oxide (GO) Mixed Matrix Membranes

Membranes ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 366
Author(s):  
Rana J. Kadhim ◽  
Faris H. Al-Ani ◽  
Muayad Al-shaeli ◽  
Qusay F. Alsalhy ◽  
Alberto Figoli

The application of membrane technology to remove pollutant dyes in industrial wastewater is a significant development today. The modification of membranes to improve their properties has been shown to improve the permeation flux and removal efficiency of the membrane. Therefore, in this work, graphene oxide nanoparticles (GO-NPs) were used to modify the polyethersulfone (PES) membrane and prepare mixed matrix membranes (MMMs). This research is dedicated to using two types of very toxic dyes (Acid Black and Rose Bengal) to study the effect of GO on PES performance. The performance and antifouling properties of the new modified membrane were studied using the following: FTIR, SEM, AFM, water permeation flux, dye removal and fouling, and by investigating the influence of GO-NPs on the structure. After adding 0.5 wt% of GO, the contact angle was the lowest (39.21°) and the permeable flux of the membrane was the highest. The performance of the ultrafiltration (UF) membrane displayed a rejection rate higher than 99% for both dyes. The membranes showed the highest antifouling property at a GO concentration of 0.5 wt%. The long-term operation of the membrane fabricated from 0.5 wt% GO using two dyes improved greatly over 26 d from 14 d for the control membrane, therefore higher flux can be preserved.

2020 ◽  
Author(s):  
Muayad Al-shaeli ◽  
Stefan J. D. Smith ◽  
Shanxue Jiang ◽  
Huanting Wang ◽  
Kaisong Zhang ◽  
...  

<p>In this study, novel <a>mixed matrix polyethersulfone (PES) membranes</a> were synthesized by using two different kinds of metal organic frameworks (MOFs), namely UiO-66 and UiO-66-NH<sub>2</sub>. The composite membranes were characterised by SEM, EDX, FTIR, PXRD, water contact angle, porosity, pore size, etc. Membrane performance was investigated by water permeation flux, flux recovery ratio, fouling resistance and anti-fouling performance. The stability test was also conducted for the prepared mixed matrix membranes. A higher reduction in the water contact angle was observed after adding both MOFs to the PES and sulfonated PES membranes compared to pristine PES membranes. An enhancement in membrane performance was observed by embedding the MOF into PES membrane matrix, which may be attributed to the super-hydrophilic porous structure of UiO-66-NH<sub>2</sub> nanoparticles and hydrophilic structure of UiO-66 nanoparticles that could accelerate the exchange rate between solvent and non-solvent during the phase inversion process. By adding the MOFs into PES matrix, the flux recovery ratio was increased greatly (more than 99% for most mixed matrix membranes). The mixed matrix membranes showed higher resistance to protein adsorption compared to pristine PES membranes. After immersing the membranes in water for 3 months, 6 months and 12 months, both MOFs were stable and retained their structure. This study indicates that UiO-66 and UiO-66-NH<sub>2</sub> are great candidates for designing long-term stable mixed matrix membranes with higher anti-fouling performance.</p>


2018 ◽  
Vol 135 (21) ◽  
pp. 46271 ◽  
Author(s):  
Elahe Ahmadi Feijani ◽  
Ahmad Tavassoli ◽  
Hossein Mahdavi ◽  
Hossein Molavi

2018 ◽  
Vol 565 ◽  
pp. 370-379 ◽  
Author(s):  
Guoji Huang ◽  
Ali Pournaghshband Isfahani ◽  
Ansori Muchtar ◽  
Kento Sakurai ◽  
Binod Babu Shrestha ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (4) ◽  
pp. 2211-2217 ◽  
Author(s):  
Bo Feng ◽  
Kai Xu ◽  
Aisheng Huang

Graphene oxide (GO) was incorporated into polyimide (PI) to fabricate GO/PI mixed matrix membranes (MMMs), which show a high water flux (36.1 kg m−2 h−1) and a high salt rejection (99.9%) for desalination of 3.5 wt% seawater at 90 °C.


2018 ◽  
Vol 212 ◽  
pp. 513-522 ◽  
Author(s):  
Stavroula Anastasiou ◽  
Nidhika Bhoria ◽  
Jeewan Pokhrel ◽  
K. Suresh Kumar Reddy ◽  
C. Srinivasakannan ◽  
...  

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