scholarly journals Mechanical Performance of Single-Graded Copolymer-Modified Pervious Concrete in a Corrosive Environment

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7304
Author(s):  
Chaohua Zhao ◽  
Xiaoyao Jia ◽  
Zhijian Yi ◽  
Hualin Li ◽  
Yi Peng
Keyword(s):  
Tensile Strength ◽  
Mechanical Performance ◽  
Mass Loss Rate ◽  
Mechanical Tests ◽  
Pervious Concrete ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cement Concrete ◽  
Flexible Polymer ◽  
Special Cases

Polymer-modified cement has found numerous applications due to its excellent tensile strength. When cement was modified with a single polymer, its tensile strength and performance marginally increased. However, when a small amount of the flexible polymer latex was added to cement, the mechanical performance of cement considerably improved. In this study, single-graded copolymer-modified pervious concrete was prepared by mixing styrene-butadiene rubber (SBR) with different acrylate polymers, and its mechanical performance and durability were systematically studied through mechanical tests and theoretical analyses. The main findings are as follows: (1) When a waterborne emulsion was added, the freeze resistance of cement concrete increased, and its mass loss rate decreased. Cement concrete with two latexes had higher sulphate corrosion resistance and substantially lower dry shrinkage strain than ordinary cement concrete. (2) Through scanning electron microscopy, the microstructural changes in the cement binder, ordinary polymer-modified concrete, and the copolymer-modified cement concrete used in this study were observed, and the findings were compared with those reported in the literature. (3) Single-graded copolymer-modified pervious concrete exhibited excellent shrinkage performance. This study showed that single-graded copolymer-modified pervious concrete satisfied the performance requirements for use as a paving material for special cases.

scholarly journals Toughness Behavior of SBR Acrylate Copolymer-Modified Pervious Concrete with Single-Sized Aggregates

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5089
Author(s):  
Chaohua Zhao ◽  
Hualin Li ◽  
Yi Peng ◽  
Xiaoyao Jia ◽  
Ali Rahman
Keyword(s):  
Mechanical Performance ◽  
Impact Resistance ◽  
Road Construction ◽  
Solid Content ◽  
Pervious Concrete ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Emulsion Copolymerization ◽  
Acrylate Copolymer ◽  
Acrylate Polymer

Pervious concrete is an eco-efficient concrete but has problems regarding its mechanical performance and permeability balance. This research investigated the feasibility of using a combination of styrene–butadiene rubber (SBR) and acrylate polymer to improve the toughness of pervious concrete while keeping its permeability. Single-sized aggregate and no sand were considered in the concrete mixture. Acrylate polymers with different solid content, PH, density, and viscosity were emulsion copolymerized with an SBR polymer. Eleven scenarios with different mix proportions and 220 specimens for compressive strength, flexural strength, flexural stiffness, impact resistance, and fracture toughness tests were selected to evaluate the effects of the copolymer on the toughness of copolymer-modified pervious concrete (CMPC). The studies showed that (1) the influence trend of the copolymers generally varied according to different mechanical indexes; (2) XG–6001 acrylate polymer mainly and comprehensively enhanced the toughness of the CMPC; (3) it was difficult to increase the enhancing property of the XG–6001 acrylate polymer with the growth of its mix proportion; (4) the zero-sand pervious concrete with 90% SBR and 10% XG–6001 acrylate emulsion copolymerization proved to have relatively high toughness. The proposed CMPC holds promising application value in sustainability traffic road construction.

Structure and Mechanical Properties of Carboxylated Styrene-Butadiene Rubber (XSBR)/Pristine Clay Nanocomposites

e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
Mahdi Abdollahi ◽  
Ali Rahmatpour ◽  
Homayon Hossein Khanli
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Tensile Strain ◽  
Clay Content ◽  
Mechanical Tests ◽  
Styrene Butadiene Rubber ◽  
Clay Nanocomposites ◽  
Butadiene Rubber ◽  
Carboxylated Styrene Butadiene Rubber ◽  
Styrene Butadiene

AbstractCarboxylated styrene- butadiene rubber (XSBR)/clay nanocomposites were prepared by mixing the XSBR latex with aqueous clay dispersion and cocoagulating the mixture. TEM and XRD were applied to characterize the structure of nanocomposites. Fully exfoliated structure was observed for the nanocomposites containing equal to or less than 10 phr (weight parts per hundred) clay. With increasing the clay content to 20 phr, both non-exfoliated (stacked layers) and exfoliated structures can be observed simultaneously in the nanocomposites. The results of mechanical tests on the vulcanized clay-free XSBR and XSBR/clay nanocomposites showed that the nanocomposites present better mechanical properties than clay-free XSBR vulcanizate. Furthermore, modulus, tensile strength, tensile strain at break and hardness (shore A) increased with increasing the clay content, indicating the nanoreinforcement effect of clay on the mechanical properties of XSBR/ clay nanocomposites.

Tensile Behavior after Oxidative Aging of Gum and Black-Filled Vulcanizates of SBR and NR

1999 ◽  
Vol 72 (4) ◽  
pp. 721-730 ◽  
Author(s):  
G. R. Hamed ◽  
J. Zhao
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Behavior ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Oxidative Aging ◽  
Prolonged Aging ◽  
Aging Period ◽  
Early Aging ◽  
Styrene Butadiene

Abstract Typical sulfur-cured vulcanizates of styrene-butadiene rubber (SBR) and natural rubber (NR) were prepared, and subjected to air-oven aging at 100 °C. Gum specimens exhibited an initial aging period in which stiffness was unchanged, while tensile strength and strain-to-break were significantly reduced. In contrast, black-filled vulcanizates stiffened during early aging. After intermediate aging times, NR specimens softened, while SBR stiffened. With prolonged aging, all compositions became hard and inextensible.

scholarly journals Effects of alkanolamide addition on cure characteristics, crosslink density and tensile properties of carbon-black-filled styrene-butadiene rubber compounds

2018 ◽  
Vol 197 ◽  
pp. 12006 ◽  
Author(s):  
Indra Surya ◽  
Hanafi Ismail
Keyword(s):  
Tensile Strength ◽  
Carbon Black ◽  
Tensile Properties ◽  
Crosslink Density ◽  
Density Measurement ◽  
Tensile Modulus ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cure Characteristics ◽  
Styrene Butadiene

By using a semi-efficient sulphur vulcanisation system, the effects of alkanolamide (ALK) addition on cure characteristics, crosslink density and tensile properties of carbon black (CB)-filled styrene-butadiene rubber (SBR) compounds were investigated. The ALK was prepared from Refined Bleached Deodorized Palm Stearin and diethanolamine and added into the CB-filled SBR compounds. The ALK loadings were 1.0, 3.0, 5.0 and 7.0 phr. It was found that ALK decreased the scorch and cure times of the CB-filled SBR compounds. ALK also improved the tensile modulus and tensile strength; especially up to a 5.0 phr of loading. The crosslink density measurement proved that the 5.0 phr of ALK exhibited the highest degree of crosslink density which caused the highest in tensile modulus and tensile strength. Due to its plasticity effect, ALK increased the elongation at break of the CB-filled SBR vulcanisates.

scholarly journals Preparation and Preliminary Study on Irradiated and Thermally Treated Polypropylene (PP) - Styrene Butadiene Rubber (SBR) Composite

2011 ◽  
Vol 3 (3) ◽  
pp. 471-479
Author(s):  
M. S. I. Mozumder ◽  
M. M. Rahman ◽  
M. A. Rashid ◽  
M. A. Islam ◽  
M. E. Haque
Keyword(s):  
Tensile Strength ◽  
Elastic Modulus ◽  
Radiation Dose ◽  
Aging Time ◽  
Modulus Of Elasticity ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Preliminary Study ◽  
Styrene Butadiene ◽  
Thermally Treated

The tensile strength (TS) and elastic modulus (ES) of non-irradiated (thermally treated) and irradiated Polypropylene (PP) - styrene butadiene rubber (SBR) composites were studied. The content of SBR (mass %) on PP and radiation dose play an important role on tensile strength and modulus of elasticity of PP-SBR composites. Tensile strength (TS) decreased markedly on increasing the SBR content on PP and even on exposing to radiation. The elastic modulus (EM) of PP-SBR composite has a tendency to increase with radiation dose and aging time but decreases with SBR loading. The water uptakes increase with SBR loading which accelerate with aging.Keywords: Polypropylene; Styrene butadiene rubber; Tensile strength; Elastic modulus.© 2011 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.doi:10.3329/jsr.v3i3.3288               J. Sci. Res. 3 (3), 481-489 (2011)

scholarly journals Hazardous Waste Management of Buffing Dust Collagen

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1498
Author(s):  
Miroslawa Prochon ◽  
Anna Marzec ◽  
Oleksandra Dzeikala
Keyword(s):  
Hazardous Waste ◽  
Waste Product ◽  
Mechanical Tests ◽  
Styrene Butadiene Rubber ◽  
Infrared Analysis ◽  
Butadiene Rubber ◽  
Scanning Calorimetry ◽  
Absorption Bands ◽  
Vis Spectroscopy ◽  
The Individual

Buffing Dust Collagen (BDC) is a hazardous waste product of chromium tanning bovine hides. The aim of this study was to investigate whether BDC has the desirable properties required of modern fillers. The microstructural properties of BDC were characterized by elemental analysis (N, Cr2O3) of dry residue and scanning electron microscopy (SEM). The BDC was applied (5 to 30 parts by weight) to styrene butadiene rubber (SBR), obtaining SBR-BDC composites. The physicochemical properties of the SBR-BDC composites were examined by Fourier transform infrared analysis, SEM, UV–Vis spectroscopy, swelling tests, mechanical tests, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The biodegradability of the SBR-BDC composites and their thermo-oxidative aging were also investigated. The filler contributed to increase the cross-link density in the elastomer structure, as evidenced by enhanced mechanical strength. The introduction of a filler into the elastomer structure resulted in an increase in the efficiency of polymer bonding, which was manifested by more favorable rheological and mechanical parameters. It also influenced the formation of stable interfacial bonds between the individual components in the polymer matrix, which in turn reduced the release of compact chromium in the BDC filler. This was shown by the absorption bands for polar groups in the infrared analysis and by imaging of the vulcanization process.

scholarly journals Characterizing Distributions of Tensile Strength and Crack Precursor Size to Evaluate Filler Dispersion Effects and Reliability of Rubber

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 203 ◽  
Author(s):  
Christopher G. Robertson ◽  
Lewis B. Tunnicliffe ◽  
Lawrence Maciag ◽  
Mark A. Bauman ◽  
Kurt Miller ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Average Diameter ◽  
Strength Distribution ◽  
Glass Beads ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Failure Distribution ◽  
Filler Dispersion ◽  
Control Compound ◽  
Styrene Butadiene

Undispersed filler agglomerates or other substantial inclusions/contaminants in rubber can act as large crack precursors that reduce the strength and fatigue lifetime of the material. To demonstrate this, we use tensile strength (stress at break, σb) data from 50 specimens to characterize the failure distribution behavior of carbon black (CB) reinforced styrene-butadiene rubber (SBR) compounds. Poor mixing was simulated by adding a portion of the CB late in the mixing process, and glass beads (microspheres) with 517 μm average diameter were introduced during milling to reproduce the effects of large inclusions. The σb distribution was well described with a simple unimodal Weibull distribution for the control compound, but the tensile strengths of the poor CB dispersion material and the compounds with the glass beads required bimodal Weibull distributions. For the material with the lowest level of glass beads—corresponding to less than one microsphere per test specimen—the bimodal failure distribution spanned a very large range of σb from 13.7 to 22.7 MPa in contrast to the relatively narrow σb distribution for the control from 18.4 to 23.8 MPa. Crack precursor size (c0) distributions were also inferred from the data, and the glass beads introduced c0 values in the 400 μm range compared to about 180 μm for the control. In contrast to σb, critical tearing energy (tear strength) was unaffected by the presence of the CB agglomerates and glass beads, because the strain energy focuses on the pre-cut macroscopic crack in the sample during tear testing rather than on the microscopic crack precursors within the rubber. The glass beads were not detected by conventional filler dispersion measurements using interferometric microscopy, indicating that tensile strength distribution characterization is an important complementary approach for identifying the presence of minor amounts of large inclusions in rubber.

Influence of Novel Electron Beam Modified Surface Treated Dual Phase Filler on Rheometric and Mechanical Properties of Styrene Butadiene Rubber Vulcanizates

2003 ◽  
Vol 76 (2) ◽  
pp. 299-317 ◽  
Author(s):  
A. M. Shanmugharaj ◽  
Anil K. Bhowmick
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Electron Beam ◽  
Styrene Butadiene Rubber ◽  
Dual Phase ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Polymer Filler ◽  
Modified Surface ◽  
Styrene Butadiene

Abstract Rheometric and mechanical properties, hysteresis and swelling behavior of the Styrene-Butadiene Rubber vulcanizates (SBR) filled with unmodified and novel electron beam modified surface treated dual phase fillers were investigated. Scorch time increases for these modified filler loaded vulcanizates due to introduction of quinone type oxygen on the surface. Electron beam modification of dual phase filler in the absence of trimethylol propanetriacrylate (TMPTA) or triethoxysilylpropyltetrasulphide (Si-69) significantly improves the modulus of the SBR vulcanizates, whereas the values of tensile strength and elongation at break drop. However, presence of TMPTA or silane slightly increases the modulus with significant improvement in tensile strength. This effect is more pronounced at higher loading of these modified fillers in SBR vulcanizates. These variations in modulus and tensile strength are explained by the equilibrium swelling data, Kraus plot and a new mathematical model interpreting the polymer-filler interaction. Hysteresis loss ratio of SBR vulcanizates loaded with irradiated fillers in absence and presence of TMPTA or silane increases due to highly aggregated structure of the filler.

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