scholarly journals The Influence of the Type of Electrolyte in the Modifying Solution on the Protective Properties of Vinyltrimethoysilane/Ethanol-Based Coatings Formed on Stainless Steel X20Cr13

Materials ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 6209
Author(s):  
Aleksandra Kucharczyk ◽  
Lidia Adamczyk ◽  
Krzysztof Miecznikowski
Keyword(s):  
Stainless Steel ◽  
Steel Substrate ◽  
Sol Gel ◽  
Lithium Perchlorate ◽  
Dip Coating ◽  
Chloride Ions ◽  
Protective Properties ◽  
Resistance Surface ◽  
Coating Method ◽  
Sulphate Media

The paper reports the results of the examination of the protective properties of silane coatings based on vinyltrimethoxysilane (VTMS) and ethanol (EtOH), doped with the following electrolytes: acetic acid (AcOH), lithium perchlorate LiClO4, sulphuric acid (VI) H2SO4 and ammonia NH3. The coatings were deposited on stainless steel X20Cr13 by the sol–gel dip-coating method. The obtained VTMS/EtOH/Electrolyte coatings were characterized in terms of corrosion resistance, surface morphology and adhesion to the steel substrate. Corrosion tests were conducted in sulphate media acidified up to pH = 2 with and without chloride ions Cl−, respectively. The effectiveness of corrosion protection was determined using potentiometric curves. It has been demonstrated that the coatings under study slow down the processes of corrosion of the steel substrate, thus effectively protecting it against corrosion.

Comparison studies of the protective properties of silane/polyrhodanine and polyrhodanine/silane bilayer coatings applied on stainless steel

2018 ◽  
Vol 65 (2) ◽  
pp. 190-196 ◽  
Author(s):  
Edyta Owczarek
Keyword(s):  
Stainless Steel ◽  
Photoelectron Spectroscopy ◽  
Steel Surface ◽  
Steel Substrate ◽  
Dip Coating ◽  
Stainless Steel Surface ◽  
Protective Properties ◽  
Content Type ◽  
Anticorrosion Properties ◽  
Bilayer Coatings

Purpose The purpose of this paper is to evaluate and compare the protective, anticorrosion properties of silane- and polyrhodanine-based bilayer coatings pRh/IBTES and IBTES/pRh on an X20Cr13 stainless steel substrate. Design/methodology/approach IBTES/pRh and pRh/IBTES have been coated using the dip-coating method and the cyclic voltammetry technique. The electrochemical measurements have been used to assess the anticorrosion properties of the resulting bilayer coatings. Morphological and chemical characterizations have been performed using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Findings The results clearly show that the combination of both the deposits of polyrhodanine and silane yields a more protective structure that affords better protection against corrosion with time. The best barrier properties are achieved by the substrates coated with polyrhodanine film upon which silane is subsequently adsorbed – the pRh/IBTES bilayer coating. Originality/value The paper reveals that the procedure of modification of silane films with polyrhodanine had a marked effect on the anti-corrosive performance of the obtained two types of bilayers coatings (pRh/IBTES, IBTES/pRh) applied on a stainless steel surface. The coating where polyrhodanine was first electrodeposited on the steel surface and then the silane layer adsorbed (pRh/IBTES) achieved the best protective properties.

Macro-Residual Stress in 304 Stainless Steel Coated with ZrO2-CeO2 Thin Films by Sol-Gel Process

2007 ◽  
Vol 336-338 ◽  
pp. 2649-2651 ◽  
Author(s):  
Xin Gang Yu ◽  
Lan Yun Liu ◽  
Yan Bin Zuo ◽  
Lin Jiang Wang ◽  
Hong Wen Ma ◽  
...  
Keyword(s):  
Residual Stress ◽  
Stainless Steel ◽  
Surface Layer ◽  
Steel Substrate ◽  
Substrate Surface ◽  
Sol Gel ◽  
Dip Coating ◽  
Metal Substrate ◽  
304 Stainless Steel ◽  
Sol Gel Process

X-ray diffraction (XRD) method to measure the residual stress existing in the metal substrate surface layer was introduced and the sol-gel ZrO2-CeO2 thin film was successfully prepared on SUS304 stainless steel substrate by dip-coating process. The macro residual stress existing in metal substrate was analyzed by XRD. It turns out that the compressive stress existing in the metal substrate surface layer increases with the increase of heat-treated temperature. Based on the above study, colored stainless steels of high quality were prepared by sol-gel process.

scholarly journals CaO stabilized ZrO2 coating intended to reduce corrosion on steel and aluminum substrates

2017 ◽  
Vol 30 (2) ◽  
pp. 14-20
Author(s):  
Iván Villarreal ◽  
Miguel Aldás ◽  
Victor Hugo Guerrero-Barragan ◽  
Nelly María Rosas-Laverde ◽  
Alexis Debut
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Spin Coating ◽  
Sol Gel ◽  
Zirconium Oxychloride ◽  
Dip Coating ◽  
304 Stainless Steel ◽  
Molar Ratio ◽  
Coating Method ◽  
Aluminum Substrates

In this work, we studied the anticorrosive properties of sol-gel nanostructured calcium stabilized zirconia coatings, deposited onto 304 stainless steel and commercial aluminum substrates by dip-coating and spin-coating. During the ceramic oxide synthesis, zirconium oxychloride octahydrate was used as precursor and calcium acetate monohydrate was used as stabilizer of the cubic zirconia structure, in a precursor/stabilizer molar ratio of 0.84/0.16. The gel films deposited on steel and aluminum were heat treated at 550 y 600 °C during 5 and 10 min, respectively, and the adherence of the resulting ceramic films was evaluated. Continuous coatings were obtained that reached average thicknesses between 2 y 3 mm when deposited on stainless steel, and between 1.5 y 1.6 on aluminum, depending on the coating method. The corrosion resistance of the best-adhered coatings was evaluated during 500 h in a saline chamber, according to ASTM B117-11. All the substrate-coating combinations showed a very good corrosion resistance. For the two substrate types, the films deposited by dip-coating showed higher corrosion resistance than the ones deposited by spin-coating. The anticorrosive protective effect of the coatings was better for the aluminum substrates, compared to the stainless-steel substrates.

Fabrication of Superhydrophobic Surface of TiO2 through Sol-Gel Process on Stainless Steel Substrate

2012 ◽  
Vol 512-515 ◽  
pp. 1032-1035 ◽  
Author(s):  
Ya Wei Hu ◽  
Hui Rong He ◽  
Yang Min Ma
Keyword(s):  
Stainless Steel ◽  
Steel Substrate ◽  
Sol Gel ◽  
Dip Coating ◽  
Contact Angles ◽  
Tio2 Coating ◽  
Crystallographic Structure ◽  
Stainless Steel Surface ◽  
Water Contact ◽  
Sol Gel Process

Nano-structured TiO2 coating was constructed through sol-gel process and dip-coating method on the stainless steel surface using tetra-n-butyl titanate as precursor. The phase and the crystallographic structure of the TiO2 coating were characterized by an X-ray diffractometer (XRD), and the surface topography and structures of the TiO2 coating were characterized by a scanning electron microscope (SEM). The superhydrophobic property of the TiO2 coating modified with the fluoroalkylsilane (FAS, CF3(CF2)7CH2CH2Si(OCH3)3) was characterized by the water contact angles. It was observed that the TiO2 coating showed superhydrophobicity with water contact angle 155.3° after modifying with FAS, and the superhydrophobicity was corrosion-resistance.

Corrosion Protective Properties of Hydrotalcites Doped Hybrid Sol-Gel Coatings on Aluminium Substrates

2010 ◽  
Vol 636-637 ◽  
pp. 996-1003 ◽  
Author(s):  
D. Álvarez ◽  
A. Collazo ◽  
Miguel Hernández ◽  
Xosé R. Nóvoa ◽  
C. Pérez
Keyword(s):  
Electrochemical Impedance ◽  
Sol Gel ◽  
Dip Coating ◽  
Precipitation Method ◽  
Corrosion Performance ◽  
Protective Properties ◽  
Coating Method ◽  
Dip Coating Method ◽  
Co Precipitation ◽  
Salt Fog

Hydrotalcite-like compound that belongs to anionic clay family was prepared by classical co-precipitation method using magnesium and aluminium nitrates as precursors. Different weight percentages of hydrotalcite with Mg/Al ratio of 2.5 was added (1, 5 and 10 % wt.) to hybrid sols prepared by copolymerization of 3-Glycydoxypropyltrimethoxysilane (GPTMS) and tetra-n-propoxyzirconium (TPOZ). The aim of this work was to study the effect of the hydrotalcite incorporation to hybrid sol-gel coatings on aluminium alloys as substitution of chromate inhibitors. Hybrid sol-gel coatings were deposited by dip coating method on AA2024-T3 substrates. By Scanning Electron Microscopy (SEM) and mechanic profilometry it was possible to see the distribution of HTCP agglomerates which varies from nanometres to micrometers. The corrosion performance was evaluated by the accelerated test salt fog spray chamber (SSFC) and by Electrochemical Impedance Spectroscopy (EIS). The obtained results show the corrosion resistance improvement at higher weight percentages of HTCP.

Study on Coating Method to the Stainless Steel Substrate Top of Ag/Al2O3 Catalyst System

2008 ◽  
Vol 368-372 ◽  
pp. 1397-1400
Author(s):  
Satoshi Kishida ◽  
Dong Ying Ju ◽  
Hong He
Keyword(s):  
Stainless Steel ◽  
Stainless Steel Substrate ◽  
Heating Temperature ◽  
Steel Substrate ◽  
Nox Reduction ◽  
Catalyst System ◽  
Dip Coating ◽  
Coating Method ◽  
Powder Addition ◽  
Al2o3 Catalyst

A study of a catalyst for NOx reduction used for a diesel engine of cars is done frequently currently. In the recent studies, Ag/Al2O3 catalyst system is considered to be a candidate for practical use. The ceramics molding body (ceramics honeycomb etc.) is used as a border brim of these catalysts usually. However, there is a problem. Strength to thermal shock is low. Moreover, it is not easy to go up in the center part until the catalyst operating temperature because thermal conductivity is bad and is obstructed working of the catalyst to the first stage of the reaction for that. In this research, the Ag/Al2O3 catalyst system was coated to stainless steel (SUS304) substrate that forming it is easy and heat conduction rate is good. The aluminum nitrate was used as a binder. After the binder is dissolved in the ion exchange water, the stainless steel substrate coated Ag/Al2O3 catalyst is sintered. In order to optimize coating conditions, the heating temperature, the sintering time, the density of the binder and the amount of the coating powder addition as well as the dip coating frequency were changed, respectively.

scholarly journals Improvement of Properties of Stainless Steel Orthodontic Archwire Using TiO2:Ag Coating

Symmetry ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1734
Author(s):  
Zofia Kielan-Grabowska ◽  
Justyna Bącela ◽  
Anna Zięty ◽  
Wioletta Seremak ◽  
Marta Gawlik-Maj ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Sol Gel ◽  
Dip Coating ◽  
Physiological Solution ◽  
Bacterial Biofilm ◽  
Orthodontic Wires ◽  
Electrochemical Tests ◽  
Corrosion Studies ◽  
Coating Method ◽  
Dip Coating Method

Orthodontic treatment carries the risk of major complications such as enamel demineralization, tooth decay, gingivitis, and periodontal damage. A large number of elements of fixed orthodontic appliance results in the creation of additional plaque retention sites which increase the risk of biofilm creation. Modification of the surface of orthodontic elements may prevent the formation of bacterial biofilm. In this paper, surface modification of stainless steel orthodontic wires with TiO2: Ag was carried out by the sol-gel thin film dip-coating method. To obtain the anatase crystal structure, substrates were calcined for 2 h at 500 °C. The properties of the obtained coatings were investigated using scanning electron microscopy, X-ray diffraction, and electrochemical tests. Corrosion studies were performed in a Ringer’s solution, which simulated physiological solution. SEM and XRD analyses of the coated surface confirmed the presence of Ag nanoparticles which may have antimicrobial potential.

Porous Gel Coatings Obtained by Phase Separation in ORMOSIL System

2000 ◽  
Vol 628 ◽  
Author(s):  
Kazuki Nakanishi ◽  
Souichi Kumon ◽  
Kazuyuki Hirao ◽  
Hiroshi Jinnai
Keyword(s):  
Phase Separation ◽  
Reaction Time ◽  
Volume Fraction ◽  
Sol Gel ◽  
Reaction Times ◽  
Dip Coating ◽  
Coating Solution ◽  
Coating Method ◽  
Gel Phase ◽  
Dip Coating Method

ABSTRACTMacroporous silicate thick films were prepared by a sol-gel dip-coating method accompanied by the phase separation using methyl-trimethoxysilane (MTMS), nitric acid and dimethylformamide (DMF) as starting components. The morphology of the film varied to a large extent depending on the time elapsed after the hydrolysis until the dipping of the coating solution. On a glass substrate, the films prepared by early dipping had inhomogeneous submicrometer-sized pores on the surface of the film. At increased reaction times, relatively narrow sized isolated macropores were observed and their size gradually decreased with the increase of reaction time. On a polyester substrate, in contrast, micrometer-sized isolated spherical gel domains were homogeneously deposited by earlier dippings. With an increase of reaction time, the volume fraction of the gel phase increased, then the morphology of the coating transformed into co-continuous gel domains and macropores, and finally inverted into the continuous gel domains with isolated macropores. The overall morphological variation with the reaction time was explained in terms of the phase separation and the structure freezing by the forced gelation, both of which were induced by the evaporation of methanol during the dipping operation.

Synthesis of WO3 Electrochromic Sensor by Sol-Gel Method and Characterization of Its Electrochemical and Optical Properties

2006 ◽  
Vol 317-318 ◽  
pp. 807-810 ◽  
Author(s):  
Chang Yeoul Kim ◽  
Jin Wook Choi ◽  
Tae Yeoung Lim ◽  
Duck Kyun Choi
Keyword(s):  
Thin Film ◽  
Sol Gel ◽  
Dip Coating ◽  
Xrd Pattern ◽  
Starting Solution ◽  
Oxide Crystal ◽  
Heat Treated ◽  
Coating Method ◽  
Dip Coating Method

Electrochromic WO3 thin film was prepared by using tungsten metal solution in hydrogen peroxide as a starting solution and by sol-gel dip coating method. XRD pattern showed that tungsten oxide crystal phase formed at 400. In the view of electrochemical property, WO3 thin film which was heat-treated at 300 and was amorphous had better than that of the crystalline phase.

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