scholarly journals Recent Advances in the Fabrication and Environmental Science Applications of Cellulose Nanofibril-Based Functional Materials

Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5390
Author(s):  
Lianming Zhang ◽  
Lei Guo ◽  
Gang Wei
Keyword(s):  
Environmental Science ◽  
Materials Science ◽  
Organic Dyes ◽  
Low Cost ◽  
Cellulose Nanofibrils ◽  
Three Dimensional ◽  
Functional Materials ◽  
Building Blocks ◽  
Research Field ◽  
Practical Applications

Cellulose is one of the important biomass materials in nature and has shown wide applications in various fields from materials science, biomedicine, tissue engineering, wearable devices, energy, and environmental science, as well as many others. Due to their one-dimensional nanostructure, high specific surface area, excellent biodegradability, low cost, and high sustainability, cellulose nanofibrils/nanofibers (CNFs) have been widely used for environmental science applications in the last years. In this review, we summarize the advance in the design, synthesis, and water purification applications of CNF-based functional nanomaterials. To achieve this aim, we firstly introduce the synthesis and functionalization of CNFs, which are further extended for the formation of CNF hybrid materials by combining with other functional nanoscale building blocks, such as polymers, biomolecules, nanoparticles, carbon nanotubes, and two-dimensional (2D) materials. Then, the fabrication methods of CNF-based 2D membranes/films, three-dimensional (3D) hydrogels, and 3D aerogels are presented. Regarding the environmental science applications, CNF-based nanomaterials for the removal of metal ions, anions, organic dyes, oils, and bio-contents are demonstrated and discussed in detail. Finally, the challenges and outlooks in this promising research field are discussed. It is expected that this topical review will guide and inspire the design and fabrication of CNF-based novel nanomaterials with high sustainability for practical applications.

scholarly journals Synthesis of Three-Dimensional Graphene-Based Hybrid Materials for Water Purification: A Review

Nanomaterials ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 1123 ◽  
Author(s):  
Yan Wang ◽  
Lei Guo ◽  
Pengfei Qi ◽  
Xiaomin Liu ◽  
Gang Wei
Keyword(s):  
Hybrid Materials ◽  
Water Purification ◽  
Environmental Science ◽  
Materials Science ◽  
Three Dimensional ◽  
Water Remediation ◽  
3D Graphene ◽  
Practical Applications ◽  
Treatment Techniques ◽  
Adsorption Removal

Graphene-based nanostructures and nanomaterials have been widely used for the applications in materials science, biomedicine, tissue engineering, sensors, energy, catalysis, and environmental science due to their unique physical, chemical, and electronic properties. Compared to two-dimensional (2D) graphene materials, three-dimensional (3D) graphene-based hybrid materials (GBHMs) exhibited higher surface area and special porous structure, making them excellent candidates for practical applications in water purification. In this work, we present recent advances in the synthesis and water remediation applications of 3D GBHMs. More details on the synthesis strategies of GBHMs, the water treatment techniques, and the adsorption/removal of various pollutants from water systems with GBHMs are demonstrated and discussed. It is expected that this work will attract wide interests on the structural design and facile synthesis of novel 3D GBHMs, and promote the advanced applications of 3D GBHMs in energy and environmental fields.

scholarly journals Continuous- versus Segmented-Flow Microfluidic Synthesis in Materials Science

Crystals ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 12 ◽  
Author(s):  
Mathieu Gonidec ◽  
Josep Puigmartí-Luis
Keyword(s):  
Continuous Flow ◽  
Materials Science ◽  
Low Cost ◽  
Parallel Evolution ◽  
Reaction Diffusion ◽  
Functional Materials ◽  
Microfluidic Devices ◽  
Research Field ◽  
Segmented Flow ◽  
Materials Synthesis

Materials science is a fast-evolving area that aims to uncover functional materials with ever more sophisticated properties and functions. For this to happen, new methodologies for materials synthesis, optimization, and preparation are desired. In this context, microfluidic technologies have emerged as a key enabling tool for a low-cost and fast prototyping of materials. Their ability to screen multiple reaction conditions rapidly with a small amount of reagent, together with their unique physico-chemical characteristics, have made microfluidic devices a cornerstone technology in this research field. Among the different microfluidic approaches to materials synthesis, the main contenders can be classified in two categories: continuous-flow and segmented-flow microfluidic devices. These two families of devices present very distinct characteristics, but they are often pooled together in general discussions about the field with seemingly little awareness of the major divide between them. In this perspective, we outline the parallel evolution of those two sub-fields by highlighting the key differences between both approaches, via a discussion of their main achievements. We show how continuous-flow microfluidic approaches, mimicking nature, provide very finely-tuned chemical gradients that yield highly-controlled reaction–diffusion (RD) areas, while segmented-flow microfluidic systems provide, on the contrary, very fast homogenization methods, and therefore well-defined super-saturation regimes inside arrays of micro-droplets that can be manipulated and controlled at the milliseconds scale. Those two classes of microfluidic reactors thus provide unique and complementary advantages over classical batch synthesis, with a drive towards the rational synthesis of out-of-equilibrium states for the former, and the preparation of high-quality and complex nanoparticles with narrow size distributions for the latter.

scholarly journals Microdroplet-guided intercalation and deterministic delamination towards intelligent rolling origami

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Borui Xu ◽  
Xinyuan Zhang ◽  
Ziao Tian ◽  
Di Han ◽  
Xingce Fan ◽  
...  
Keyword(s):  
Low Cost ◽  
Rolling Direction ◽  
Three Dimensional ◽  
Van Der Waals Interaction ◽  
Creative Design ◽  
General Strategy ◽  
Practical Applications ◽  
On Demand ◽  
Vapor Sensing ◽  
Fundamental Research

Abstract Three-dimensional microstructures fabricated by origami, including folding, rolling and buckling, gain great interests in mechanics, optics and electronics. We propose a general strategy on on-demand and spontaneous rolling origami for artificial microstructures aiming at massive and intelligent production. Deposited nanomembranes are rolled-up in great amount triggered by the intercalation of tiny droplet, taking advantage of a creative design of van der Waals interaction with substrate. The rolling of nanomembranes delaminated by liquid permits a wide choice in materials as well as precise manipulation in rolling direction by controlling the motion of microdroplet, resulting in intelligent construction of rolling microstructures with designable geometries. Moreover, this liquid-triggered delamination phenomenon and constructed microstructures are demonstrated in the applications among vapor sensing, microresonators, micromotors, and microactuators. This investigation offers a simple, massive, low-cost, versatile and designable construction of rolling microstructures for fundamental research and practical applications.

scholarly journals Electrospinning Nanoparticles-Based Materials Interfaces for Sensor Applications

Sensors ◽  
2019 ◽  
Vol 19 (18) ◽  
pp. 3977 ◽  
Author(s):  
Zhang ◽  
Jia ◽  
Liu ◽  
Wei ◽  
Su
Keyword(s):  
High Performance ◽  
Environmental Science ◽  
Materials Science ◽  
Functional Materials ◽  
Label Free ◽  
Structure Property ◽  
Metallic Oxide ◽  
Electrospinning Technique ◽  
Sensor Applications ◽  
Surface Enhanced Raman

Electrospinning is a facile technique to fabricate nanofibrous materials with adjustable structure, property, and functions. Electrospun materials have exhibited wide applications in the fields of materials science, biomedicine, tissue engineering, energy storage, environmental science, sensing, and others. In this review, we present recent advance in the fabrication of nanoparticles (NPs)-based materials interfaces through electrospinning technique and their applications for high-performance sensors. To achieve this aim, first the strategies for fabricating various materials interfaces through electrospinning NPs, such as metallic, oxide, alloy/metal oxide, and carbon NPs, are demonstrated and discussed, and then the sensor applications of the fabricated NPs-based materials interfaces in electrochemical, electric, fluorescent, colorimetric, surface-enhanced Raman scattering, photoelectric, and chemoresistance-based sensing and detection are presented and discussed in detail. We believe that this study will be helpful for readers to understand the fabrication of functional materials interfaces by electrospinning, and at the same time will promote the design and fabrication of electrospun nano/micro-devices for wider applications in bioanalysis and label-free sensors.

scholarly journals Compressive Sensing Based Three-Dimensional Imaging Method with Electro-Optic Modulation for Nonscanning Laser Radar

Symmetry ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 748
Author(s):  
Yulong An ◽  
Yanmei Zhang ◽  
Haichao Guo ◽  
Jing Wang
Keyword(s):  
Compressive Sensing ◽  
3D Imaging ◽  
Low Cost ◽  
Functional Model ◽  
Three Dimensional ◽  
Visible Spectrum ◽  
Depth Map ◽  
Imaging Method ◽  
Practical Applications ◽  
Electro Optic

Low-cost Laser Detection and Ranging (LiDAR) is crucial to three-dimensional (3D) imaging in applications such as remote sensing, target detection, and machine vision. In conventional nonscanning time-of-flight (TOF) LiDAR, the intensity map is obtained by a detector array and the depth map is measured in the time domain which requires costly sensors and short laser pulses. To overcome such limitations, this paper presents a nonscanning 3D laser imaging method that combines compressive sensing (CS) techniques and electro-optic modulation. In this novel scheme, electro-optic modulation is applied to map the range information into the intensity of echo pulses symmetrically and the measurements of pattern projection with symmetrical structure are received by the low bandwidth detector. The 3D imaging can be extracted from two gain modulated images that are recovered by solving underdetermined inverse problems. An integrated regularization model is proposed for the recovery problems and the minimization functional model is solved by a proposed algorithm applying the alternating direction method of multiplier (ADMM) technique. The simulation results on various subrates for 3D imaging indicate that our proposed method is feasible and achieves performance improvement over conventional methods in systems with hardware limitations. This novel method will be highly valuable for practical applications with advantages of low cost and flexible structure at wavelengths beyond visible spectrum.

Zeolitic Host–Guest Interactions and Building Blocks for the Self-Assembly of Complex Materials

MRS Bulletin ◽  
2005 ◽  
Vol 30 (10) ◽  
pp. 713-720 ◽  
Author(s):  
Thomas Bein
Keyword(s):  
Self Assembly ◽  
Electrostatic Interactions ◽  
Spatial Organization ◽  
Organic Dyes ◽  
Three Dimensional ◽  
Internal Surface ◽  
Building Blocks ◽  
Three Dimensional Objects ◽  
Surface Areas ◽  
Catalyst Systems

AbstractOrdered nanoscale pore systems such as those represented by zeolites offer many opportunities for the design of complex functional systems via self-assembly.With their large internal surface areas and tunable, well-defined crystalline pore structures that allow molecular sieving and ion exchange, zeolites can be adapted for numerous applications. The nanoscale reactors present in zeolite pore systems have been explored as structural templates for the spatial organization of numerous guests. Examples from various fields are discussed, such as the stabilization of organic dyes for the construction of energy transfer and storage systems, the construction of host–guest hybrid catalyst systems, and the encapsulation of conducting or semiconducting nanoscale wires and clusters. More complex, hierarchical forms of nanostructured matter become accessible when zeolite crystals are used as building blocks for the selfassembly of thin films or three-dimensional objects. A combination of weaker and stronger interactions ranging from dispersive forces, hydrogen bonding, and electrostatic interactions to covalent bonding can be used to build functional hierarchical constructs. Several examples and novel applications of such systems will be discussed, including oriented channel systems, chemical sensors, and hierarchical pore systems for catalytic reactions.

Self-Assembled Cobalt Oxide Nanocrystals with Tetrahedral Shape

1998 ◽  
Vol 4 (S2) ◽  
pp. 736-737
Author(s):  
J.S. Yin ◽  
Z.L. Wang
Keyword(s):  
Cobalt Oxide ◽  
Materials Science ◽  
Surface Active Agent ◽  
Active Agent ◽  
Vertical Direction ◽  
Building Blocks ◽  
Research Field ◽  
In Situ Tem ◽  
Small Magnetic Field

Nanocrystal materials are an emerging research field of chemistry, physics and materials science. The size and shape specificity of nanocrystals suggests them as building blocks for constructing selfassembly passivated nanocrystals superlattices (NCS's) or nanocrystals arrays (NCA) [1-6]. In this paper, NCAs of CoO with controlled tetrahedral shape are reported and their structural stability is examined by in-situ TEM.Cobalt oxide nanocrystals were synthesized by chemical decomposition of Co2(CO)8 in toluene under oxygen atmosphere, as given in detail elsewhere [1].Sodium bis(2-ethylhexyl) sulfosuccinate (Na(AOT)) was added as a surface active agent, forming an ordered monolayer passivation (called the thiolate) over the nanocrystal surface. The particle size was controlled by adjusting the wt.% ratio between the precursor and Na(AOT). The as-prepared solution contained Co, CoO and possibly C03O4 nanoparticles, and pure CoO nanoparticles were separated by applying a small magnetic field, which is generated by a horseshoe permanent magnet in vertical direction.

scholarly journals Biomimetic Hydroxyapatite on Graphene Supports for Biomedical Applications: A Review

Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1435 ◽  
Author(s):  
Gang Wei ◽  
Coucong Gong ◽  
Keke Hu ◽  
Yabin Wang ◽  
Yantu Zhang
Keyword(s):  
Biomedical Applications ◽  
High Performance ◽  
Environmental Science ◽  
Materials Science ◽  
Low Cost ◽  
Biomimetic Synthesis ◽  
Synthesis Methods ◽  
Design And Synthesis ◽  
High Performance Composite ◽  
Biomimetic Hydroxyapatite

Hydroxyapatite (HA) has been widely used in fields of materials science, tissue engineering, biomedicine, energy and environmental science, and analytical science due to its simple preparation, low-cost, and high biocompatibility. To overcome the weak mechanical properties of pure HA, various reinforcing materials were incorporated with HA to form high-performance composite materials. Due to the unique structural, biological, electrical, mechanical, thermal, and optical properties, graphene has exhibited great potentials for supporting the biomimetic synthesis of HA. In this review, we present recent advance in the biomimetic synthesis of HA on graphene supports for biomedical applications. More focuses on the biomimetic synthesis methods of HA and HA on graphene supports, as well as the biomedical applications of biomimetic graphene-HA nanohybrids in drug delivery, cell growth, bone regeneration, biosensors, and antibacterial test are performed. We believe that this review is state-of-the-art, and it will be valuable for readers to understand the biomimetic synthesis mechanisms of HA and other bioactive minerals, at the same time it can inspire the design and synthesis of graphene-based novel nanomaterials for advanced applications.

Four isostructural lanthanide(III) coordination compounds based on a new N-oxydic pyridyl naphthalenediimide ligand: synthesis and characterization

2019 ◽  
Vol 75 (1) ◽  
pp. 38-45
Author(s):  
Zheng Xiang ◽  
Yue-Bin Shan ◽  
Tao Li ◽  
Chang-Cang Huang ◽  
Xi-He Huang ◽  
...  
Keyword(s):  
Organic Dyes ◽  
Three Dimensional ◽  
Wide Band ◽  
Building Blocks ◽  
Lanthanide Ions ◽  
Dimensional Structure ◽  
Spectral Studies ◽  
Hydrothermal Conditions ◽  
Large Variability ◽  
Π Interactions

Naphthalenediimides, an attractive class of electron-deficient organic dyes with rich redox and photoredox properties, have been investigated extensively as building blocks for coordination networks or metal–organic frameworks in recent decades. However, most of the available work has focused on d-block metal cations rather than f-block lanthanide ions, whose complexes exhibit a large variability in coordination numbers. In this article, four coordination polymers composed of naphthalenediimides and lanthanide cations, namely catena-poly[[[tris(nitrato-κ2 O,O′)lanthanide]-bis{μ-N,N′-bis[(1-oxidopyridin-1-ium-3-yl)methyl]-1,8:4,5-naphthalenetetracarboxdiimide-κ2 O:O′}-[tris(nitrato-κ2 O,O′)lanthanide]-μ-N,N′-bis[(1-oxidopyridin-1-ium-3-yl)methyl]-1,8:4,5-naphthalenetetracarboxdiimide-κ2 O:O′] methanol disolvate], {[Ln(C26H16N4O4)1.5(NO3)3]·CH3OH} n , with Ln = Eu, 1, Gd, 2, Dy, 3, and Er, 4, have been successfully synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analyses revealed that the four compounds are isomorphic and that each asymmetric unit contains one nine-coordinated Ln centre, one and a half diimide ligands, three nitrate anions and one uncoordinated methanol molecule. In addition, each metal centre is surrounded by nine O atoms in a distorted tricapped trigonal–prismatic geometry. Two centres are bridged by two cis ligands to form a ring, which is further bridged by trans ligands to generate one-dimensional chains. Neighbouring chains are stacked via π–π interactions between pyridine rings to give a two-dimensional structure, which is stabilized by π–π interactions between naphthalene rings, forming the final three-dimensional supermolecular network. Solid-state optical diffuse-reflectance spectral studies indicate that compound 4 is a potential wide band gap semiconductor.

scholarly journals A general aerosol-assisted biosynthesis of functional bulk nanocomposites

2018 ◽  
Vol 6 (1) ◽  
pp. 64-73 ◽  
Author(s):  
Qing-Fang Guan ◽  
Zi-Meng Han ◽  
Tong-Tong Luo ◽  
Huai-Bin Yang ◽  
Hai-Wei Liang ◽  
...  
Keyword(s):  
Electromagnetic Interference ◽  
Large Scale ◽  
Bulk Material ◽  
Cellulose Nanofibrils ◽  
High Strength ◽  
Building Blocks ◽  
Scale Production ◽  
Cellulose Nanofibril ◽  
Practical Applications ◽  
Wide Range

Abstract Although a variety of nanoparticles with better-than-bulk material performances can be synthesized, it remains a challenge to scale the extraordinary properties of individual nanoscale units to the macroscopic level for bulk nanostructured materials. Here, we report a general and scalable biosynthesis strategy that involves simultaneous growth of cellulose nanofibrils through microbial fermentation and co-deposition of various kinds of nanoscale building blocks (NBBs) through aerosol feeding on solid culture substrates. We employ this biosynthesis strategy to assemble a wide range of NBBs into cellulose nanofibril-based bulk nanocomposites. In particular, the biosynthesized carbon nanotubes/bacterial cellulose nanocomposites that consist of integrated 3D cellulose nanofibril networks simultaneously achieve an extremely high mechanical strength and electrical conductivity, and thus exhibit outstanding performance as high-strength lightweight electromagnetic interference shielding materials. The biosynthesis approach represents a general and efficient strategy for large-scale production of functional bulk nanocomposites with enhanced performances for practical applications. Industrial-scale production of these bulk nanocomposite materials for practical applications can be expected in the near future.

Sign in / Sign up

Export Citation Format

Share Document