scholarly journals The Effect of Heat Flux to the Fire-Technical and Chemical Properties of Spruce Wood (Picea abies L.)

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4989
Author(s):  
Martin Zachar ◽  
Iveta Čabalová ◽  
Danica Kačíková ◽  
Lucia Zacharová
Keyword(s):  
Heat Flux ◽  
Picea Abies ◽  
Burning Rate ◽  
Structural Changes ◽  
Thermal Loading ◽  
Chemical Properties ◽  
Spruce Wood ◽  
Lignin Condensation ◽  
Proposed Model ◽  
Charring Rate

The paper assesses the influence of the heat flux on spruce wood (Picea abies L.) behavior. The heat flux was performed at 15, 20, 25, and 30 kW∙m−2. The fire-technical properties, such as the mass burning rate, charring thickness, charring rate, as well as the chemical composition (contents of the extractives, lignin, cellulose, holocellulose), of wood were determined. The highest burning rate of spruce wood of 0.32 %·s−1 was reached at the heat flux of 30 kW∙m−2. The charring rate ranged from 1.004 mm·min−1 (15 kW∙m−2) to 2.016 mm.min−1 (30 kW∙m−2). The proposed model of the charring process of spruce wood in time and appropriate thickness as a selected parameter is applicable in validation of the results of computer fire models in the design of fire protection of wooden buildings. The decrease in the holocellulose content mostly caused by the degradation of hemicelluloses was observed during thermal loading. The biggest decrease in hemicelluloses (24.94%) was recorded in samples loaded at 30 kW∙m−2. The contents of cellulose increased due to the structural changes (carbonization and crosslinking), the content of lignin increased as well due to its higher thermal stability compared to saccharides, as well as the resulting lignin condensation.

THE MECHANISM OF RAISING AND QUANTIFICATION OF SPECIFIC HEAT FLUX AT BOILING OF NANOFLUIDS IN FREE CONVECTION CONDITIONS

2017 ◽  
pp. 25-34
Author(s):  
V.N. Moraru
Keyword(s):  
Heat Transfer ◽  
Heat Flux ◽  
Heat Capacity ◽  
Specific Heat ◽  
Chemical Properties ◽  
Heating Surface ◽  
Physical Models ◽  
Superheated Liquid ◽  
Two Phase ◽  
Boiling Process

The results of our work and a number of foreign studies indicate that the sharp increase in the heat transfer parameters (specific heat flux q and heat transfer coefficient _) at the boiling of nanofluids as compared to the base liquid (water) is due not only and not so much to the increase of the thermal conductivity of the nanofluids, but an intensification of the boiling process caused by a change in the state of the heating surface, its topological and chemical properties (porosity, roughness, wettability). The latter leads to a change in the internal characteristics of the boiling process and the average temperature of the superheated liquid layer. This circumstance makes it possible, on the basis of physical models of the liquids boiling and taking into account the parameters of the surface state (temperature, pressure) and properties of the coolant (the density and heat capacity of the liquid, the specific heat of vaporization and the heat capacity of the vapor), and also the internal characteristics of the boiling of liquids, to calculate the value of specific heat flux q. In this paper, the difference in the mechanisms of heat transfer during the boiling of single-phase (water) and two-phase nanofluids has been studied and a quantitative estimate of the q values for the boiling of the nanofluid is carried out based on the internal characteristics of the boiling process. The satisfactory agreement of the calculated values with the experimental data is a confirmation that the key factor in the growth of the heat transfer intensity at the boiling of nanofluids is indeed a change in the nature and microrelief of the heating surface. Bibl. 20, Fig. 9, Tab. 2.

scholarly journals Thermochemical and Structural Analysis of Tautomers of Sulfur and Selenium Modified RNA Nucleobases

2019 ◽  
Vol 2 (2) ◽  
pp. 47-48
Author(s):  
Megan Joy ◽  
Alex Brown ◽  
Arturo Mora Gomez ◽  
Maria Rossano-Tapia ◽  
Shyam Parshotam
Keyword(s):  
Ir Spectra ◽  
Structural Changes ◽  
Chemical Properties ◽  
Hydrogen Atoms ◽  
Relative Population ◽  
Geometry Analysis ◽  
Physical And Chemical ◽  
Modified Nucleobases ◽  
Relative Gibbs Free Energy ◽  
And Chemical Properties

Nucleobases (adenine, cytosine, guanine, and uracil), the four molecules that forms RNA, have been found to be useful in probing in the human body when modified because they can emit light. Non-modified nucleobases do not exhibit emissive properties and cannot be used as probes. Some of the modifications include the substitution of nitrogen atoms with sulfur and selenium, and the resulting modified nucleobases give place to the so-called tz- and ts- RNA alphabets, respectively. Therefore, the aim of this project was to provide insights about the viability, from a computational perspective, of using the modified nucleobases as probes, evaluating the differences in thermochemical, structural and emissive properties of the modified nucleobases with respect to the non-modified ones. Nucleobases can coexist with other modified nucleobases or tautomers, molecules that differ due to the change in position of hydrogen atoms in a molecule’s structure and as a result have different physical and chemical properties. The thermochemical properties evaluation mainly consisted in the computation of the relative Gibbs Free Energy (G), which is related to the fraction F, an index of the relative population among tautomers. This was done using Gaussian 09 software by performing geometry analysis and frequency computations on each one of the tautomers. By comparing the equilibrium fractions, it was determined that in both cases, tz- and ts- guanine and cytosine exist principally in the form of one of their tautomers (Cytosine 2 and Guanine 2) as in the case of the non-modified cases. After confirming which tz- and ts- tautomers were the ones with the largest probable population, infrared (IR) and ultraviolet-visible (UV-vis) spectra were obtained. The IR spectra of selenium and sulfur tautomers of guanine and cytosine indicated that the tautomers had peaks at similar frequencies with respect to each other, however, the intensities varied, implying slight structural changes between the tautomers. On the other hand, the UV-vis spectra showed a change in peak positions between the tautomers with sulfur and selenium, suggesting that the change between sulfur and selenium has an effect on the spectra by shifting the peaks from the original molecules’ λmax values. Their relative population fractions show that only the canonical forms of the modified nucleobases exist in a larger extent than the rest of their tautomer forms. In addition, the features in their UV-vis and IR spectra allow these tautomers to be differentiated from each other.

Investigations of Actinide Metals and Compounds under Pressure Provide Important Insights into Bonding and Chemistry

2003 ◽  
Vol 802 ◽  
Author(s):  
R. G. Haire ◽  
S. Heathman ◽  
T. Le Bihan ◽  
A. Lindbaum ◽  
M. Iridi
Keyword(s):  
Structural Changes ◽  
Chemical Properties ◽  
X Ray Diffraction ◽  
Interatomic Distances ◽  
X Ray ◽  
Effect Of Pressure ◽  
Electronic Configurations ◽  
5F Electrons ◽  
Actinide Series ◽  
Alloys And Compounds

ABSTRACTOne effect of pressure on elements and compounds is to decease their interatomic distances, which can bring about dramatic perturbations in their electronic nature and bonding, which can be reflected in changes in physical and/or chemical properties. One important issue in the actinide series of elements is the effect of pressure on the 5f-electrons. We have probed changes in electronic behavior with pressure by monitoring structure by X-ray diffraction, and have studied several actinide metals and compounds from thorium through einsteinium. These studies have employed angle dispersive diffraction using synchrotron radiation, and energy dispersive techniques via conventional X-ray sources. The 5f-electrons of actinide metals and their alloys are often affected significantly by pressure, while with compounds, the structural changes are often not linked to the involvement of 5 f-electron. We shall present some of our more recent findings from studies of selected actinide metals, alloys and compounds under pressure. A discussion of the results in terms of the changes in electronic configurations and bonding with regard to the element's position in the series is also addressed.

A refined sinusoidal model for functionally graded plates subjected to thermomechanical loading

2018 ◽  
Vol 53 (14) ◽  
pp. 1883-1896
Author(s):  
Ren Xiaohui ◽  
Wu Zhen
Keyword(s):  
Functionally Graded Material ◽  
Thermal Loading ◽  
Functionally Graded ◽  
Normal Strain ◽  
Sinusoidal Model ◽  
Proposed Model ◽  
Graded Material ◽  
Plane Displacement ◽  
Stress Free Boundary ◽  
Transverse Normal Strain

A refined sinusoidal model considering transverse normal strain has been developed for thermoelastic analysis of functionally graded material plate. Although transverse normal strain has been considered, the additional displacement parameters are not increased as transverse normal strain only includes the thermal expansion coefficient and thermal loading. Moreover, the merit of the previous sinusoidal model satisfying tangential stress-free boundary conditions on the surfaces can be maintained. It is important that the effects of transverse normal thermal deformation are incorporated in the in-plane displacement field, which can actively influence the accuracy of in-plane stresses. To assess the performance of the proposed model, the thermoelastic behaviors of functionally graded material plates with various configurations have been analyzed. Without increase of displacement variables, accuracy of the proposed model can be significantly improved by comparing to the previous sinusoidal model. Agreement between the present results and quasi-dimensional solutions are very good, and the proposed model only includes the five displacement variables which can illustrate the accuracy and effectiveness of the present model. In addition, new results using several models considered in this paper have been presented, which can serve as a reference for future investigations.

scholarly journals A simple model to estimate ice ablation under a thick debris layer

2006 ◽  
Vol 52 (179) ◽  
pp. 528-536 ◽  
Author(s):  
Han Haidong ◽  
Ding Yongjing ◽  
Liu Shiyin
Keyword(s):  
Heat Flux ◽  
Simple Model ◽  
Iterative Procedure ◽  
Indirect Comparison ◽  
Tien Shan ◽  
Balance Model ◽  
Complex Phase ◽  
Proposed Model ◽  
Koxkar Glacier

AbstractThis paper presents a simple model to estimate ice ablation under a thick supraglacial debris cover. The key method employed in the model is to establish a link between the debris heat flux and the debris temperature at a certain depth when the heat transfer in the debris is described by a diffusion process. Given surface temperature, debris thermal properties and relevant boundary conditions, the proposed model can estimate mean debris temperature at interfaces of different debris layers using an iterative procedure, and then the heat flux for ice ablation. The advantage of the proposed model is that it only requires a few parameters to conduct the modeling, which is simpler and more applicable than others. The case study on Koxkar glacier, west Tien Shan, China, shows, in general, that the proposed model gives good results for the prediction of debris temperatures, except for an apparent phase shift between modeled and observed values. We suggest that this error is mainly due to complex phase relations between debris temperature and debris heat flux. The modeled ablation rates at three experimental sites also show good results, using a direct comparison with observed data and an indirect comparison with a commonly used energy-balance model.

scholarly journals A new multifield finite element method in steady state heat analysis

2005 ◽  
Vol 9 (1) ◽  
pp. 111-130 ◽  
Author(s):  
Dubravka Mijuca ◽  
Ana Ziberna ◽  
Bojan Medjo
Keyword(s):  
Finite Element Method ◽  
Heat Flux ◽  
Finite Element ◽  
Thermal Loading ◽  
Mixed Finite Element ◽  
Finite Element Approach ◽  
Benchmark Tests ◽  
Element Approach ◽  
Steady State Heat ◽  
Solid Bodies

A new original primal-mixed finite element approach and related hexahedral finite element HC:T/q for the analysis of behavior of solid bodies under thermal loading is presented. The essential contributions of the present approach is the treatment of temperature and heat flux as fundamental variables that are simultaneously calculated, as well as capability to introduce initial and prescribed temperature and heal flux. In order to minimize accuracy error and enable introductions afflux constraints, the tensorial character of the present finite element equations is fully respected. The proposed finite element is subjected to some standard benchmark tests in order to test convergence of the results, which enlighten the effectiveness and reliability of the approach proposed.

scholarly journals How Bark Beetle Attack Changes the Tensile and Compressive Strength of Spruce Wood (Picea abies (L.) H. Karst.)

Forests ◽  
2022 ◽  
Vol 13 (1) ◽  
pp. 87
Author(s):  
Radim Löwe ◽  
Miroslav Sedlecký ◽  
Adam Sikora ◽  
Anna Prokůpková ◽  
Roman Modlinger ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Picea Abies ◽  
Bark Beetle ◽  
Reference Group ◽  
Ct Scanning ◽  
The Czech Republic ◽  
Central European ◽  
Spruce Wood ◽  
Mechanical And Physical Properties ◽  
Individual Trees

Since 2014, forestry in the Czech Republic has been significantly affected by a bark beetle outbreak. The volume of infested trees has exceeded processing capacity and dead standing spruce (Picea abies) remain in the forest stands, even for several years. What should be done with this bark beetle wood? Is it necessary to harvest it in order to preserve the basic mechanical and physical properties? Is it possible to store it under standard conditions, or what happens to it when it is “stored” upright in the forest? These are issues that interested forest owners when wood prices were falling to a minimum (i.e., in 2018–2019) but also today, when the prices of quality wood in Central European conditions are rising sharply. To answer these questions, we found out how some of the mechanical properties of wood change in dead, bark beetle-infested trees. Five groups of spruce wood were harvested. Each of these groups was left upright in the forest for a specified period of time after bark beetle infestation, and one group was classified as a reference group (uninfested trees). Subsequently, we discovered what changes occurred in tensile and compressive strength depending on the time left in the stand and the distance from the center of the trunk. When selecting samples, we eliminated differences between individual trees using a CT scanning technique, which allowed us to separate samples, especially with different widths of annual rings and other variations that were not caused by bark beetle. The results showed the effect of log age and radial position in the trunk on tensile and compressive strength. The values for tensile strength in 3-year infested trees decreased compared to uninfested trees by 14% (from 93.815 MPa to 80.709 MPa); the values for compressive strength then decreased between the same samples by up to 25.6% (from 46.144 MPa to 34.318 MPa). A significant decrease in values for compressive strength was observed in the edges of the trunks, with 44.332 MPa measured in uninfested trees and only 29.750 MPa in 3-year infested trees (a decrease of 32.9%). The results suggest that the use of central timber from bark beetle-infested trees without the presence of moulds and fungi should not be problematic for construction purposes.

Flexible Non-Intrusive Heat Flux Instrumentation for the AFRL Research Turbine

2011 ◽  
Author(s):  
Richard J. Anthony ◽  
John P. Clark ◽  
Stephen W. Kennedy ◽  
John M. Finnegan ◽  
Dean Johnson ◽  
...  
Keyword(s):  
Thin Film ◽  
Heat Flux ◽  
Large Scale ◽  
Thermal Loading ◽  
Pressure Sensors ◽  
Large Data ◽  
Fast Response ◽  
Data Sets ◽  
Unsteady Aerodynamic ◽  
Analysis System

This paper describes a large scale heat flux instrumentation effort for the AFRL HIT Research Turbine. The work provides a unique amount of high frequency instrumentation to acquire fast response unsteady heat flux in a fully rotational, cooled turbine rig along with unsteady pressure data to investigate thermal loading and unsteady aerodynamic airfoil interactions. Over 1200 dynamic sensors are installed on the 1 & 1/2 stage turbine rig. Airfoils include 658 double-sided thin film gauges for heat flux, 289 fast-response Kulite pressure sensors for unsteady aerodynamic measurements, and over 40 thermocouples. An overview of the instrumentation is given with in-depth focus on the non-commercial thin film heat transfer sensors designed and produced in the Heat Flux Instrumentation Laboratory at WPAFB. The paper further describes the necessary upgrade of data acquisition systems and signal conditioning electronics to handle the increased channel requirements of the HIT Research Turbine. More modern, reliable, and efficient data processing and analysis code provides better handling of large data sets and allows easy integration with the turbine design and analysis system under development at AFRL. Example data from cooled transient blowdown tests in the TRF are included along with measurement uncertainty.

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