scholarly journals Cost-Effectively 3D-Printed Rigid and Versatile Interpenetrating Polymer Networks

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4544
Author(s):  
Osman Konuray ◽  
Arnau Sola ◽  
Jordi Bonada ◽  
Agnieszka Tercjak ◽  
Albert Fabregat-Sanjuan ◽  
...  
Keyword(s):  
3D Printing ◽  
Polymer Networks ◽  
Complex Form ◽  
Interpenetrating Polymer Networks ◽  
Dual Processing ◽  
Digital Light Processing ◽  
Superior Mechanical Properties ◽  
3D Printed ◽  
Acrylate Resin ◽  
Printed Materials

Versatile acrylate–epoxy hybrid formulations are becoming widespread in photo/thermal dual-processing scenarios, especially in 3D printing applications. Usually, parts are printed in a stereolithography or digital light processing (DLP) 3D printer, after which a thermal treatment would bestow the final material with superior mechanical properties. We report the successful formulation of such a hybrid system, consisting of a commercial 3D printing acrylate resin modified by an epoxy–anhydride mixture. In the final polymeric network, we observed segregation of an epoxy-rich phase as nano-domains, similar to what was observed in a previous work. However, in the current work, we show the effectiveness of a coupling agent added to the formulation to mitigate this segregation for when such phase separation is undesired. The hybrid materials showed significant improvement of Young’s modulus over the neat acrylate. Once the flexible, partially-cured material was printed with a minimal number of layers, it could be molded into a complex form and thermally cured. Temporary shapes were readily programmable on this final material, with easy shape recovery under mild temperatures. Inspired by repairable 3D printed materials described recently, we manufactured a large object by printing its two halves, and then joined them covalently at the thermal cure stage with an apparently seamless union.

APPLICATION OF 3D PRINTING TECHNOLOGY FOR RAPID TOOLING IN SHEET METAL FORMING

2020 ◽  
Vol 3 ◽  
pp. 20-30
Author(s):  
M.A. SEREZHKIN ◽  
D.O. KLIMYUK ◽  
A.I. PLOKHIKH
Keyword(s):  
3D Printing ◽  
Sheet Metal ◽  
Sheet Metal Forming ◽  
Metal Forming ◽  
Rapid Tooling ◽  
Printing Technology ◽  
3D Printing Technology ◽  
3D Printed ◽  
Printed Materials ◽  
Printing Parameters

The article presents the study of the application of 3D printing technology for rapid tooling in sheet metal forming for custom or small–lot manufacturing. The main issue of the usage of 3D printing technology for die tooling was discovered. It is proposed to use the method of mathematical modelling to investigate how the printing parameters affect the compressive strength of FDM 3D–printed parts. Using expert research methods, the printing parameters most strongly affecting the strength of products were identified for further experiments. A method for testing the strength of 3D–printed materials has been developed and tested.

scholarly journals 3D Printing of Thermo-Sensitive Drugs

Pharmaceutics ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1524
Author(s):  
Sadikalmahdi Abdella ◽  
Souha H. Youssef ◽  
Franklin Afinjuomo ◽  
Yunmei Song ◽  
Paris Fouladian ◽  
...  
Keyword(s):  
3D Printing ◽  
Three Dimensional ◽  
Fused Deposition Modelling ◽  
Future Directions ◽  
Digital Light Processing ◽  
Fused Deposition ◽  
Printing Technique ◽  
3D Printed ◽  
Semi Solid ◽  
Selection Of

Three-dimensional (3D) printing is among the rapidly evolving technologies with applications in many sectors. The pharmaceutical industry is no exception, and the approval of the first 3D-printed tablet (Spiratam®) marked a revolution in the field. Several studies reported the fabrication of different dosage forms using a range of 3D printing techniques. Thermosensitive drugs compose a considerable segment of available medications in the market requiring strict temperature control during processing to ensure their efficacy and safety. Heating involved in some of the 3D printing technologies raises concerns regarding the feasibility of the techniques for printing thermolabile drugs. Studies reported that semi-solid extrusion (SSE) is the commonly used printing technique to fabricate thermosensitive drugs. Digital light processing (DLP), binder jetting (BJ), and stereolithography (SLA) can also be used for the fabrication of thermosensitive drugs as they do not involve heating elements. Nonetheless, degradation of some drugs by light source used in the techniques was reported. Interestingly, fused deposition modelling (FDM) coupled with filling techniques offered protection against thermal degradation. Concepts such as selection of low melting point polymers, adjustment of printing parameters, and coupling of more than one printing technique were exploited in printing thermosensitive drugs. This systematic review presents challenges, 3DP procedures, and future directions of 3D printing of thermo-sensitive formulations.

Environment Influence on the Properties of Functional Parts Made of HIPS Material

2021 ◽  
Vol 105 (1) ◽  
pp. 431-440
Author(s):  
Pavel Šafl ◽  
Jana Zimáková ◽  
Tomáš Binar
Keyword(s):  
Electron Microscope ◽  
3D Printing ◽  
Tensile Test ◽  
Uv Light ◽  
Starting Material ◽  
Climatic Chamber ◽  
3D Printed ◽  
Formation Of Cracks ◽  
Printed Materials ◽  
Degree Of Degradation

The aim of this work is to study the climatic influences on 3D printed materials. This study focuses on the HIPS material, which was chosen as the starting material for further studies. The material in the field of 3D printing is known for its rapid photooxidation, which results in the formation of cracks in the final product. A climatic chamber was used for degradation, in which UV light, heat and increased humidity were applied to the material. The degree of degradation was then checked by tensile test and electron microscope.

scholarly journals DLP 3D Printing Meets Lignocellulosic Biopolymers: Carboxymethyl Cellulose Inks for 3D Biocompatible Hydrogels

Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1655 ◽  
Author(s):  
Giuseppe Melilli ◽  
Irene Carmagnola ◽  
Chiara Tonda-Turo ◽  
Fabrizio Pirri ◽  
Gianluca Ciardelli ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Additive Manufacturing ◽  
3D Printing ◽  
Carboxymethyl Cellulose ◽  
Biomedical Applications ◽  
Digital Light Processing ◽  
Chemically Modified ◽  
Significant Step ◽  
3D Printed ◽  
Biomedical Field

The development of new bio-based inks is a stringent request for the expansion of additive manufacturing towards the development of 3D-printed biocompatible hydrogels. Herein, methacrylated carboxymethyl cellulose (M-CMC) is investigated as a bio-based photocurable ink for digital light processing (DLP) 3D printing. CMC is chemically modified using methacrylic anhydride. Successful methacrylation is confirmed by 1H NMR and FTIR spectroscopy. Aqueous formulations based on M-CMC/lithium phenyl-2,4,6-trimethylbenzoylphosphinate (LAP) photoinitiator and M-CMC/Dulbecco’s Modified Eagle Medium (DMEM)/LAP show high photoreactivity upon UV irradiation as confirmed by photorheology and FTIR. The same formulations can be easily 3D-printed through a DLP apparatus to produce 3D shaped hydrogels with excellent swelling ability and mechanical properties. Envisaging the application of the hydrogels in the biomedical field, cytotoxicity is also evaluated. The light-induced printing of cellulose-based hydrogels represents a significant step forward in the production of new DLP inks suitable for biomedical applications.

Thermal Conductivity Testing Apparatus for 3D Printed Materials

2017 ◽  
Author(s):  
Tiffaney Flaata ◽  
Gregory J. Michna ◽  
Todd Letcher
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Additive Manufacturing ◽  
3D Printing ◽  
Polymer Composite ◽  
Heat Exchangers ◽  
Fused Deposition ◽  
3D Printed ◽  
Printed Materials ◽  
Metal Polymer

Additive manufacturing, the layer-by-layer creation of parts, was initially used for rapid prototyping of new designs. Recently, due to the decrease in the cost and increase in the resolution and strength of additively manufactured parts, additive manufacturing is increasingly being used for production of parts for end-use applications. Fused Deposition Modeling (FDM), a type of 3d printing, is a process of additive manufacturing in which a molten thermoplastic material is extruded to create the desired geometry. Many potential heat transfer applications of 3d printed parts, including the development of additively manufactured heat exchangers, exist. In addition, the availability of metal/polymer composite filaments, first used for applications such as tooling for injection molding applications and to improve wear resistance, could lead to increased performance 3d printed heat exchangers because of the higher thermal conductivity of the material. However, the exploitation of 3d printing for heat transfer applications is hindered by a lack of reliable thermal conductivity data for as-printed materials, which typically include significant void fractions. In this experimental study, an apparatus to measure the effective thermal conductivity of 3d printed composite materials was designed and fabricated. Its ability to accurately measure the thermal conductivity of polymers was validated using a sample of acrylic, whose conductivity is well understood. Finally, the thermal conductivities of various 3d printed polymer, metal/polymer composite, and carbon/polymer composite filaments were measured and are reported in this paper. The materials used are acrylonitrile butadiene styrene (ABS), polylactic acid (PLA), stainless steel/PLA, Brass/PLA, and Bronze/PLA.

Utility and cost–effectiveness of 3D-printed materials for clinical use

2019 ◽  
Vol 3 (4) ◽  
pp. 209-218 ◽  
Author(s):  
Julian Vitali ◽  
Matthew Cheng ◽  
Michael Wagels
Keyword(s):  
Cost Effectiveness ◽  
3D Printing ◽  
Relevant Literature ◽  
Clinical Use ◽  
Surgical Guides ◽  
Rigorous Testing ◽  
Clinical Benefits ◽  
3D Printed ◽  
Surgical Adjunct ◽  
Printed Materials

This review summarizes the utility of 3D-printing as a surgical adjunct, reviewing the cost–effectiveness. The relevant literature was analyzed outlining the utility and/or cost–effectiveness of 3D-printing for clinical use. Compared with existing methods, the evidence suggests an advantage of using 3D-printing as a technology in the treatment of complex clinical cases. However, in high frequency cases, the additional preoperative expenses are not justified. Considerable evidence of its clinical benefits exists for the application of 3D-printed anatomical models and teaching tools. However, the evidence supporting 3D-printing’s use as surgical guides or implantable devices is less clear. Furthermore, caution must exist when using these devices in the clinical setting due to a paucity of rigorous testing, global regulation and long-term data.

scholarly journals 3D printers in dentistry: a review of additive manufacturing techniques and materials

2021 ◽  
Author(s):  
Leonardo Portilha Gomes da Costa ◽  
Stephanie Isabel Díaz Zamalloa ◽  
Fernando Amorim Mendonça Alves ◽  
Renan Spigolon ◽  
Leandro Yukio Mano ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Dental Materials ◽  
Clinical Results ◽  
Digital Light Processing ◽  
Fused Deposition ◽  
3D Printers ◽  
Manufacturing Techniques ◽  
Printed Materials

3D printers manufacture objects used in various dental specialties. Objective: This literature review aims to explore different techniques of current 3D printers and their applications in printed materials for dental purposes. Methods: The online PubMed databases were searched aiming to find applications of different 3D printers in the dental area. The keywords searched were 3D printer, 3D printing, additive manufacturing, rapid prototyping, 3D prototyping, dental materials and dentistry. Results: From the search results, we describe Stereolithography (SLA), Digital Light Processing (DLP), Material Jetting (MJ), Fused Deposition Modeling (FDM), Binder Jetting (BJ) and Dust-based printing techniques. Conclusion: 3D printing enables different additive manufacturing techniques to be used in dentistry, providing better workflows and more satisfying clinical results.

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