scholarly journals Silicate Mineral Eutectics with Special Reference to Lithium

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4334
Author(s):  
Agata Stempkowska

In this paper, the system of natural mineral alkali fluxes used in typical mineral industry technologies was analyzed. The main objective was to reduce the melting temperature of the flux systems. Particular attention was paid to the properties of lithium aluminium silicates in terms of simplifying and accelerating the heat treatment process. In this area, an alkaline flux system involving lithium was analyzed. A basic flux system based on sodium potassium lithium aluminosilicates was analyzed; using naturally occurring raw materials such as spodumene, albite and orthoclase, an attempt was made to obtain the eutectic with the lowest melting point. Studies have shown that there are two eutectics in these systems, with about 30% spodumene content. The active influence of sodium feldspar was found.

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7321
Author(s):  
Agata Stempkowska

The aim of the research was to check whether the system of three fluxes based on lithium aluminium silicate and alkali feldspars has a eutectic point, i.e., with the lowest melting temperature. Lithium was introduced into the mixtures in the form of petalite, which occurs naturally in nature (Bikita Zimbabwe deposit). Using naturally occurring raw materials such as petalite, sodium feldspar, and potassium feldspar, an attempt was made to obtain eutectics with the lowest melting point to facilitate thermal processing of the mineral materials. In addition, the high-temperature viscosity of the mineral alloys and physical parameters such as density, linear shrinkage, and open porosity were studied. The study showed that in these systems, there is one three-component eutectic at 1345 °C, with the lowest viscosity of 1·105 Pas and the highest density of 2.34g/cm3, with a weight content of petalite 20%, sodium feldspar 20%, and potassium feldspar 20%.


2021 ◽  
Vol 410 ◽  
pp. 699-703
Author(s):  
Valeriya È. Shvarczkopf ◽  
Irina A. Pavlova ◽  
Elena P. Farafontova

The research focuses on the properties of by-products formed in the production of porcelain stoneware: polishing residue and residue of the mixture-preparation shop. The polishing residue consists of glassy phase (80%), quartz (14%), mullite (5%). Residue of the mixture-preparation shop consists of quartz (~ 18%), muscovite (~ 6.9%), kaolinite (~ 20.5%), calcium-sodium feldspar (~ 51.4%), diopside (~ 2.98%). Polishing residue occurs when polishing porcelain stoneware to create a glossy surface and when polishing the side faces of porcelain stoneware to obtain accurate tile geometry. The particle size of the polishing residue is less than 0.2 mm, and the residue of the mixture-preparation shop is less than 40 microns. Residue of the mixture-preparation shop is formed when cleaning equipment: mills, mixers, slipways, etc. The ways of utilization of by-product are follows: as a filler for the silicate production; for polymer-cement, water-dispersion and oil paints; as a filler for the production of roofing materials, bituminous roofing mastics based on organic binders; raw materials for the production of foam glass materials and products.


2012 ◽  
Vol 727-728 ◽  
pp. 1016-1021 ◽  
Author(s):  
S.R. Bragança ◽  
H.C.M Lengler ◽  
Carlos Pérez Bergmann

Wollastonite is a calcium silicate mineral natural or synthetic. Commercial wollastonite starts to melt at about 1450°C and can not be considered a "flux" as alkali feldspar. For this function, it depends on the reaction with other raw materials. Faced with this, came the goal of this work which was to investigate the mechanism of action of wollastonite as a ceramic flux. The use of wollastonite in ceramic bodies was investigated by analysis of its reactivity with other materials such as quartz, kaolin, talc and feldspar. It was analyzed the technological properties of the final parts, especially in relation to the firing temperature, phase formation and technological properties (mechanical strength, porosity, etc.). The results of this characterization showed that the technical properties of the parts are developed according to commercial porcelain products.


2010 ◽  
Vol 450 ◽  
pp. 137-140
Author(s):  
Fwu Hsing Liu ◽  
Tsui Yen Ni ◽  
Yung Kang Shen ◽  
Jeou Long Lee

This paper proposes a solid freefrom fabrication (SFF) technology for fabricating hydroxyapatite(HA)-silica ceramics, which can generate porous three-dimensional physical objects. The HA powder and the silica are mixed with water into slurries form as raw materials. The slurries are paved by a scraper to from a thin layer which is selective scanned by a laser beam according to the cross-section of a 3D model. The HA particles are embeded in the sintered silica matrix to form green parts via a suitable range of process parameters. The benefits of this process are: bio-ceramic parts can be built by lower laser energy and faster fabricating speed. Following a subsequence heat treatment process has been developed to optimize the crystallization process and to increase the strength of the sintered parts. The parts were analyzed by an Atomic Force Microscope (AFM) to determine the surface roughness. The results obtained indicate that the proposed process was possible to generate multilayer, overhanging, and porous structure with brittle property but sufficient integrity for handling prior to post-processing. It was possible to produce the porous structure from the proposed hydroxyapatite-silica ceramics, which had a greater potential for possible bone scaffolds fabrication.


2021 ◽  
Author(s):  
E. P. Lokshin ◽  
◽  
O. A. Tareeva ◽  
◽  
◽  
...  

This paper summarizes the findings of the research aimed at the development of a new method for the integrated processing of naturally occurring and anthropogenic rare-earth raw materials based on the decomposition of rare-earth element (REE) concentrates in the presence of sulfocationite. Sorption and desorption of REE cations on a strongly acidic ion exchanger, sorbent regeneration, and REE recovery from eluates are discussed. A virtually zero-waste integrated process for apatite concentrate is proposed. The generalization of the research findings is aimed at demonstrating the prospects and universality of the proposed resource-saving and environmentally safe approach to the processing of various types of naturally occurring and anthropogenic rare-earth mineral feeds. The new methodology made it possible to develop a number of new hydrochemical processes united by a single approach, providing a qualitative increase in the processing performance of various types of rare-earth mineral feeds. The theoretical foundations of a unified approach to the processing of a wide range of minerals can significantly accelerate and cheapen the implementation of specific process circuits, significantly reduce reagent consumption and waste generation, simplify the separation of rare earth elements and impurities, and the separation of rare earth elements from naturally occurring radionuclides, fluorine, and phosphorus. The study was funded by the Kolarctic CBC 2014-2020 program, Project KO1030 SEESIMA — Supporting Environmental Economic and Social Impacts of Mining Activity.


Author(s):  
Olga P. Sazhina ◽  
Oxana V. Glazkova ◽  
Alexandr A. Shabarin ◽  
Yulia I. Matyushkina

An approach implemented in a higher school education system requires use of interactive forms in learning process. Using the example of organisation of laboratory and practical lessons "Methods of quality control with respect to raw materials and products of chemistry manufacture" the effectiveness of training discussions as an interactive form of learning while implementing a competency based approach was demonstrated. Analysis of natural magnetite, used as a raw material for production of iron by the pyrometallurgical method, was chosen as a subject of the discussion. Initially, students analyse State Standard (GOST) N 32517.1-2013 on their own. In class they analyse the Standard from the perspective of use of potentiometric titration instead of visual one under the supervision of instructors. They do modernization of technique for determining: correct a list of specimen used, solution strength, mass of magnetite sample, volume of a sample for titration; suggest a list of laboratory dishes and devices, make preliminary calculations and find out the calculation formula. In the course of discussion, the most preferable method of experiment is elaborated on and recorded. Upon completion a public discussion of the results is held. Each group analyses the obtained data, indicates the positive and negative sides of the suggested method for potentiometric determination of iron content in naturally occurring magnetite. Based on results of questionnaire survey having been held among students who took part in the pedagogic experiment, it was discovered that the proposed way of holding laboratory and practical lessons is more effective in comparison to the traditional one, while serving to unlock the students’ research potential. This way requires applying theoretical skills learned earlier to perform a particular research task. They also learn to work in a team, to sum up results of the common activity and hold responsibility for the results received. Moreover, public speaking is also an important point of learning process. The proposed methods of gaining skills for solution of training tasks facilitate development of intellectual, speaking and communicative students’ competences; they make future specialists more prepared for resolving real production issues.For citation:Sazhina O.P., Glazkova O.V., Shabarin A.A., Matyushkina Yu.I. Use of training discussion at laboratory and practical lessons while implementing competency based approach. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 7. P. 97-101.


2014 ◽  
Vol 608 ◽  
pp. 325-330 ◽  
Author(s):  
Chaisiri Luangnaem ◽  
Apha Sathonsaowaphak ◽  
Onlamee Kamon-In ◽  
Kedsarin Pimraksa

This paper developed engobe samples for Dan Kwian ceramic body. Kaolinite clay, zirconium silicate, sodium feldspar and quartz were used as raw materials which were varied to obtain various samples. Mix proportion was designed by the square sampling method to obtain 16 samples. All samples were milled and fired at 1200°C under oxidation and reduction atmospheres. The results showed that the suitable engobe composition of kaolinite clay 10 wt%, zirconium silicate 10 wt%, sodium feldspar 40 wt% and quartz 40 wt% to produce good surface appearance for Dan Kwian ceramics. Engobe surfaces and the body had no defect both in the oxidation and reduction atmospheres. The color and engobe surface were opaque white and glossy, respectively.


2014 ◽  
Vol 587-589 ◽  
pp. 1007-1011
Author(s):  
Xiao Hui Ju

There are many kinds of materials and technology for asphalt pavement crack treatment. There are difference in treatment effect and the time spent, and significant differences between the treatment cost. In order to select reasonable crack treatment process and material, to choose the crack maintenance of advanced technology and environmental protection, it is necessary to put forward a scientific and reasonable method of asphalt pavement crack treatment. Three new concept of evaluation method of asphalt pavement crack treatment are put forward, such as durability evaluation index, economy evaluation index and process evaluation index. On this basis, the evaluation method of single asphalt pavement crack treatment is put forward, while the index of the quality of raw materials are determined.


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