scholarly journals Changes in the Strength Properties and Phase Transition of Gypsum Modified with Microspheres, Aerogel and HEMC Polymer

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3486
Author(s):  
Justyna Ciemnicka ◽  
Karol Prałat ◽  
Artur Koper ◽  
Grzegorz Makomaski ◽  
Łukasz Majewski ◽  
...  
Keyword(s):  
Phase Transition ◽  
Differential Scanning Calorimetry ◽  
Compressive Strength ◽  
Bending Strength ◽  
Strength Properties ◽  
Test Results ◽  
Strength Parameters ◽  
Scanning Calorimetry ◽  
Binding Material ◽  
The Impact

The paper presents an assessment of the impact of using additives on the strength of a binding material, i.e., building gypsum, and also the phase transformation that takes place in it. Microspheres, aerogel and polymer (HEMC) additives were added to a building gypsum slurry with a water to gypsum ratio of 0.75. In order to investigate their influence on bending strength, compressive strength, and the effect of high temperatures, differential scanning calorimetry (DSC), as well as tests of the multicomponent binder, were carried out in accordance with the applicable PN-EN 13279-2:2005 standard. The obtained test results allowed to determine that the used additives influenced the strength parameters of the obtained composites. It was shown that the applied additives decreased the compressive and bending strength of the modified gypsum. Despite these properties, the obtained gypsum materials are environmentally friendly because they reuse wastes, such as microspheres. Out of all the applied additives, the use of microspheres in an amount of 10% caused a decrease in the bending strength by only 10%, and an increase in the compressive strength by 4%.

scholarly journals Impact of Elevated Temperatures on Strength Properties and Microstructure of Calcium Sulfoaluminate Paste

Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6751
Author(s):  
Konrad A. Sodol ◽  
Łukasz Kaczmarek ◽  
Jacek Szer ◽  
Sebastian Miszczak ◽  
Mariusz Stegliński
Keyword(s):  
Compressive Strength ◽  
Building Materials ◽  
Elevated Temperatures ◽  
Cooling System ◽  
Base Material ◽  
Visual Assessment ◽  
Strength Properties ◽  
Strength Parameters ◽  
Calcium Sulfoaluminate ◽  
Wide Range

This article is motivated by civil fire safety. Fire-prevention engineering demands a wide range of information about building materials including alternative cements, for instance CSA-cement. Because of exposure of the cement-base material to a high temperature, its strength properties deteriorate due to dehydration connected with phase and microstructure changes. Previous research indicated that the main endothermic reaction of CSA-based composite, dehydration of ettringite, might be used as a cooling system for a metal structure during fire-load. This article examines visual assessment, microstructure, density, as well as flexural and compressive strength parameters of CSA-based composite after isothermal heating at temperatures from 23 °C to 800 °C. The results of SEM/EDS investigations showed that the calcium sulfoaluminate paste may start partially re-sintering above 600 °C. Mechanical tests revealed significant reduction of strength parameters but residual compressive strength was maintained in the whole temperature range e.g., 8 MPa at 800 °C. Additionally, visual assessment of the specimens indicated that it might be possible to predict the material temperature heating based on the specific surface color. These findings add to the evidence of general knowledge about CSA hydrates.

scholarly journals The Influence of the Nature of Redox-Active Moieties on the Properties of Redox-Active Ionic Liquids and on Their Use as Electrolyte for Supercapacitors

Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6344
Author(s):  
Philipp S. Borchers ◽  
Patrick Gerlach ◽  
Yihan Liu ◽  
Martin D. Hager ◽  
Andrea Balducci ◽  
...  
Keyword(s):  
Phase Transition ◽  
Differential Scanning Calorimetry ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Binary Mixtures ◽  
Thermal Characteristics ◽  
The Other ◽  
Scanning Calorimetry ◽  
Imidazolium Ionic Liquids ◽  
Redox Active

In this work, two new redox-active ionic liquids, one based on 2,2,6,6-tetramethylpiperidine-N-oxide and the other based on 4,4′-bipyridine, are synthesized and characterized. A ferrocene-based redox-active ionic liquid is used for referencing the results. All ionic liquids are formed via salt-metathesis from halogenate to bis(trifluoromethylsulfonyl)imide. Their fundamental thermal characteristics are assessed with differential scanning calorimetry. While the imidazolium ionic liquids show no melting point, the phase transition is well observable for the viologen-based ionic liquid. The properties of the neat redox-active ionic liquids and of binary mixtures containing these ionic liquids (0.1 m) and 1-butyl-1-methyl pyrrolidinium-bis(trifluoromethylsulfonyl)imide have been investigated. Finally, the use of these binary mixtures in combination with activated carbon-based electrodes has been considered in view of the use of these redox-active electrolytes in supercapacitors.

DIFFERENTIAL SCANNING CALORIMETRY INVESTIGATION OF PHASE TRANSITION IN BaZrXTi1-XO3

2009 ◽  
Vol 108 (1) ◽  
pp. 106-115 ◽  
Author(s):  
B. GARBARZ-GLOS ◽  
R. BUJAKIEWICZ-KOROŃSKA ◽  
D. MAJDA ◽  
M. ANTONOVA ◽  
A. KALVANE ◽  
...  
Keyword(s):  
Phase Transition ◽  
Differential Scanning Calorimetry ◽  
Scanning Calorimetry

Influence of Cadmium Oxide on Thermal Hazard of AP-CMDB Propellants

2015 ◽  
Vol 1095 ◽  
pp. 419-422 ◽  
Author(s):  
Hao Nan Jia ◽  
Gui E Lu ◽  
Zhen Tao An ◽  
Jin Yong Jiang ◽  
Qiang Ge ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Decomposition Rate ◽  
Initial Temperature ◽  
Cadmium Oxide ◽  
Thermal Hazard ◽  
Test Results ◽  
Thermal Safety ◽  
Scanning Calorimetry ◽  
Two Stages

The influence of cadmium oxide on the thermal decomposition behaviors of AP-CMDB propellants was studied by differential scanning calorimetry (DSC) and accelerating rate calorimetry (ARC). The test results show that the decomposition process of AP-CMDB can be divided into two stages. Cadmium oxide can increase the initial temperature, slow down the decomposition rate and improve the thermal safety of AP-CMDB.

scholarly journals Strength and abrasive properties of andesite: relationships between strength parameters measured on cylindrical test specimens and micro-Deval values—a tool for durability assessment

2020 ◽  
Author(s):  
Balázs Czinder ◽  
Ákos Török
Keyword(s):  
Compressive Strength ◽  
Uniaxial Compressive Strength ◽  
Test Results ◽  
Strength Parameters ◽  
Data Set ◽  
Freeze Thaw ◽  
Laboratory Test Results ◽  
Significant Difference ◽  
Abrasive Properties ◽  
Water Saturated

Abstract Aggregates are necessary materials for the construction industry. Owing to their favourable properties, andesites are frequently used rock materials; hence, the investigation of their mechanical and aggregate properties has great significance. This paper introduces the analyses of 13 Hungarian andesite lithotypes. The samples were collected from six andesite quarries in Hungary. Cylindrical specimens and aggregate samples with 10.0/14.0-mm-sized grains were made from rock blocks. The specimens were tested in dry, water-saturated and freeze–thaw subjected conditions. Bulk density, uniaxial compressive strength, modulus of elasticity, indirect tensile strength and water absorption were measured. The abrasion resistance was tested by micro-Deval tests. The flakiness indexes of the samples were also measured. The data set of the laboratory test results provided input for further, one- and two-variable statistical analyses. According to the test results, there is no significant difference between the strength parameters measured in water-saturated and in freeze–thaw subjected conditions. The correlation and regression analyses revealed relationships between some rock mechanical parameters, as well as between micro-Deval coefficient and uniaxial compressive strength.

A Novel Approach to Unzipped Tubes Synthesis Using Sulfanilic Acid as the Backbone Amino Acid

2019 ◽  
Vol 57 ◽  
pp. 17-30
Author(s):  
Christopher Narh ◽  
Charles Frimpong ◽  
Qu Fu Wei
Keyword(s):  
Differential Scanning Calorimetry ◽  
Bond Formation ◽  
Sulfanilic Acid ◽  
Test Results ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Torsion Angles ◽  
X Ray ◽  
Novel Approach ◽  
Hydrophobic Peptide

In this research, unzipped sulfanilic acid inspired hydrophobic peptide tube was synthesis by increasing the polarity of sulfanilic acid through nucleophilic attachment of aniline which then provided two reactive sites at the S-terminus. These two sites were then attached with the N-terminal of valine and alanine respectively at an intensity of 1000-1600 of 11 2θ (°). Through π-π stacking at the side chains, the opened ended peptide was linearly arranged to form the unzipped tube. Fourier transform infrared spectroscopy (FTIR) confirm the amine bond formation whiles X-ray diffraction test results confirmed D-spacing 7.36 and 4.44 corresponding 2θ (°)12 and 19.97 respectively whiles the torsion angles (Ø2) conformations was between-150.5°and-169.2° and-2 between-129.0° and-150.6°. The Thermogravimetric analysis result showed an increase in the rigidity of the bond with an increasing intensity. Finally, Differential scanning calorimetry (DSC) test was carried out to confirm the crystallinity of the structure. Keywords: Sulfanilic acid, hydrophobic Peptide, Unzipped tubes, Nanomaterial

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