scholarly journals Carbon-Silica Composite as Adsorbent for Removal of Hazardous C.I. Basic Yellow 2 and C.I. Basic Blue 3 Dyes

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3245
Author(s):  
Małgorzata Wiśniewska ◽  
Monika Wawrzkiewicz ◽  
Magda Onyszko ◽  
Magdalena Medykowska ◽  
Agnieszka Nosal-Wiercińska ◽  
...  
Keyword(s):  
Solid Surface ◽  
Organic Dyes ◽  
Ionic Composition ◽  
Dye Adsorption ◽  
Hazardous Substances ◽  
Isotherm Models ◽  
Phase Contact Time ◽  
Silica Composite ◽  
Equilibrium Data ◽  
Triton X

Treatment of wastewaters containing hazardous substances such as dyes from the textile, paper, plastic and food industries is of great importance. Efficient technique for the removal of highly toxic organic dyes is adsorption. In this paper, adsorptive properties of the carbon-silica composite (C/SiO2) were evaluated for the cationic dyes C.I. Basic Blue 3 (BB3) and C.I. Basic Yellow 2 (BY2). The sorption capacities were determined as a function of temperature (924.6–1295.9 mg/g for BB3 and 716.3-733.2 mg/g for BY2 at 20–60 °C) using the batch method, and the Langmuir, Freundlich and Temkin isotherm models were applied for the equilibrium data evaluation using linear and non-linear regression. The rate of dye adsorption from the 100 mg/L solution was very fast, after 5 min. of phase contact time 98% of BB3 and 86% of BY2 was removed by C/SiO2. Presence of the anionic (SDS), cationic (CTAB) and non-ionic (Triton X-100) surfactants in the amount of 0.25 g/L caused decrease in BB3 and BY2 uptake. The electrokinetic studies, including determination of the solid surface charge density and zeta potential of the composite suspensions in single and mixed adsorbate systems, were also performed. It was shown that presence of adsorption layers changes the structure of the electrical double layer formed on the solid surface, based on the evidence of changes in ionic composition of both surface layer and the slipping plane area. The greatest differences between suspension with and without adsorbates was obtained in the mixed dye + SDS systems; the main reason for this is the formation of dye-surfactant complexes in the solution and their adsorption at the interface.

scholarly journals Study on the adsorption of methylene blue from aqueous solution using hydrogel glucomannan/graphene oxide

2021 ◽  
Vol 10 (1) ◽  
pp. 59-66
Author(s):  
Son Le Lam ◽  
Phu Nguyen Vinh ◽  
Hieu Le Trung ◽  
Tan Le Thua ◽  
Nhan Dang Thi Thanh ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Graphene Oxide ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Dye Adsorption ◽  
Order Kinetic ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Glucomannan/graphene oxide (GM/GO) hydrogel was synthesized by using calcium hydroxide as the crosslinker. The synthesized material was characterized by using IR, XRD, SEM, EDX and RAMAN technology. The composite hydrogel was used for removal of organic dyes from aqueous solution. The results showed that the GM/GO hydrogel had a porous structure and a high adsorption capacity toward methylene blue (MB). The pseudo-second-order kinetic model could fit the rate equation of MB adsorption onto the GM/GO hydrogel. The adsorption of MB onto GM/GO hydrogel was a spontaneous process. In addition, the equilibrium adsorption isotherm data indicated that equilibrium data were fitted to the Langmuir isotherm and the maximum dye adsorption capacity was 198,69 mg.g-1. Moreover, the hydrogel was stable and easily recovered and adsorption capacity was around 97% of the initial saturation adsorption capacity after being used five times.

scholarly journals Synthesis of Copper(II) Trimesinate Coordination Polymer and Its Use as a Sorbent for Organic Dyes and a Precursor for Nanostructured Material

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1024 ◽  
Author(s):  
Gulzhian I. Dzhardimalieva ◽  
Rose K. Baimuratova ◽  
Evgeniya I. Knerelman ◽  
Galina I. Davydova ◽  
Sarkyt E. Kudaibergenov ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Organic Dyes ◽  
Methyl Violet ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Infrared Spectrometry ◽  
Synthesis Methods ◽  
Type I ◽  
Free Energy Of Adsorption

Several important synthesis pathways for metal-organic frameworks (MOFs) were applied to determine how the synthesis methods and conditions affect the structure and adsorption capacity of the resulting samples. In the present work, three different synthesis routes were used to obtain copper trimesinate coordination polymer: Slow evaporation (A), solvothermal synthesis using a polyethylene glycol (PEG-1500) modulator (B), and green synthesis in water (C). This MOF was characterized by elemental analysis, infrared spectrometry, X-ray diffraction, scanning electron microscopy, thermogravimetry and volumetric nitrogen adsorption/desorption. The samples have permanent porosity and a microporous structure with a large surface area corresponding to the adsorption type I. The obtained MOF was tested as a sorbent to remove organic dyes methylene blue (МВ), Congo red (CR) and methyl violet (MV) as examples. Dye adsorption followed pseudo-first-order kinetics. The equilibrium data were fitted to the Langmuir and Freundlich isotherm models, and the isotherm constants were determined. Thermodynamic parameters, such as changes in the free energy of adsorption (∆G0), enthalpy (∆H0), and entropy (∆S0), were calculated. Thermolysis of copper trimesinate leads to the formation of carbon materials Cu@C with a high purity.

scholarly journals Chemical and physical preparation of activated carbon using Raw bagasse for cationic dye adsorption

2016 ◽  
Vol 18 (2) ◽  
pp. 402-415 ◽  
Keyword(s):  
Activated Carbon ◽  
Sugarcane Bagasse ◽  
Contact Time ◽  
Dye Adsorption ◽  
Isotherm Models ◽  
Adsorptive Capacity ◽  
Adsorption Isotherm Models ◽  
Equilibrium Data ◽  
Agriculture Wastes ◽  
Physical Preparation

<div> <p>Agriculture wastes like sugarcane bagasse are available in large quantities in Egypt. Various adsorbents from natural materials, industrial waste materials, agricultural by-products, and biomass based activated carbon can be used in the removal of various dyes. Raw Bagasse pith (RBP) was used to prepare activated carbon (AC) using phosphoric acid (H<sub>3</sub>PO<sub>4</sub>) as a chemical activating agent. C The raw BP and the synthesized adsorbent were characterized by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscope (SEM). The effectiveness of AC prepared in adsorption of methylene blue (MB) has been studied as a function of adsorbent type, initial dye concentration and contact time. The effects of the initial dye concentration and contact time were evaluated. Adsorption isotherm models - Langmuir, Freundlich and Temkin were used to simulate the equilibrium data. Langmuir equation was found to have the highest value of R<sup>2</sup> compared with other models. Furthermore, it was found that sugarcane bagasse have a high adsorptive capacity towards MB.</p> </div> <p>&nbsp;</p>

scholarly journals Adsorption of Organic Dyes by TiO2@Yeast-Carbon Composite Microspheres and Their In Situ Regeneration Evaluation

2015 ◽  
Vol 2015 ◽  
pp. 1-13 ◽  
Author(s):  
Zheng Pei ◽  
Zhang Kaiqiang ◽  
Dang Yu ◽  
Bai Bo ◽  
Guan Weisheng ◽  
...  
Keyword(s):  
Organic Dyes ◽  
Low Cost ◽  
Carbon Composite ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Carbon Microspheres ◽  
Composite Microspheres ◽  
Equilibrium Data ◽  
Order Kinetic Model

TiO2@yeast-carbon microspheres with raspberry-like morphology were fabricated based on the pyrolysis method. The obtained products were characterized by field emission scanning electron microscopy (FE-SEM), energy dispersive spectrometry (EDS), and X-ray diffraction (XRD). Effects of initial dye concentration and contact time on adsorption capacity of TiO2@yeast-carbon for cationic dye methylene blue (MB) and anionic dye congo red (CR) were investigated. Experimental data were described by Langmuir, Freundlich, Temkin, and Koble-Corrigan isotherm models, respectively. It was found that the equilibrium data of MB adsorption were best represented by Koble-Corrigan, and CR adsorption was best described by both Freundlich and Koble-Corrigan isotherm models. The kinetic data of MB and CR adsorption fitted pseudo-second-order kinetic model well. The results demonstrated that TiO2@yeast-carbon microspheres achieved favorable removal for the cationic MB in comparison with that for the anionic CR. In addition, regeneration experimental results showed that TiO2@yeast-carbon exhibited good recycling stability, reusability, and in situ renewability, suggesting that the as-prepared TiO2@yeast-carbon might be used as the potential low cost alternative for recalcitrant dye removal from industrial wastewater. One possible mechanism for regenerating dye-loaded TiO2@yeast in situ was also proposed.

scholarly journals Super-Adsorbent Hydrogels for Removal of Methylene Blue from Aqueous Solution: Dye Adsorption Isotherms, Kinetics, and Thermodynamic Properties

Macromol ◽  
2021 ◽  
Vol 1 (4) ◽  
pp. 256-275
Author(s):  
Buddhabhushan Salunkhe ◽  
Thomas P. Schuman
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Polymer Network ◽  
Dye Adsorption ◽  
Isotherm Models ◽  
High Adsorption ◽  
High Adsorption Capacity ◽  
Efficient Option ◽  
Sodium Styrenesulfonate

Removal of dyes through adsorption from wastewater has gained substantial interest in recent years, especially in development of hydrogel based adsorbents, owing to their easy use and economical nature. The aim of the present study was to design a super-adsorbent hydrogel based on sodium styrenesulfonate (NaSS) monomer for removal of dyes like methylene blue (MB). NaSS displays both an aromatic ring and strongly ionic group in its monomer structure that can enhance adsorption capacity. Poly(sodium styrenesulfonate-co-dimethylacrylamide) hydrogels were prepared by solution free radical polymerization using gelatin methacryloyl (GelMA) as crosslinker, creating a highly porous, three-dimensionally crosslinked polymer network contributing to higher swelling ratios of up to 27,500%. These super-adsorbent hydrogels exhibited high adsorption capacity of 1270 mg/g for MB adsorption with above 98% removal efficiency. This is the first report for such a high adsorption capacity for dye absorbance for NaSS-based hydrogels. Additionally, the adsorption kinetics using a pseudo-first-order and the Freundlich adsorption isotherm models for multilayer, heterogeneous adsorption processes has been reported. The adsorbents’ reusability was confirmed through 4 repeated cycles of desorption-adsorption. The results discussed herein illustrate that NaSS based chemistries can be used as an efficient option for removal of organic dyes from contaminated wastewater.

scholarly journals Adsorption of arsenazo (III) due by phosphorus-containing polymer sorbent

2016 ◽  
Vol 81 (8) ◽  
pp. 907-921 ◽  
Author(s):  
Rasim Alosmanov
Keyword(s):  
Ph Effect ◽  
Arsenazo Iii ◽  
Isotherm Models ◽  
Solution Ph ◽  
Phase Contact Time ◽  
Polymer Sorbent ◽  
Adsorption Isotherm Models ◽  
Phosphorus Containing ◽  
Equilibrium Data ◽  
Pseudo Second Order

Phosphorus-containing polymer sorbent was employed for removal hazardous Arsenazo (III) dye from water. The adsorption characteristics were determined by the study at different parameters such as effect of solution pH, effect of initial dye concentration, sorbent dose, phase contact time, and temperature. The equilibrium data were analyzed on the basis of various adsorption isotherm models, namely Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich. The highest monolayer adsorption capacity has been obtained (24.75 mg g-1) at 55?C. Different thermodynamic parameters such as free energy, enthalpy, and entropy have been calculated and it was concluded that when temperature rises, adsorption increases, indicating the endothermic nature of the process. Kinetic parameters were derived by pseudo-first-order, pseudo-second-order and intraparticle kinetic models. Scanning Electron Microscopy and Fourier Transform Infrared spectroscopy were used to characterize the sorbent and also to validate the adsorption mechanism.

scholarly journals Batch Adsorption of Maxilon Red GRL from Aqueous Solution by Natural Sugarcane Stalks Powder

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Gamal Owes El-Sayed ◽  
Talaat Younis Mohammed ◽  
Ashraf Abd-Allah Salama
Keyword(s):  
Aqueous Solution ◽  
Dye Removal ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Textile Dye ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Pseudo Second Order

Sugarcane stalks powder was tested for its efficiency of removing a textile dye Maxilon Red GRL from aqueous solution. Different parameters affecting dye removal efficiency were studied. These parameters include contact time, initial dye concentration, adsorbent dose, ionic strength, pH, and temperature. Langmuir and Freundlich isotherm models were applied to the equilibrium data. The data fitted well with the Langmuir isotherm (). The maximum monolayer adsorption capacity () was found to be 20.96 mg/g at an initial pH of 7.2. The temperature variation study showed that dye adsorption is exothermic and spontaneous with increased randomness at the solid solution interface. The results indicated that sugarcane stalks could be an alternative for more costly adsorbents used for dye removal. The kinetic of the adsorption process followed the pseudo second-order kinetics model.

scholarly journals A batch study on the adsorption/desorption behavior of vancomycin on bentonite nanoparticles in aqueous solutions

2020 ◽  
Vol 82 (11) ◽  
pp. 2603-2612
Author(s):  
Hossein Khamooshi ◽  
Behnaz Dahrazma ◽  
Ali Ebrahimi ◽  
Siavash Davoodi
Keyword(s):  
Ionic Strength ◽  
Solid Surface ◽  
Mesoporous Structure ◽  
Isotherm Models ◽  
Before And After ◽  
Equilibrium Data ◽  
Metallic Cations ◽  
Adsorption Desorption ◽  
Influential Parameters ◽  
Best Fit

Abstract In this study, adsorption/desorption of vancomycin (VAN) on bentonite nanoparticles was investigated in a batch system. Adsorption experiments were carried out as a function of several influential parameters such as adsorbent dosage, pH, contact time and ionic strength. Bentonite nanoparticles were characterized by field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, Brunauer–Emmett–Teller, and Fourier transform infrared (FTIR) analyses and the mesoporous structure was revealed. Langmuir, Freundlich, and Temkin isotherm models were applied for the examination of equilibrium data, and Langmuir was found to be the best fit. With the increase in pH and ionic strength, the adsorption capacity decreases, which suggests the adsorption process may be dominated by the cation exchange mechanism. Moreover, VAN desorption from bentonite nanoparticles in two initial VAN loadings was investigated under different concentrations of metallic cations of various valences (Na+, Ca2+, Al3+), and pHs 3–10. Desorption was strongly pH-dependent and the amount of VAN desorbed increased with increasing cations concentrations. The FTIR analysis before and after VAN desorption suggests that the formation of Al-VAN and Ca-VAN complexes on the solid surface and then their detachment from the solid surface may contribute to the higher VAN desorption by Al3+ and Ca2+.

scholarly journals Biochars derived from bamboo and rice straw for sorption of basic red dyes

PLoS ONE ◽  
2021 ◽  
Vol 16 (7) ◽  
pp. e0254637
Author(s):  
Ebenezer Ampofo Sackey ◽  
Yali Song ◽  
Ya Yu ◽  
Haifeng Zhuang
Keyword(s):  
Adsorption Capacity ◽  
Rice Straw ◽  
Low Cost ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Isotherm Models ◽  
Acceptor Interaction ◽  
Equilibrium Data ◽  
Pseudo Second Order

The primary purpose of this study is to eliminate Basic Red 46 dye from aqueous solutions utilizing batch experiments by adsorption on biochars prepared from bamboo and rice straw biomass. Biochars prepared from bamboo (B), and rice straw (R) was pyrolyzed at 500°C (B500 and R500). Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FTIR) Spectroscopy, X-ray Diffraction (XRD), and surface area and porosity analyzers were used to characterize the B500 and R500 samples. The characterization results indicated that the biochars possessed an amorphous porous structure with many functional groups consisting primarily of silicates. The adsorption rate of BR46 was evaluated using two kinetic models (pseudo-first-order and pseudo-second-order), and the results indicated that the pseudo-second-order model fitted to the experimental data well (R2>0.99). Nearly 24 h was sufficient to achieve equilibrium with the dye adsorption for the two biochars. R500 had a greater adsorption efficiency than B500. As pH levels increased, the dye’s adsorption capability increased as well. The Langmuir and Freundlich isotherm models were used to investigate the equilibrium behavior of BR46 adsorption, and the equilibrium data fitted well with the Langmuir model (R2>0.99) compared to the Freundlich model (R2>0.89). The maximum adsorption capacities of BR46 are 9.06 mg/g for B500 and 22.12 mg/g for R500, respectively. Additionally, adsorption capacity increased as temperature increased, indicating that adsorption is favored at higher temperatures. The electrostatic interaction is shown to be the dominant mechanism of BR46 adsorption, and BR46 acts as an electron-acceptor, contributing to n-π EDA (Electron Donor-Acceptor) interaction. Thermodynamic parameters for the dye-adsorbent system revealed that the adsorption process is spontaneous and feasible. The values of the adsorption coefficient (Kd) were on the order of 102−103. Kd of R500 was greater than that of B500, indicating that R500 had a greater adsorption capacity. The results showed that R500 could be used as a low-cost alternative adsorbent for removing BR46 from effluents.

Comparison of color removal from reactive dye contaminated water by systems containing fungal biosorbent, active carbon and their mixture

2014 ◽  
Vol 70 (7) ◽  
pp. 1168-1174 ◽  
Author(s):  
Ülküye Dudu Gül ◽  
Hülya Silah
Keyword(s):  
Active Carbon ◽  
Low Cost ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Reactive Dye ◽  
Isotherm Models ◽  
Experimental Conditions ◽  
Adsorbent Dosage ◽  
Freundlich Adsorption Isotherm ◽  
Equilibrium Data

The adsorption of Everzol Black (EB) from synthetic aqueous solution onto active carbon (AC) and dried fungal biosorbent (Rhizopus arrhizus) was studied under the same experimental conditions. The effects of initial dye concentration, adsorbent dosage and contact time were examined at a batch-scale level. As an alternative to AC, fungus was investigated as a low-cost adsorbent for dye removal. The amount of EB adsorbed onto AC was lower compared with fungal biosorbent; dye adsorption capacity of AC and fungal biosorbent were 94.48 and 106.61 mg/g, respectively. The adsorbent dosage experiments showed that 4 g/L biosorbent removed 100% of EB (Co: 114.39 mg/L) after 2 hours. The results obtained from this study showed that biosorbent effectively removed reactive dye from dye-containing water in a short time period. Langmuir and Freundlich adsorption isotherm models were used for mathematical description of the biosorption equilibrium data; the Freundlich model was found to exhibit good fits to the experimental data. According to the Freundlich isotherm, the maximum dye adsorption capacities of AC and biosorbent were calculated as 344.82 and 357.14 mg/g, respectively. The Fourier transform infrared spectroscopy spectral analysis showed the involvement of functional groups for dye bindings.

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