scholarly journals Mechanical Properties and Toxicity Risks of Lead-Zinc Sulfide Tailing-Based Construction Materials

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2940
Author(s):  
Yang Zhou ◽  
Xinlian Duan ◽  
Tao Chen ◽  
Bo Yan ◽  
Lili Li
Keyword(s):  
Heavy Metal ◽  
Zinc Sulfide ◽  
Construction Materials ◽  
Drying Shrinkage ◽  
Recovery Process ◽  
Xrd Analysis ◽  
Metal Contents ◽  
Concrete Production ◽  
Lead Zinc ◽  
Sulfide Tailing

The leaching residue of the lead–zinc sulfide tailing (LRT) is the only residue generated from the tailing leaching recovery process; it is a typical hazardous material for its high heavy-metal contents and high acidity. Due to the large output of LRT, and because its main components are Ca, Si, and Al, the preparation of building construction materials with LRT was studied. The results showed that when the LRT addition is less than 47%, with the ordinary Portland cement (OPC) and fly ash (FA) added and the curing conditions appropriate, the strength values of the tested specimens meet the M15 Class of the autoclaved lime sand brick standard (GB/T 16753-1997). The carbonization coefficient and drying shrinkage of the specimen were 0.79 and smaller than 0.42, respectively. As the SEM, TG, and XRD analysis have shown, the LRT can chemically react with additives to form stable minerals. The heavy metal contents that were leached out well met the limits in GB5085.3-2007. Based on the high addition of the LRT, the good strength and lower heavy metals were leached out of the prepared test specimen, and the tailing could be reused completely with the leaching recovery and the LRT reuse process. LRT can be used to replace OPC, allowing more sustainable concrete production and improved ecological properties of LRT.

scholarly journals Physico-chemical properties and heavy metal contents of a tropical estuarine ecosystem, Nigeria

2018 ◽  
Vol 5 (11) ◽  
pp. 781-797
Author(s):  
Paul Chinedu Echi ◽  
Daberechi Ndudim Okpechi ◽  
Janet Azu Urum ◽  
Izuchukwu Samson Arukwe
Keyword(s):  
Heavy Metal ◽  
Chemical Properties ◽  
Oxygen Demand ◽  
International Standards ◽  
Anthropogenic Pressure ◽  
Estuarine Ecosystem ◽  
Metal Concentrations ◽  
Metal Contents ◽  
Zinc Cadmium ◽  
Lead Zinc

Ibaka Estuarine in Mbo, Nigeria, has little or no information on its basic properties, therefore its water samples were studied from March to June 2018 in three different stations and compared with International Standards to evaluate its physic-chemical properties as well as heavy metal contents. The physic-chemical properties studied include pH, salinity (g/L), EC (μs/cm), turbidity (NTU), total suspended solids (mg/L), total dissolved solids (mg/L), dissolved oxygen (mg/L), BOD5 (mg/L), and chemical oxygen demand (mg/L). In addition, some metal concentrations of manganese, iron, copper, lead, zinc, cadmium, chloride and magnesium were determined by atomic absorption spectroscopy (AAS). The range of metal concentrations manganese (0.08-0.12 mg/L), copper (0.05-0.09 mg/L), lead (0.01-0.03 mg/L), iron (1.86-4.66 mg/L), zinc (0.68-1.16 mg/L), cadmium (0.04-0.08 mg/L), chloride (675.0-791.25 mg/L), magnesium (10.66-14.30 mg/L). The study infers that anthropogenic pressure plays damaging role to its properties in addition to general health implication of high values for Fe, Zn, Cd, Cl and Mg which exceeded international standard.

scholarly journals Desulfurization kinetics of high lead and zinc sulfide containing slag with oxygen blowing

2019 ◽  
Vol 55 (2) ◽  
pp. 187-196
Author(s):  
K. Ouyang ◽  
Z.-H. Dou ◽  
T.-A. Zhang ◽  
Y. Liu ◽  
L.-P. Niu
Keyword(s):  
Zinc Sulfide ◽  
Spinel Phase ◽  
Xrd Analysis ◽  
Smelting Process ◽  
Experimental Conditions ◽  
Lead And Zinc ◽  
Desulfurization Process ◽  
Lead Zinc ◽  
Kinetics Of ◽  
High Lead

The desulfurization process of lead and zinc slag is an important smelting process to obtain lead and zinc. The aim of this paper is to study the desulfurization process of high lead and zinc sulfide containing slag with oxygen blowing. The predominance area diagrams of the Pb-Zn-Fe-S-O system (Pb/(Fe+Pb+Zn)=0.176, Zn/(Fe+Pb+Zn)=0.56) at various temperature were thermodynamically constructed. The physical properties, the chemical composition and the phase transformation of the desulfurization slag were investigated. The thermodynamic results indicated that lead, zinc, and iron can be oxidized to form high lead and zinc slag. The experimental results illustrated that the sulfur content in the oxidation slag can be reduced to less than 1% as temperature increased up to 1573 K. The XRD analysis of as-quenched slag shows the PbS and ZnS phase decreased, while zincite and spinel phase (ZnxFe3-xO4+y) emerged and increased as the reaction time increased. The desulfurization process of molten slag were considered to be the first-order reaction and the apparent activation energy was estimated to be 44.46 kJ/mol. Under the experimental conditions, the mass transfer in the gas and liquid phase was likely to be the restrictive step.

Standardization and bacteria inhibitory test of purified extract of mahogany (Swietenia mahagoni (L.) Jacq) seeds and leaves

2019 ◽  
Vol 10 (3) ◽  
pp. 2132-2138
Author(s):  
Virsa Handayani ◽  
Rezki Amriati Syarif ◽  
Ahmad Najib ◽  
Aktsar Roskiana Ahmad ◽  
Abdullah Mahmud ◽  
...  
Keyword(s):  
Escherichia Coli ◽  
Heavy Metal ◽  
Bitter Taste ◽  
Drying Shrinkage ◽  
Ash Content ◽  
Water Soluble ◽  
Lead Contamination ◽  
Specific Parameter ◽  
Chemical Content ◽  
Swietenia Mahagoni

Mahogany (Swietenia mahagoni (L.) Jacq) is one of the plants that is often used by the community as traditional medicine. One of them is antifungal, antibacterial, antidiabetic, and eczema. This study aims to obtain standardized extracts from mahogany seeds and leaves. Standardization of purified extract of mahogany has been carried out according to the monographs of extract standardization guidelines, which include testing of specific and non-specific parameters. The results of the specific parameter testing showed that the purified extract of mahogany seeds is a thick extract, brown to reddish, smells distinctive and has a bitter taste. While the purified extract of mahogany leaves is a thick extract, greenish-brown in color, distinctive smell and has a bitter taste. The chemical content of purified extract of mahogany seeds and leaves showed the presence of flavonoids, alkaloids, terpenoids and saponins. Water-soluble essence levels in mahogany seeds and leaves was 14.84% and 10.28%. While the ethanol-soluble essence levels in mahogany seeds and leaves were 15.38% and 12.43%. Testing of non-specific parameters on mahogany seeds and leaves showed the results of drying shrinkage levels of 0.22% and 8.84%, moisture content of 2.60% and 4.04%, total ash content of 1.71% and 1.93%, levels acidic insoluble ash 0.38% and 0.32%, Total Plate Number (ALT) of mahogany seed bacteria 1x102 colonies/g, Number of mahogany mold seeds 4x10 colonies/g, heavy metal lead contamination and cadmium in mahogany seeds 0.0607µg/g and<0.003µg/g. The inhibitory diameter of each concentration of seeds against Escherichia coli, 3%, 5%, 7%, and 9%, is 12,67; 13,67; 17,67; and 19,67 mm, respectively. The inhibitory diameter of each concentration of leaves against Escherichia coli, 3%, 5%, 7%, and 9%, is 10,27; 10,90; 13,46; and 15,68 mm, respectively.

Evaluation of Heavy Metal Contents in Mudflat Solar Salt, Salt Water, and Sea Water in the Nationwide Salt Pan

2012 ◽  
Vol 41 (7) ◽  
pp. 1014-1019 ◽  
Author(s):  
Hag-Lyeol Kim ◽  
Young-Joo Yoo ◽  
In-Sun Lee ◽  
Gang-Hee Ko ◽  
In-Cheol Kim
Keyword(s):  
Heavy Metal ◽  
Sea Water ◽  
Salt Water ◽  
Solar Salt ◽  
Metal Contents ◽  
Salt Pan

Heavy Metal Contents and Safety Evaluation of Commercial Salts in Seoul

2012 ◽  
Vol 41 (1) ◽  
pp. 129-135 ◽  
Author(s):  
Ae-Kyung Kim ◽  
Sung-Ja Cho ◽  
Jae-Eun Kwak ◽  
Jin-Young Kum ◽  
Il-Young Kim ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Safety Evaluation ◽  
Metal Contents

Effect of some Soil Properties on Heavy Metal Contents in Soil Qena Governorate.

2017 ◽  
Vol 8 (9) ◽  
pp. 401-409
Author(s):  
M. Ibrahim ◽  
A. Abd El-Galil ◽  
O. Negim ◽  
M. Nazir
Keyword(s):  
Heavy Metal ◽  
Soil Properties ◽  
Metal Contents

Metallic pollution in clogging materials of urban porous pavements

1995 ◽  
Vol 32 (1) ◽  
pp. 57-62 ◽  
Author(s):  
Valérie Colandini ◽  
Michel Legret ◽  
Yves Brosseaud ◽  
Jean-Daniel Baladès
Keyword(s):  
Heavy Metal ◽  
Particle Size ◽  
Road Traffic ◽  
Total Concentration ◽  
Extraction Procedure ◽  
Interaction Strength ◽  
Metal Mobility ◽  
Residual Fraction ◽  
Metal Contents ◽  
Copper Zinc

Porous pavements infiltrated with stormwater are faced with clogging problems: runoff particles seep and clog the pervious surface layer of these structures. Clogging material samples (in the form of sludge) have been collected in cleaning operations on the pervious asphalt. This study aims at characterizing these materials, particle size distribution, heavy metal contents by particle size, and studying interactions between metals and particles. A sequential extraction procedure proposed by the experts of the Community Bureau of Reference (B.C.R.) was applied to provide information about heavy metal distribution on particles and to evaluate interaction strength, and consequently potential metal mobility when chemical variations occurred in the environment. Mainly made up of sand, the materials are polluted with lead, copper, zinc and cadmium. The concentrations appeared to be linked with road traffic intensity. The heavy metal contents by particle size showed that the finer are the particles, the higher are the heavy metal concentrations. Heavy metals were found potentially labile; metals contents in the residual fraction (mineral fraction) represented less than 20 % of the total concentration. Cadmium and zinc were apparently more labile than lead and copper.

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