scholarly journals Investigation of the Behavior and Mechanism of Action of Ether-Based Polycarboxylate Superplasticizers Absorption on Large Bibulous Stone Powder

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2736
Author(s):  
Zuiliang Deng ◽  
Guimin Lu ◽  
Lefeng Fu ◽  
Weishan Wang ◽  
Baicun Zheng
Keyword(s):  
Infrared Spectroscopy ◽  
Thermogravimetric Analysis ◽  
Zeta Potential ◽  
Mechanism Of Action ◽  
Water Consumption ◽  
Pore Volume ◽  
High Water ◽  
Hydrodynamic Diameter ◽  
Coarse Aggregates ◽  
Polycarboxylate Superplasticizer

The aim of this paper is to study the adsorption behavior of polycarboxylate superplasticizers (PCE) on coarse aggregates with a property of high water consumption (above 2%). The coarse aggregates were ground into a powder to create large bibulous stone powder, and it was observed that significant amounts of the ether-based PCE were absorbed onto large bibulous stone powder. The adsorption rate immediately reached a maximum after 5 min and then gradually decreased until an equilibrium absorption was established after 30 min. Zeta potential, infrared spectroscopy, and thermogravimetric analysis (TGA) measurements confirmed that the polycarboxylate superplasticizer adsorbed on the surface of the stone powder. Hydrodynamic diameter measurements showed that the polycarboxylate superplasticizer molecules were smaller than pore size, and the surface area and pore volume were reduced by the polymer incorporation in the pores.

scholarly journals Life Cycle Blue and Grey Water in the Supply Chain of China’s Apparel Manufacturing

Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1212
Author(s):  
Ao Liu ◽  
Aixi Han ◽  
Li Chai
Keyword(s):  
Water Pollution ◽  
Supply Chain ◽  
Life Cycle ◽  
Water Consumption ◽  
Agricultural Sector ◽  
Oxygen Demand ◽  
High Water ◽  
Grey Water ◽  
Apparel Manufacturing ◽  
Economic Output

Apparel manufacturing involves high water consumption and heavy water pollution in its supply chain, e.g., planting cotton, producing chemical fibers, and dyeing. This study employs a multi-regional input–output (MRIO) model to (1) assess the life cycle of blue and grey water (chemical oxygen demand (COD) specific) of China’s apparel manufacturing; (2) reveal the hidden linkage among sectors and regions in the whole supply chain; and (3) identify the key regions and upstream sectors with the most water consumption and heaviest water pollution. We found that the agricultural sector (i.e., planting fiber crops) is responsible for primary water consumption and water pollution. In addition, different provinces assume different production roles. Guangdong is a major output province in apparel manufacturing. However, its economic output is contributed to by other regions, such as blue water from Xinjiang and Jiangsu and grey water from Hebei and Shandong. Our research reveals the significance of taking an inter-regional perspective on water resource issues throughout the supply chain in apparel manufacturing. The sustainable development of China’s apparel manufacturing relies on improving water-use efficiency and reasonable industrial layout. The results are of significance and informative for policymakers to build a water-sustainable apparel industry.

Synthesis, Characterisation and Structural Studies of [Zn(phen)3][Fe(CN)5(NO)]·2H2O·0.25MeOH and [(bipy)2(H2O)Zn(μ-NC)Fe(CN)4(NO)]·0.5H2O

2003 ◽  
Vol 58 (9) ◽  
pp. 916-921 ◽  
Author(s):  
Amitabha Datta ◽  
Samiran Mitra ◽  
Georgina Rosair
Keyword(s):  
Infrared Spectroscopy ◽  
Thermogravimetric Analysis ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Structural Studies ◽  
Crystal Lattices ◽  
X Ray ◽  
X Ray Crystallography ◽  
Distorted Octahedral ◽  
Solvent Molecules

Two new bimetallic complexes [Zn(phen)3][Fe(CN)5(NO)] · 2 H2O · 0.25 MeOH, (1) and [(bipy)2(H2O)Zn(μ-NC)Fe(CN)4(NO)] · 0.5 H2O, (2), have been isolated (where phen = 1,10-phenanthroline and bipy = bipyridyl) and characterised by X-ray crystallography [as the 2 H2O · 0.25 CH3OH solvate for (1) and hemihydrate for (2)] infrared spectroscopy and thermogravimetric analysis. Substitution of phenanthroline for bipyridyl resulted in a cyano-bridged bimetallic species rather than two discrete mononuclear metal complexes. The bond angles of Fe-N-O were shown to be practically linear for both 1 [179.2(7)°] and 2 [178.3(3)°], and the Zn atoms have distorted octahedral geometry. The solvent molecules in both crystal lattices take part in forming hydrogen-bonded networks.

scholarly journals Valorization of Byproducts of Hemp Multipurpose Crop: Short Non-Aligned Bast Fibers as a Source of Nanocellulose

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4723
Author(s):  
Sara Dalle Vacche ◽  
Vijayaletchumy Karunakaran ◽  
Alessia Patrucco ◽  
Marina Zoccola ◽  
Loreleï Douard ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Thermogravimetric Analysis ◽  
Cannabis Sativa ◽  
Crystallinity Index ◽  
Residual Lignin ◽  
Chemical Pretreatment ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bast Fibers ◽  
Seed Maturity

Nanocellulose was extracted from short bast fibers, from hemp (Cannabis sativa L.) plants harvested at seed maturity, non-retted, and mechanically decorticated in a defibering apparatus, giving non-aligned fibers. A chemical pretreatment with NaOH and HCl allowed the removal of most of the non-cellulosic components of the fibers. No bleaching was performed. The chemically pretreated fibers were then refined in a beater and treated with a cellulase enzyme, followed by mechanical defibrillation in an ultrafine friction grinder. The fibers were characterized by microscopy, infrared spectroscopy, thermogravimetric analysis and X-ray diffraction after each step of the process to understand the evolution of their morphology and composition. The obtained nanocellulose suspension was composed of short nanofibrils with widths of 5–12 nm, stacks of nanofibrils with widths of 20–200 nm, and some larger fibers. The crystallinity index was found to increase from 74% for the raw fibers to 80% for the nanocellulose. The nanocellulose retained a yellowish color, indicating the presence of some residual lignin. The properties of the nanopaper prepared with the hemp nanocellulose were similar to those of nanopapers prepared with wood pulp-derived rod-like nanofibrils.

Study on Relationship between Structure and Properties of Polycarboxylate Superplasticizer

2012 ◽  
Vol 487 ◽  
pp. 43-47
Author(s):  
Sheng Hua Lv ◽  
Di Li ◽  
Qiang Cao
Keyword(s):  
Acrylic Acid ◽  
Zeta Potential ◽  
Ethyl Ester ◽  
Functional Groups ◽  
Cement Paste ◽  
Ethyl Acrylate ◽  
Structure And Properties ◽  
Polycarboxylate Superplasticizer ◽  
Carboxylic Groups

A polycarboxylate superplasticizer (PCs) was synthesized by copolymerization of allyl polyoxyethylene ethers (APE), acrylic acid (AA), sodium methylallyl Sulfonate (SMAS) and ethyl acrylate (EA). The effect of functional groups and branch chain on PCs properties was investigated by the test of fluidity of cement paste, retardation performance and Zeta potential of cement particles. The results showed that carboxylic groups and ethyl ester groups can improve water reducing ratio and fluidity of cement paste, and the sulfonic groups has an important contributiion to retardation performance of PCs.

Formulation, Physical and Chemical Stability of Ocimum gratissimum L. Leaf Oil Nanoemulsion

2021 ◽  
Vol 901 ◽  
pp. 117-122
Author(s):  
Netnapa Ontao ◽  
Sirivan Athikomkulchai ◽  
Sarin Tadtong ◽  
Phuriwat Leesawat ◽  
Chuda Chittasupho
Keyword(s):  
Essential Oil ◽  
Zeta Potential ◽  
Chemical Stability ◽  
Polydispersity Index ◽  
Hydrodynamic Diameter ◽  
Potential Value ◽  
Yellow Color ◽  
Leaf Oil ◽  
The Stability ◽  
Physical And Chemical

Ocimum gratissimum L. leaf oil exhibited many pharmacological properties. This study aimed to formulate and evaluate the physical and chemical stability of O.gratissimum leaf oil nanoemulsion. O.gratissimum leaf oil was extracted by hydrodistillation. The major component of the essential oil eugenol, was analyzed by UV-Vis spectrophotometry. Nanoemulsions of O.gratissimum leaf oil were formulated using polysorbate 80, hyaluronic acid, poloxamer 188, and deionized water by phase inversion composition method. The hydrodynamic diameter, polydispersity index, and zeta potential value of O.gratissimum leaf oil nanoemulsion was evaluated by a dynamic light scattering technique. The %remaining of eugenol in the nanoemulsion was analyzed by UV-Vis spectrophotometry. The essential oil extracted from of O. gratissimum leaf oil was a clear, pale yellow color. The %yield of the essential oil was 0.15 ± 0.03% v/w. The size of the nanoemulsion was less than 106 nm. The polydispersity index of the nanoemulsion was ranging from 0.303 - 0.586 and the zeta potential value of the nanoemulsion was closely to zero, depending on the formulation component. O. gratissimum leaf oil at concentrations ranging from 0.002 - 0.012% v/v contained 35 - 41% of eugenol. The size of nanoemulsion was significantly decreased after storage at 4 °C, while significantly increased upon storage at 45 °C. The size of nanoemulsion stored at 30 °C did not significantly change. The %remaining of eugenol in the nanoemulsion was more than 90% after storage at 4 °C and 30 °C for 28 days. The percentage of eugenol remaining in the nanoemulsion stored at 45 °C was more than 85 - 90%, suggesting that the temperature affected the stability of eugenol in the nanoemulsion.

scholarly journals Water resources planning in bioethanol production from sugarcane

Memorias ◽  
2018 ◽  
pp. 30-35
Author(s):  
Danny Ibarra Vega Danny Ibarra Vega ◽  
Carlos Peña Rincón ◽  
Johnny Valencia Calvo ◽  
Johan Manuel Redondo ◽  
Gerard Olivar Tost
Keyword(s):  
Mathematical Model ◽  
High Risk ◽  
Water Resources ◽  
Water Consumption ◽  
High Water ◽  
Water Shortage ◽  
Agricultural Crops ◽  
Bioethanol Production ◽  
Water Resources Planning ◽  
Resources Planning

The biofuels industry has grown and has positioned itself in Colombia for national purposes, these come from biomass sources such as agricultural crops. Bioethanol is the most used in Colombia and is obtained from sugarcane. One of the main concerns of the sector and society, is the high water consumption associated with agricultural crops (9,000 m3 / ha-year), there are currently 232,000 hectares of sugarcane for the production of sugar and bioethanol. Given the aforementioned, the need arises to carry out a planning of industrial increase of the sector taking into account as a main base the demand and availability of water resources for different activities in the Cauca river basin and the demand for sugarcane crops. In this document it is presented a mathematical model and the evaluation of different scenarios of the estimation of the trend of water consumption in the bioethanol production process in Colombia and in this way to establish scenarios of high risk of water shortage both for the population, interested parties and cane cultivation.

scholarly journals Energy and Water Consumption Characterization of Portuguese Indoor Swimming Pools

2018 ◽  
Author(s):  
Bruno J. Cardoso ◽  
Adélio Rodrigues Gaspar ◽  
José Carlos Góis ◽  
Eugénio Rodrigues
Keyword(s):  
Water Consumption ◽  
Performance Indicators ◽  
Financial Burden ◽  
Operating Time ◽  
High Water ◽  
Swimming Pools ◽  
Two Cities ◽  
Gas Consumption ◽  
Natural Gas Consumption

Indoor swimming pools have high water and energy (electricity and natural gas) consumption levels due to the need to provide suitable thermal comfort conditions (temperature and relative humidity) to its occupants and to counterbalance losses (evaporation, ventilation, etc.). In Portugal, most of the swimming pool facilities belong to the municipalities and their operation represent a considerable financial burden. This work intent to characterize and benchmark the energy (electrical and thermal) and water consumption of five sport complexes with indoor swimming pools, located in two cities of the Centre of Portugal. The four most commonly performance indicators used in the literature were calculated and analyzed according to the operating time and services. Some measures are suggested to enhance the energy efficiency as well as to reduce the consumptions.

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