scholarly journals Influence of Quenching and Subsequent Annealing on the Conductivity and Electromechanical Properties of Na1/2Bi1/2TiO3-BaTiO3

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2149
Author(s):  
Lalitha Kodumudi Venkataraman

Na1/2Bi1/2TiO3-based materials have gained considerable attention for their potential to exhibit giant strain, very-high ionic conductivity comparable to yttria stabilized zirconia or high mechanical quality factor for use in high power ultrasonics. In recent times, quenching Na1/2Bi1/2TiO3-based compositions have been demonstrated to enhance the thermal depolarization temperature, thus increasing the operational temperature limit of these materials in application. This work investigates the role of quenching-induced changes in the defect chemistry on the dielectric, ferroelectric and piezoelectric properties of quenched Na1/2Bi1/2TiO3-BaTiO3. The quenched samples indeed demonstrate an increase in the bulk conductivity. Nevertheless, while subsequent annealing of the quenched samples in air/oxygen atmosphere reverts back the depolarization behaviour to that of a furnace cooled specimen, the bulk conductivity remains majorly unaltered. This implies a weak correlation between the defect chemistry and enhanced thermal stability of the piezoelectric properties and hints towards other mechanisms at play. The minor role of oxygen vacancies is further reinforced by the negligible (10–15%) changes in the mechanical quality factor and hysteresis loss.

1999 ◽  
Vol 67 (10) ◽  
pp. 985-987
Author(s):  
Yoshiyuki ABE ◽  
Taisyu YANAGISAWA ◽  
Kazuyuki KAKEGAWA ◽  
Yoshinori SASAKI

2011 ◽  
Vol 239-242 ◽  
pp. 486-489
Author(s):  
Ling Fang Xu ◽  
Wen Chen ◽  
Jing Zhou ◽  
Chang Ping Yang

Niobium doped Pb(Zr,Ti)O3fiber/epoxy resin 1-3 composites with different ceramic volume fraction of 10-85% were fabricated by filling-casting method. Effects of ceramic volume fraction on electric properties were investigated. For a typical 30% ceramic content composite, the thickness coupling coefficientkt, mechanical quality factorQm, acoustic impedanceZmand anisotropic propertykt/kpwere 0.67, 0.55, 11.03 MRayl and 2.23, respectively.


2015 ◽  
Vol 2015 (DPC) ◽  
pp. 001564-001593
Author(s):  
Chong Li ◽  
Yixuan Wu ◽  
Haoyue Yang ◽  
Luke L. Jenkins ◽  
Robert N. Dean ◽  
...  

The transmissibility reveals two very useful characteristics of a micro-electro-mechanical systems (MEMS) device, the resonant frequency and the mechanical quality factor. Real time knowledge on these two important factors can enhance application performance or avoid potential problems from environmental disturbances due to fabrication tolerances and the resulting operational differences in otherwise identical devices. Expensive laboratory equipment is typically used to measure the transmissibility. However, these test systems are not readily adaptable to field use. Therefore, it is important to be able to measure the transmissibility using a real time technique with a simplified test setup. This study proposes a technique that can compute the transmissibility in real time using a low cost microcontroller. This technique utilizes two laser vibrometers to detect the input and output motions of the proof mass in a MEMS device, which are fed to high speed 500 KHz analog to digital converters (ADC) in the microcontroller. A filtering step is performed to decrease noise. After the sampling and pre-filtering, a Fast Fourier Transform (FFT) is performed to convert the time-domain signals to frequency domain signals. The amplitude of the output signal at each frequency is divided by the amplitude of the corresponding input signal at each frequency to obtain the transmissibility. To overcome the difficulties resulting from measurement and quantization noise, a recursive calculating algorithm and a de-quantization filter are introduced. The recursive calculating process guarantees that the system updates the results continually, which results in a transmissibility plot covering the entire bandwidth. The de-quantization filter considers the validity of the data and performs the transmissibility division step accordingly. A cantilevered structure was chosen as the device-under-test to verify and evaluate this technique. The cantilevered device was attached to an electromechanical shaker system for vibratory stimulation. Two laser vibrometers were used to detect the input and output motion and this data was fed into a microcontroller. The microcontroller was STM32F407, which is 32-bit and 168 MHz controller. The tests demonstrated that this technique can measure the transmissibility and therefore the resonant frequency and mechanical quality factor accurately compared to a professional signal analyzer.


2017 ◽  
Vol 37 (5) ◽  
pp. 2083-2089 ◽  
Author(s):  
Hyoung-Su Han ◽  
Jurij Koruza ◽  
Eric A. Patterson ◽  
Jan Schultheiß ◽  
Emre Erdem ◽  
...  

2000 ◽  
Vol 273 (5-6) ◽  
pp. 310-315 ◽  
Author(s):  
T Uchiyama ◽  
T Tomaru ◽  
D Tatsumi ◽  
S Miyoki ◽  
M Ohashi ◽  
...  

2012 ◽  
Vol 569 ◽  
pp. 35-38
Author(s):  
Tao Zhang ◽  
Min Li ◽  
Ting Liu ◽  
Bin Sun ◽  
Sheng Nan Zhou

The high piezoelectricity and high mechanical quality factor thin films are very important for the fabrications of micro devices. The Pb(Zrx,Ti1-x)O3(PZT) thin films own high piezoelectricity, however, its mechanical quality factor is small. The proper doping of Pb(Mn1/3,Nb2/3)O3(PMnN) will perfectly improve the mechanical quality of the films. However, the doping of PMnN will change the dielectric property of PZT thin films, and so it’s very necessary to investigate the dielectric property of PZT thin films doped with different ratio of PMnN. In this paper, the Pb(Mn1/3,Nb2/3)O3- PbZrO3-PbTiO3(PMnN-PZT) thin films with different doping ratio of PMnN are deposited by the magnetron sputtering method, and the X-ray diffraction is applied to analyze the structure of thin films, and the relative dielectric constant are characterized by the LCR testing system. The results show that the PMnN-PZT thin films with smaller doping ratio than 20% exhibit polycrstal structure, and the dielectric constant of thin films increase with the doping ratio of PMnN sharply, especially the doped PMnN is smaller than 6 mol percent. All the dielectric constants decrease with the testing frequency, and which have little change if the testing frequency is larger than 2.5kHz.


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