scholarly journals A Straightforward Approach to Create Ag/SWCNT Composites

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1956
Author(s):  
Monika Rdest ◽  
Dawid Janas
Keyword(s):  
Electrical Conductivity ◽  
Flexible Electronics ◽  
Specific Conductivity ◽  
Free Standing ◽  
Conductive Materials ◽  
Comparable Level ◽  
Application Potential ◽  
Walled Carbon Nanotubes ◽  
Straightforward Approach ◽  
High Application

Flexible and conductive materials have a high application potential across many parts of modern life. In this work, thin free-standing films from single-walled carbon nanotubes (SWCNTs) were doped with Ag to enhance their electrical conductivity. A facile method to integrate these two materials is described herein. As a consequence, the material exhibited a six-fold boost to the electrical conductivity: an increase from 250 ± 11 S/cm to 1721 ± 125 S/cm. Interestingly, the specific conductivity remained at a comparable level upon doping, so the material was deemed promising in exploitation fields whereweight is of the essence. Furthermore, the material showed good bending characteristics, thereby revealing its applicability in flexible electronics.

scholarly journals Electrically Conductive Networks from Hybrids of Carbon Nanotubes and Graphene Created by Laser Radiation

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1875
Author(s):  
Alexander Yu. Gerasimenko ◽  
Artem V. Kuksin ◽  
Yury P. Shaman ◽  
Evgeny P. Kitsyuk ◽  
Yulia O. Fedorova ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Laser Irradiation ◽  
Flexible Electronics ◽  
Threshold Energy ◽  
Wavelength Region ◽  
Hybrid Nanostructures ◽  
Graphene Sheets ◽  
Electrically Conductive ◽  
Walled Carbon Nanotubes

A technology for the formation of electrically conductive nanostructures from single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), and their hybrids with reduced graphene oxide (rGO) on Si substrate has been developed. Under the action of single pulses of laser irradiation, nanowelding of SWCNT and MWCNT nanotubes with graphene sheets was obtained. Dependences of electromagnetic wave absorption by films of short and long nanotubes with subnanometer and nanometer diameters on wavelength are calculated. It was determined from dependences that absorption maxima of various types of nanotubes are in the wavelength region of about 266 nm. It was found that contact between nanotube and graphene was formed in time up to 400 fs. Formation of networks of SWCNT/MWCNT and their hybrids with rGO at threshold energy densities of 0.3/0.5 J/cm2 is shown. With an increase in energy density above the threshold value, formation of amorphous carbon nanoinclusions on the surface of nanotubes was demonstrated. For all films, except the MWCNT film, an increase in defectiveness after laser irradiation was obtained, which is associated with appearance of C–C bonds with neighboring nanotubes or graphene sheets. CNTs played the role of bridges connecting graphene sheets. Laser-synthesized hybrid nanostructures demonstrated the highest hardness compared to pure nanotubes. Maximum hardness (52.7 GPa) was obtained for MWCNT/rGO topology. Regularity of an increase in electrical conductivity of nanostructures after laser irradiation has been established for films made of all nanomaterials. Hybrid structures of nanotubes and graphene sheets have the highest electrical conductivity compared to networks of pure nanotubes. Maximum electrical conductivity was obtained for MWCNT/rGO hybrid structure (~22.6 kS/m). Networks of nanotubes and CNT/rGO hybrids can be used to form strong electrically conductive interconnections in nanoelectronics, as well as to create components for flexible electronics and bioelectronics, including intelligent wearable devices (IWDs).

scholarly journals Simple Method to Improve Electrical Conductivity of Films Made from Single-Walled Carbon Nanotubes

Nanomaterials ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 1113 ◽  
Author(s):  
Bogumiła Kumanek ◽  
Tomasz Wasiak ◽  
Grzegorz Stando ◽  
Paweł Stando ◽  
Dariusz Łukowiec ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Single Walled Carbon Nanotubes ◽  
Simple Approach ◽  
Sonication Time ◽  
Free Standing ◽  
Simple Method ◽  
New Approach ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Despite the widespread use of sonication for individualization of nanomaterials, its destructive nature is rarely acknowledged. In this study, we demonstrated how exposure of the material to a hostile sound wave environment can be limited by the application of another preprocessing step. Single-walled carbon nanotubes (CNTs) were initially ground in a household coffee grinder, which enabled facile deagglomeration thereof. Such a simple approach enabled us to obtain high-quality CNT dispersion at reduced sonication time. Most importantly, electrical conductivity of free-standing films prepared from these dispersion was improved almost fourfold as compared with unground material eventually reaching 1067 ± 34 S/cm. This work presents a new approach as to how electrical properties of nanocarbon ensembles may be enhanced without the application of doping agents, the presence of which is often ephemeral.

Fabrication and Properties of Multi-Walled Carbon Nanotubes Buckypaper

2015 ◽  
Vol 1108 ◽  
pp. 33-38 ◽  
Author(s):  
W.A.D. Wan Dalina ◽  
M. Mariatti ◽  
Soon Huat Tan ◽  
Z.A. Mohd Ishak ◽  
Abdul Rahman Mohamed
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
High Performance ◽  
Free Standing ◽  
Filtration Process ◽  
Different Types ◽  
Multi Walled Carbon Nanotubes ◽  
Triton X ◽  
Walled Carbon Nanotubes

Free-standing carbon nanotubes (CNTs) film known as buckypaper is a method used to address dispersion problems of CNTs. Unique properties of CNTs made the CNTs buckypaper to be considered as promising reinforcement materials in development of high-performance of nanocomposites. Buckypaper was fabricated by dispersing multi-walled carbon nanotubes (MWCNTs) in two different types of solution namely Triton X-100 and ethanol then followed by filtration process. In this study, MWCNTs loading and pressure used during filtration process were manipulated. The morphology, thermal and electrical conductivity of the buckypaper produced was studied.

scholarly journals Sensing Organophosphorus Compounds with SWCNT Films

Sensors ◽  
2021 ◽  
Vol 21 (14) ◽  
pp. 4915
Author(s):  
Mika Sahlman ◽  
Mari Lundström ◽  
Dawid Janas
Keyword(s):  
Electrical Conductivity ◽  
Organophosphorus Compounds ◽  
Free Standing ◽  
Highly Sensitive ◽  
N Doping ◽  
Order Of Magnitude ◽  
Beneficial Action ◽  
Phosphine Derivatives ◽  
Walled Carbon Nanotubes ◽  
Highly Sensitive Sensors

Promising electrical properties of single-walled carbon nanotubes (SWCNTs) open a spectrum of applications for this material. As the SWCNT electronic characteristics respond well to the presence of various analytes, this makes them highly sensitive sensors. In this contribution, selected organophosphorus compounds were detected by studying their impact on the electronic properties of the nanocarbon network. The goal was to untangle the n-doping mechanism behind the beneficial effect of organic phosphine derivatives on the electrical conductivity of SWCNT networks. The highest sensitivity was obtained in the case of the application of 1,6-Bis(diphenylphoshpino)hexane. Consequently, free-standing SWCNT films experienced a four-fold improvement to the electrical conductivity from 272 ± 21 to 1010 ± 44 S/cm and an order of magnitude increase in the power factor. This was ascribed to the beneficial action of electron-rich phenyl moieties linked with a long alkyl chain, making the dopant interact well with SWCNTs.

scholarly journals Thermoelectric Properties of Thin Films from Sorted Single-Walled Carbon Nanotubes

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3808 ◽  
Author(s):  
Blazej Podlesny ◽  
Bogumila Kumanek ◽  
Angana Borah ◽  
Ryohei Yamaguchi ◽  
Tomohiro Shiraki ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Thermoelectric Properties ◽  
Large Scale ◽  
Single Walled Carbon Nanotubes ◽  
Parent Material ◽  
Free Standing ◽  
Two Phase ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes ◽  
Aqueous Two Phase Extraction

Single-walled carbon nanotubes (SWCNTs) remain one of the most promising materials of our times. One of the goals is to implement semiconducting and metallic SWCNTs in photonics and microelectronics, respectively. In this work, we demonstrated how such materials could be obtained from the parent material by using the aqueous two-phase extraction method (ATPE) at a large scale. We also developed a dedicated process on how to harvest the SWCNTs from the polymer matrices used to form the biphasic system. The technique is beneficial as it isolates SWCNTs with high purity while simultaneously maintaining their surface intact. To validate the utility of the metallic and semiconducting SWCNTs obtained this way, we transformed them into thin free-standing films and characterized their thermoelectric properties.

scholarly journals Ag/VO2/Ag sandwich nylon film for smart thermal management and thermo-responsive electrical conductivity

2021 ◽  
pp. 152808372098654
Author(s):  
Linghui Peng ◽  
Lingling Shen ◽  
Weiren Fan ◽  
Zichuan Liu ◽  
Hongbo Qiu ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Thermal Comfort ◽  
Thermal Management ◽  
Flexible Electronics ◽  
Sandwich Structure ◽  
Outdoor Thermal Comfort ◽  
Ir Radiation ◽  
Indoor Space ◽  
Layer Structures ◽  
Radiation Management

Due to the effects of climate changing, the importance of outdoor thermal comfort has been recognized, and has gained more and more research attentions. Unlike indoor space where air conditioning can be easily implemented, outdoor thermal comfort can only be achieved by localized thermal management. Using textile is a simple but energy-saving way to realize outdoor thermal comfort. Herein, we report the design of a smart thermal management film with the silver/vanadium dioxide/silver (Ag/VO2/Ag) sandwich structure prepared by one-dimensional (1 D) nanowires. It was found that the Ag/VO2/Ag sandwich film was able to lower the temperature by around 10 °C under intense infrared (IR) radiation. In addition, the Ag/VO2/Ag sandwich structure film showed a thermo-responsive electrical conductivity and an outstanding bending stability, due to network structure formed by nanowires. It was experimentally proved that this sandwich structure was superior to other layer structures in IR shielding performance and thermo-responsive electrical conductivity. The as-prepared Ag/VO2/Ag sandwich structure film has great potential for various applications such as wearable devices, flexible electronics, medical monitors and smart IR radiation management.

scholarly journals Strain Sensor Based on Biological Nanomaterial

2021 ◽  
Vol 6 (1) ◽  
pp. 23
Author(s):  
Levan P. Ichkitidze ◽  
Alexander Yu. Gerasimenko ◽  
Dmitry V. Telyshev ◽  
Eugeny P. Kitsyuk ◽  
Vladimir A. Petukhov ◽  
...  
Keyword(s):  
Screen Printing ◽  
Respiratory Diseases ◽  
Specific Conductivity ◽  
Strain Sensor ◽  
Aqueous Dispersion ◽  
Strain Sensors ◽  
Bending Angle ◽  
Multi Walled Carbon Nanotubes ◽  
Number Of Cycles ◽  
Walled Carbon Nanotubes

We investigated a prototype of a strain sensor based on the layers of a bionanomaterial containing bovine serum albumin (BSA matrix) and multi-walled carbon nanotubes (MWCNT filler). The aqueous dispersion of 25 wt.% BSA/0.3 wt.% MWCNT was applied by screen printing onto flexible polyethylene terephthalate substrates. After drying the layers by laser irradiation (~970 nm), various parameters of the layers were controlled, i.e., resistance R, bending angle θ, number of cycles n, and measurement time. One measurement cycle corresponded to a change within the range θ = ±150°. The layers of the BSA/MWCNT bionanomaterial had dimensions of (15 ÷ 20) mm × (8 ÷ 10) mm × (0.5 ÷ 1. 5) µm. The dependences of resistance R on the bending angle θ were similar for all layers at θ = ±30, and the R(θ) curves represented approximate linear dependences (with an error of ≤ 10%); beyond this range, the dependences became nonlinear. The following quantitative values were obtained for the investigated strain sensor: specific conductivity ~1 ÷ 10 S/m, linear strain sensitivity ~160, and bending sensitivity 1.0 ÷ 1.5%/°. These results are high. The examined layers of the bionanomaterial BSA/MWCNT as a strain sensor are of particular interest for medical practice. In particular, strain sensors can be implemented by applying a water dispersion of nanomaterials to human skin using a 3D printer for monitoring movements (arms and blinking) and the detection of signs of pathology (dysphagia, respiratory diseases, angina, etc.).

scholarly journals Enhancement of Electrical Conductivity of Aluminum-Based Nanocomposite Produced by Spark Plasma Sintering

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1150
Author(s):  
Nicolás A. Ulloa-Castillo ◽  
Roberto Hernández-Maya ◽  
Jorge Islas-Urbano ◽  
Oscar Martínez-Romero ◽  
Emmanuel Segura-Cárdenas ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Spark Plasma Sintering ◽  
Experimental Tests ◽  
Powder Morphology ◽  
Plasma Sintering ◽  
Multi Walled Carbon Nanotubes ◽  
Spark Plasma ◽  
Ball Milling Technique ◽  
Walled Carbon Nanotubes

This article focuses on exploring how the electrical conductivity and densification properties of metallic samples made from aluminum (Al) powders reinforced with 0.5 wt % concentration of multi-walled carbon nanotubes (MWCNTs) and consolidated through spark plasma sintering (SPS) process are affected by the carbon nanotubes dispersion and the Al particles morphology. Experimental characterization tests performed by scanning electron microscopy (SEM) and by energy dispersive spectroscopy (EDS) show that the MWCNTs were uniformly ball-milled and dispersed in the Al surface particles, and undesirable phases were not observed in X-ray diffraction measurements. Furthermore, high densification parts and an improvement of about 40% in the electrical conductivity values were confirmed via experimental tests performed on the produced sintered samples. These results elucidate that modifying the powder morphology using the ball-milling technique to bond carbon nanotubes into the Al surface particles aids the ability to obtain highly dense parts with increasing electrical conductivity properties.

scholarly journals Photomodulation of electrical conductivity of a PCBM-doped free-standing lipid bilayer in buffer solution

2019 ◽  
Vol 832 ◽  
pp. 55-58 ◽  
Author(s):  
Kensaku Kanomata ◽  
Takafumi Deguchi ◽  
Teng Ma ◽  
Takumi Haseyama ◽  
Masanori Miura ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Lipid Bilayer ◽  
Buffer Solution ◽  
Free Standing

Electrical Conductivity of Magnesium Oxide/Molten Carbonate Eutectic Coexisting System

2019 ◽  
Vol 74 (9) ◽  
pp. 739-742
Author(s):  
Elena V. Nikolaeva ◽  
Andrey L. Bovet ◽  
Irina D. Zakiryanova
Keyword(s):  
Activation Energy ◽  
Electrical Conductivity ◽  
Magnesium Oxide ◽  
Solid Phase ◽  
Specific Conductivity ◽  
Maxwell Model ◽  
Impedance Method ◽  
Molten Carbonate ◽  
Carbonate Ions ◽  
Alkali Carbonate

AbstractThe electrical conductivity of molten ternary alkali carbonate eutectic, coexisting with MgO particles, has been investigated. The conductivity was measured by the AC impedance method. The apparent activation energy ΔEa increased with the MgO content. This fact can be attributed to the effect of the solid phase. The specific conductivity of those systems could not be described using the Maxwell model over the solvation process of the carbonate ions on the particles of the magnesium oxide.

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