scholarly journals Preparation and Electrochemical Properties of LiNi2/3Co1/6Mn1/6O2 Cathode Material for Lithium-Ion Batteries

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1766
Author(s):  
Meijie Zhu ◽  
Jiangang Li ◽  
Zhibei Liu ◽  
Li Wang ◽  
Yuqiong Kang ◽  
...  

The cathode material LiNi2/3Co1/6Mn1/6O2 with excellent electrochemical performance was prepared successfully by a rheological phase method. The materials obtained were characterized by X-ray diffraction, scanning electron microscopy, electrochemical impedance spectroscopy and charge-discharge tests. The results showed that both calcination temperatures and atmosphere are very important factors affecting the structure and electrochemical performance of LiNi2/3Co1/6Mn1/6O2 material. The sample calcinated at 800 °C under O2 atmosphere displayed well-crystallized particle morphology, a highly ordered layered structure with low defects, and excellent electrochemical performance. In the voltage range of 2.8–4.3 V, it delivered capacity of 188.9 mAh g−1 at 0.2 C and 130.4 mAh g−1 at 5 C, respectively. The capacity retention also reached 93.9% after 50 cycles at 0.5 C. All the results suggest that LiNi2/3Co1/6Mn1/6O2 is a promising cathode material for lithium-ion batteries.

2021 ◽  
Author(s):  
K. Kalaiselvi ◽  
S. Premlatha ◽  
M. Raju ◽  
Paruthimal Kalaignan Guruvaiah

Abstract LiNi1/3Mn1/3Co1/3O2 as a promising cathode material for lithium-ion batteries was synthesized by a sol-gel method using nitrate precursor calcined at 800°C for 10 hours. The crystallite nature of samples is confirmed from X-ray diffraction analysis. SEM and TEM analyses were used to investigate the surface morphology of the prepared samples. It was found that, highly crystalline polyhedral RuO2 nanoparticles are well doped on the surface of pristine LiNi1/3Mn1/3Co1/3O2 with a size of about approximately 200 nm. The chemical composition of the prepared samples was characterized by EDX and XPS analyses. The electrochemical performance of the proposed material was studied by cyclic voltammetry and charge/discharge analyses. The electrode kinetics of the samples was studied by electrochemical impedance spectroscopy. The developed RuO2 doping may provide an effective strategy to design and synthesize the advanced electrode materials for lithium ion batteries. The doping strategy has dramatically increased the capacity retention from 74 % to 90% with a high discharge capacity of 251.2 mAhg− 1. 3 % RuO2-doped LiNi1/3Mn1/3Co1/3O2 cathode materials have showed the similar characteristics of two potential plateaus obtained at 2.8 and 4.2 V compared with un doped electrode cathode material. These results revealed the enhanced performance of RuO2- doped LiNi1/3Mn1/3Co1/3O2 during insertion and extraction of lithium ions compared to pristine material.


2015 ◽  
Vol 44 (40) ◽  
pp. 17579-17586 ◽  
Author(s):  
Yi Cheng ◽  
Kai Feng ◽  
Wei Zhou ◽  
Hongzhang Zhang ◽  
Xianfeng Li ◽  
...  

A promising cathode material Li3V1.97Bi0.03(PO4)3/C for high-power Li rechargeable batteries shows excellent electrochemical performance.


2016 ◽  
Vol 4 (40) ◽  
pp. 15302-15308 ◽  
Author(s):  
Zhigao Luo ◽  
Jiang Zhou ◽  
Lirong Wang ◽  
Guozhao Fang ◽  
Anqiang Pan ◽  
...  

We report the synthesis of a novel 2D hybrid nanosheet constructed by few layered MoSe2 grown on reduced graphene oxide (rGO), which exhibits excellent electrochemical performance as anodes for lithium ion batteries.


2017 ◽  
Vol 5 (14) ◽  
pp. 6522-6531 ◽  
Author(s):  
Yining Ma ◽  
Aibin Huang ◽  
Huaijuan Zhou ◽  
Shidong Ji ◽  
Shuming Zhang ◽  
...  

Various V2O5 hierarchical structures were successfully synthesized via a template-free method and exhibited excellent electrochemical performance.


Sign in / Sign up

Export Citation Format

Share Document