scholarly journals Resins for Frontal Photopolymerization: Combining Depth-Cure and Tunable Mechanical Properties

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 743
Author(s):  
Catharina Ebner ◽  
Julia Mitterer ◽  
Joamin Gonzalez-Gutierrez ◽  
Gisbert Rieß ◽  
Wolfgang Kern
Keyword(s):  
Mechanical Properties ◽  
Optical Density ◽  
Material Properties ◽  
Complex Surface ◽  
Tensile Tests ◽  
Light Induction ◽  
Significant Development ◽  
Temperature Resistance ◽  
Tunable Mechanical Properties ◽  
Long Chain

Photopolymerization has undergone significant development in recent years. It enables fast and easy processing of materials with customized properties and allows precise printing of complex surface geometries. Nevertheless, photopolymerization is mainly applied to cure thin films since the low curing depth limits the fast production of large volumes. Frontal photopolymerization (FPP) is suitable to overcome these limitations so that curing of centimeter-thick (meth)acrylic layers can be accomplished within minutes by light induction only. Prerequisites, however, are the low optical density of the resin and bleaching ability of the photoinitiator. To date, tailored FPP-resins are not commercially available. This study discusses the potential of long-chain polyether dimethacrylates, offering high-temperature resistance and low optical density, as crosslinkers in photobleaching resins and investigates the mechanical properties of photofrontally-cured copolymers. Characteristics ranging from ductile to hard and brittle are observed in tensile tests, demonstrating that deep curing and versatile material properties are achieved with FPP. Analyzed components display uniform polymerization over a depth of four centimeters in Fourier transform infrared spectroscopy and swelling tests.

scholarly journals Experimental Analysis of Welded Rods with a Functionally Graded Material Approach

2020 ◽  
Vol 10 (11) ◽  
pp. 3908 ◽  
Author(s):  
Ayse Basmaci ◽  
Seckin Filiz ◽  
Mümin Şahin
Keyword(s):  
Mechanical Properties ◽  
Functionally Graded Material ◽  
Material Properties ◽  
Friction Welding ◽  
Arc Welding ◽  
Tensile Tests ◽  
Electric Arc ◽  
Functionally Graded ◽  
Graded Material ◽  
Electric Arc Welding

In recent years, with the development of welding methods, using these methods in manufacturing industry and in advanced engineering has become more popular. In this study, mechanical properties of rods obtained by friction welding and electric arc welding are compared. Hence, three specimens with different material properties are manufactured, two of which are welded by friction welding and one of which is welded by electric arc welding. These three specimens are adapted to the ASTM E8-04 standard with the help of a universal lathe. Moreover, the tensile stress values and the elasticity modulus of all these specimens are obtained as a result of tensile tests. Accordingly, the effects of the type of welding and material properties used in manufacturing on the mechanical behavior of the specimens are examined. In addition, specimens taken from the cracked surfaces of the pieces broken from the specimens as a result of the tensile test are examined with SEM (scanning electron microscopy). These examinations reveal the microstructure of the specimens. The elemental distribution data obtained as a result of examinations with SEM and the mechanical property data obtained as a result of tensile tests support each other. Furthermore, effects of a heat affected zone (HAZ) on the mechanical properties of the rod are investigated as a functionally graded material.

scholarly journals A novel technique for the assessment of mechanical properties of vascular tissue

2020 ◽  
Vol 19 (5) ◽  
pp. 1585-1594 ◽  
Author(s):  
Stefan N. Sanders ◽  
Richard G. P. Lopata ◽  
Lambert C. A. van Breemen ◽  
Frans N. van de Vosse ◽  
Marcel C. M. Rutten
Keyword(s):  
Mechanical Properties ◽  
Material Properties ◽  
High Speed ◽  
Vascular Tissue ◽  
Plaque Rupture ◽  
Tensile Tests ◽  
Accurate Estimation ◽  
Uniaxial Tensile ◽  
Inflation Experiment ◽  
Set Up

Abstract Accurate estimation of mechanical properties of the different atherosclerotic plaque constituents is important in assessing plaque rupture risk. The aim of this study was to develop an experimental set-up to assess material properties of vascular tissue, while applying physiological loading and being able to capture heterogeneity. To do so, a ring-inflation experimental set-up was developed in which a transverse slice of an artery was loaded in the radial direction, while the displacement was estimated from images recorded by a high-speed video camera. The performance of the set-up was evaluated using seven rubber samples and validated with uniaxial tensile tests. For four healthy porcine carotid arteries, material properties were estimated using ultrasound strain imaging in whole-vessel-inflation experiments and compared to the properties estimated with the ring-inflation experiment. A 1D axisymmetric finite element model was used to estimate the material parameters from the measured pressures and diameters, using a neo-Hookean and Holzapfel–Gasser–Ogden material model for the rubber and porcine samples, respectively. Reproducible results were obtained with the ring-inflation experiment for both rubber and porcine samples. Similar mean stiffness values were found in the ring-inflation and tensile tests for the rubber samples as 202 kPa and 206 kPa, respectively. Comparable results were obtained in vessel-inflation experiments using ultrasound and the proposed ring-inflation experiment. This inflation set-up is suitable for the assessment of material properties of healthy vascular tissue in vitro. It could also be used as part of a method for the assessment of heterogeneous material properties, such as in atherosclerotic plaques.

scholarly journals Finite Element-Based Simulation of Cooling Rate on the Material Properties of an Automobile Silent Block

2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Burak Öztürk ◽  
Fuat Kara
Keyword(s):  
Mechanical Properties ◽  
Finite Element ◽  
Cooling Rate ◽  
Material Properties ◽  
High Speed ◽  
Tensile Tests ◽  
Isothermal Transformation ◽  
Element Analysis ◽  
Front Suspension ◽  
Safety Coefficient

The aluminum silent block is the part that connects the front suspension mounting and the road wheels. These products are used in high-speed cars and are subject to high engineering stresses. Over time, fractures occur in the connection part of these products due to insufficient strength. These problems are related to production metallurgy, which led to the concept of this study. During mass production, these parts are manufactured using the aluminum extrusion method. In this study, a rapid cooling process using water was applied, with the aim of improving the mechanical properties of the connecting part exposed to high dynamic loads. Samples were taken from the regions of these products which differed in thickness and width, and microhardness and tensile tests were performed for each region. The effects of both the extrusion cooling rate and the regional flash cooling on the material properties were then characterized. As a result of the isothermal transformation, the grain size in the microstructure of the material had shrunk. According to the findings, in this type of production, an average increase in strength of 25% was observed in the parts of the material subjected to maximum stress. The stress and safety coefficient values were found using finite element analysis, and curves were then drawn showing the differences in the safety coefficient values from the different points. As a result of cooperation between university and industry, the material and mechanical properties of an automobile part were improved in this study. This research has shown that, in terms of the accuracy of the results, it is very important to consider the variations in different regions of the product when defining the mechanical properties of any material produced by applying casting, heat treatment, and plastic forming methods.

Influence of ECAR Processing on OFHC Cu Material Properties

2010 ◽  
Vol 667-669 ◽  
pp. 133-137 ◽  
Author(s):  
Tibor Kvačkaj ◽  
Michal Kvačkaj ◽  
Volodymir Stoyka ◽  
Robert Kočiško ◽  
Jana Bidulská ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cross Section ◽  
Material Properties ◽  
Effective Strain ◽  
Cold Drawing ◽  
Tensile Tests ◽  
Experimental Methods ◽  
Effective Normal Stress ◽  
Mathematical Simulations ◽  
Deform 3D

The influence of severe plastic deformation (SPD) on distribution of effective stresses, effective strains and temperatures during equal channel angular rolling (ECAR) process is mathematically simulated. Effect of ECAR processing on substructural and mechanical properties of oxygen free high conductivity (OFHC) Cu material is investigated too. Mathematical simulations in software DEFORM-3D, ECAR technology, tensile tests, EBSD analysis were used as experimental methods. Mathematical simulations of first ECAR pass referred on following results: effective normal stress had low heterogeneity with value 385 MPa, effective strain was distinguished with high heterogeneity in cross section of sample (φ=1,5-3) and temperature in deformation zone achieved value 150 °C. Mechanical properties after cold drawing were: Rp0,2 = 217 MPa, Rm = 260 MPa, Z = 63 % and after sixth ECAR pass were: Rp0,2 = 412 MPa, Rm = 426 MPa, Z = 72 %. From experiments is resulting the stabilization of mechanical properties after fourth ECAR pass were obtained.

Preparation of supramolecular silicone elastomersviahomo- and hetero-assembly

2018 ◽  
Vol 42 (3) ◽  
pp. 1973-1978 ◽  
Author(s):  
Jinfeng Cao ◽  
Linglong Feng ◽  
Shengyu Feng
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Self Assembly ◽  
Silicone Elastomers ◽  
Temperature Resistance ◽  
Tunable Mechanical Properties ◽  
Low Temperature Resistance

Supramolecular silicone elastomers were preparedviaself-assembly and they exhibit ultra-low temperature resistance and tunable mechanical properties.

Cytocompatibility and Material Properties of Poly-carbonate Urethane/Carbon Nanofiber Composites for Neural Applications

2003 ◽  
Vol 774 ◽  
Author(s):  
Janice L. McKenzie ◽  
Michael C. Waid ◽  
Riyi Shi ◽  
Thomas J. Webster
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanofibers ◽  
Material Properties ◽  
Carbon Nanofiber ◽  
Scar Tissue ◽  
Tissue Response ◽  
Positive Interactions ◽  
Weight Percentage ◽  
Poly Carbonate

AbstractCarbon nanofibers possess excellent conductivity properties, which may be beneficial in the design of more effective neural prostheses, however, limited evidence on their cytocompatibility properties exists. The objective of the present in vitro study was to determine cytocompatibility and material properties of formulations containing carbon nanofibers to predict the gliotic scar tissue response. Poly-carbonate urethane was combined with carbon nanofibers in varying weight percentages to provide a supportive matrix with beneficial bulk electrical and mechanical properties. The substrates were tested for mechanical properties and conductivity. Astrocytes (glial scar tissue-forming cells) were seeded onto the substrates for adhesion. Results provided the first evidence that astrocytes preferentially adhered to the composite material that contained the lowest weight percentage of carbon nanofibers. Positive interactions with neurons, and, at the same time, limited astrocyte functions leading to decreased gliotic scar tissue formation are essential for increased neuronal implant efficacy.

scholarly journals 3D Printing of High Viscosity Reinforced Silicone Elastomers

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2239
Author(s):  
Nicholas Rodriguez ◽  
Samantha Ruelas ◽  
Jean-Baptiste Forien ◽  
Nikola Dudukovic ◽  
Josh DeOtte ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Performance ◽  
New Technologies ◽  
Three Dimensional ◽  
High Viscosity ◽  
Layer By Layer ◽  
Silicone Elastomers ◽  
Uv Curable ◽  
Octet Truss ◽  
Tunable Mechanical Properties

Recent advances in additive manufacturing, specifically direct ink writing (DIW) and ink-jetting, have enabled the production of elastomeric silicone parts with deterministic control over the structure, shape, and mechanical properties. These new technologies offer rapid prototyping advantages and find applications in various fields, including biomedical devices, prosthetics, metamaterials, and soft robotics. Stereolithography (SLA) is a complementary approach with the ability to print with finer features and potentially higher throughput. However, all high-performance silicone elastomers are composites of polysiloxane networks reinforced with particulate filler, and consequently, silicone resins tend to have high viscosities (gel- or paste-like), which complicates or completely inhibits the layer-by-layer recoating process central to most SLA technologies. Herein, the design and build of a digital light projection SLA printer suitable for handling high-viscosity resins is demonstrated. Further, a series of UV-curable silicone resins with thiol-ene crosslinking and reinforced by a combination of fumed silica and MQ resins are also described. The resulting silicone elastomers are shown to have tunable mechanical properties, with 100–350% elongation and ultimate tensile strength from 1 to 2.5 MPa. Three-dimensional printed features of 0.4 mm were achieved, and complexity is demonstrated by octet-truss lattices that display negative stiffness.

scholarly journals Improving Rheological and Mechanical Properties of Various Virgin and Recycled Polypropylenes by Blending with Long-Chain Branched Polypropylene

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1137
Author(s):  
Sascha Stanic ◽  
Thomas Koch ◽  
Klaus Schmid ◽  
Simone Knaus ◽  
Vasiliki-Maria Archodoulaki
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Tensile Test ◽  
Reactive Extrusion ◽  
Original Material ◽  
Melt Flow Rate ◽  
Single Screw Extruder ◽  
Pp Blends ◽  
The Impact ◽  
Long Chain

Blends of two long-chain branched polypropylenes (LCB-PP) and five linear polypropylenes (L-PP) were prepared in a single screw extruder at 240 °C. The two LCB-PPs were self-created via reactive extrusion at 180 °C by using dimyristyl peroxydicarbonate (PODIC C126) and dilauroyl peroxide (LP) as peroxides. For blending two virgin and three recycled PPs like coffee caps, yoghurt cups and buckets with different melt flow rate (MFR) values were used. The influence of using blends was assessed by investigating the rheological (dynamic and extensional rheology) and mechanical properties (tensile test and impact tensile test). The dynamic rheology indicated that the molecular weight as well as the molecular weight distribution could be increased or broadened. Also the melt strength behavior could be improved by using the two peroxide modified LCB-PP blends on the basis of PODIC C126 or PEROXAN LP (dilauroyl peroxide). In addition, the mechanical properties were consistently enhanced or at least kept constant compared to the original material. In particular, the impact tensile strength but also the elongation at break could be increased considerably. This study showed that the blending of LCB-PP can increase the investigated properties and represents a promising option, especially when using recycled PP, which demonstrates a real “up-cycling” process.

scholarly journals Synthesis, Properties, and Biodegradability of Thermoplastic Elastomers Made from 2-Methyl-1,3-propanediol, Glutaric Acid and Lactide

Life ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 43
Author(s):  
Lamya Zahir ◽  
Takumitsu Kida ◽  
Ryo Tanaka ◽  
Yuushou Nakayama ◽  
Takeshi Shiono ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Glutaric Acid ◽  
Triblock Copolymers ◽  
Tensile Tests ◽  
Thermoplastic Elastomers ◽  
Proteinase K ◽  
Synthesis Properties

An innovative type of biodegradable thermoplastic elastomers with improved mechanical properties from very common and potentially renewable sources, poly(L-lactide)-b-poly(2-methyl-1,3-propylene glutarate)-b-poly(L-lactide) (PLA-b-PMPG-b-PLA)s, has been developed for the first time. PLA-b-PMPG-b-PLAs were synthesized by polycondensation of 2-methyl-1,3-propanediol and glutaric acid and successive ring-opening polymerization of L-lactide, where PMPG is an amorphous central block with low glass transition temperature and PLA is hard semicrystalline terminal blocks. The copolymers showed glass transition temperature at lower than −40 °C and melting temperature at 130–152 °C. The tensile tests of these copolymers were also performed to evaluate their mechanical properties. The degradation of the copolymers and PMPG by enzymes proteinase K and lipase PS were investigated. Microbial biodegradation in seawater was also performed at 27 °C. The triblock copolymers and PMPG homopolymer were found to show 9–15% biodegradation within 28 days, representing their relatively high biodegradability in seawater. The macromolecular structure of the triblock copolymers of PLA and PMPG can be controlled to tune their mechanical and biodegradation properties, demonstrating their potential use in various applications.

Comprehensive study on mechanical properties of coated biaxial warp-knitted fabrics

2021 ◽  
pp. 073168442110204
Author(s):  
Bin Yang ◽  
Yingying Shang ◽  
Zeliang Yu ◽  
Minger Wu ◽  
Youji Tao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Failure Modes ◽  
Least Squares Method ◽  
Tensile Tests ◽  
Tensile Creep ◽  
Base Layer ◽  
Sustained Load ◽  
Uniaxial Tensile ◽  
Membrane Structures ◽  
Knitted Fabrics

In recent years, coated fabrics have become the major material used in membrane structures. Due to the special structure of base layer and mechanical properties, coated biaxial warp-knitted fabrics are increasingly applied in pneumatic structures. In this article, the mechanical properties of coated biaxial warp-knitted fabrics are investigated comprehensively. First, off-axial tensile tests are carried out in seven in-plane directions: 0°, 15°, 30°, 45°, 60°, 75°, and 90°. Based on the stress–strain relationship, tensile strengths are obtained and failure modes are studied. The adaptability of Tsai–Hill criterion is analyzed. Then, the uniaxial tensile creep test is performed under 24-h sustained load and the creep elongation is calculated. Besides, tearing strengths in warp and weft directions are obtained by tearing tests. Finally, the biaxial tensile tests under five different load ratios of 1:1, 2:1, 1:2, 1:0, and 0:1 are carried out, and the elastic constants and Poisson’s ratio are calculated using the least squares method based on linear orthotropic assumption. Moreover, biaxial specimens under four load ratios of 3:1, 1:3, 5:1, and 1:5 are further tensile tested to verify the adaptability of linear orthotropic model. These experimental data offer a deeper and comprehensive understanding of mechanical properties of coated biaxial warp-knitted fabrics and could be conveniently adopted in structural design.

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