scholarly journals Effect of Chemical Blowing Agent on the PVC Cellular Coating Extrusion

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5752
Author(s):  
Tomasz Garbacz ◽  
Aneta Tor-Świątek ◽  
Tomasz Jachowicz

Depending on the type and application, the coatings of power, electric, telecommunication cables as well as other types of conduits are made of various kinds of polymer plastics. However, most often, because of good mechanical properties and many other advantages, they are first of all made from polyvinyl chlorine (PVC). This paper contains characteristics of the developed cellular extrusion of cable coatings, as well as specification of the blowing agent (BA) used and selected research results of the obtained cellular extrusion product. In technological tests the coating extrusion technological line was used. The material was modified with a new blowing agent of exothermic distribution of process characteristics, which was introduced into the material in quantities from 0.2 to 0.6% wt. The amount of blowing agent used has a direct impact on the density and structure of the received result for the extrusion of modified polymers. The cellular structure of the cellular coatings was presented. The results of the study are thin-walled properties of single- and double-layer cellular outer coatings, forming an outer surface on a steel wire. The research on the structure of manufactured materials, density and the degree of porosity, water and oil absorptivity, mechanical strength is presented.

2011 ◽  
Vol 236-238 ◽  
pp. 241-246 ◽  
Author(s):  
Yuan Bo Huang ◽  
Zhi Feng Zheng ◽  
Hao Feng ◽  
Hui Pan

The resol-type resin was prepared with a high yield from the liquefied products of walnut shell in phenol, which was reacted with formaldehyde under low alkaline conditions. The effects of reaction temperature and time on the yield and viscosity of the resol resin were investigated. Results showed that the optimum resol resinification conditions were a reaction temperature of 80°C and a reaction time of 2 h. The biomass-based resol resin from liquefied products of walnut shell was successfully applied to produce phenolic foam with diisopropyl ether as the blowing agent, Tween 80 as the surfactant and hydrochloric acid as the catalyst, respectively. The obtained foams showed satisfactory mechanical properties and a uniform fine cellular structure.


2012 ◽  
Vol 217-219 ◽  
pp. 517-521 ◽  
Author(s):  
Hong Ling Yi ◽  
Ting Wei ◽  
Lin Heng ◽  
Bai Cun Zheng

In this paper the closed-cell sponge of chloroprene rubber(CR) were produced by foaming agent Azodicarbonamide (AC) and Oxybis (benzene sulfonyl) hydrazide (OBSH). The blend blowing agent AC/OBSH was more effective than the pure AC as it could produce chloroprene foam with greater cell porosity, more uniform and better cell distributions. The CR foam prepared with AC/OBSH had better tensile strength and tear strength than pure AC, but higher Shore C hardness. The Polyethyene glycol (PEG) modified Zinc Oxide (ZnO) could accelerate curing and foam process simultaneously. Increase the content of PEG, CR foam has bigger swell ratio, smaller cell size, and better softness.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3817
Author(s):  
Yingjie Huang ◽  
Wenke Zha ◽  
Yingying Xue ◽  
Zimu Shi

This study focuses on the uniaxial compressive behaviour of thin-walled Al alloy tubes filled with pyramidal lattice material. The mechanical properties of an empty tube, Al pyramidal lattice material, and pyramidal lattice material-filled tube were investigated. The results show that the pyramidal lattice material-filled tubes are stronger and provide greater energy absorption on account of the interaction between the pyramidal lattice material and the surrounding tube.


Author(s):  
Vipul P. Gohil ◽  
Paul K. Canavan ◽  
Hamid Nayeb-Hashemi

This research is aimed to study the variations in the biomechanical behavior of bone and bone tissues with osteoporosis and bone tumors. Osteoporosis and bone tumors reduce the mechanical strength of bone, which creates a greater risk of fracture. In the United States alone, ten million individuals, eight million of whom are women, are estimated to already have osteoporosis, and almost 34 million more are estimated to have low bone mass (osteopenia) placing them at increased risk for osteoporosis. World Health Organization defines osteopenia, as a bone density between one and two and a half standard deviations (SD) below the bone density of a normal young adult. (Osteoporosis is defined as 2.5 SD or more below that reference point.). Together, osteoporosis and osteopenia are expected to affect an estimated 52 million women and men age 50 and older by 2010, and 61 million by 2020. The current medical cost of osteoporosis total is nearly about $18 billion in the U.S. each year. There is a dearth of literature that addresses the effects of osteoporosis on bone tissue properties. Furthermore, there are few studies published related to the effect of bone tumors such as Adamantinoma of long bones, Aneurysmal bone cyst, Hemangioma and others on overall behavior of bone. To understand the variations in bio-mechanical properties of internal tissues of bone with osteoporosis and bone tumor, a 2D finite element (FE) model of bone is developed using ANSYS 9.0 ® (ANSYS Inc., Canonsburg, PA). Trabecular bone is modeled using hexagonal and voronoi cellular structure. This finite element model is subjected to change in BVF (bone volume fraction) and bone architecture caused by osteoporosis. The bone tumor is modeled as finer multi-cellular structure and the effects of its size, location, and property variation of tumor on overall bone behavior are studied. Results from this analysis and comparative data are used to determine behavior of bone and its tissue over different stage of osteoporosis and bone tumor. Results indicate that both bone tumor and osteoporosis significantly change the mechanical properties of the bone. The results show that osteoporosis increases the bone tissue stiffness significantly as BVF reduces. Bone tissue stiffness is found to increase by 80 percent with nearly 55 percent reduction of BVF. The results and methods developed in this research can be implemented to monitor variation in bio-mechanical properties of bone up to tissue level during medication or to determine type and time for need of external support such as bracing.


2021 ◽  
Author(s):  
Wenhuan Zhang ◽  
Zhaoping Deng ◽  
Hongwei Yuan ◽  
Shikai Luo ◽  
Huayin Wen ◽  
...  

AbstractIn this paper, silicone rubber materials with foam/solid alternating multilayered structures were successfully constructed by combining the two methods of multilayered hot-pressing and supercritical carbon dioxide (SCCO2) foaming. The cellular morphology and mechanical properties of the foam/solid alternating multilayered silicone rubber materials were systematically studied. The results show that the growth of the cell was restrained by the solid layer, resulting in a decrease in the cell size. In addition, the introduction of the solid layer effectively improved the mechanical properties of the microcellular silicone rubber foam. The tensile strength and compressive strength of the foam/solid alternating multilayered silicone rubber materials reached 5.39 and 1.08 MPa, which are 46.1% and 237.5% of the pure silicone rubber foam, respectively. Finite element analysis (FEA) was applied and the results indicate that the strength and proportion of the solid layer played important roles in the tensile strength of the foam/solid alternating multilayered silicone rubber materials. Moreover, the small cellular structures in silicone rubber foam can provided a high supporting counterforce during compression, meaning that the microcellular structure of silicone rubber foam improved the compressive property compared to that for the large cellular structure of silicone rubber foam.


2013 ◽  
Vol 746 ◽  
pp. 394-399
Author(s):  
Niwat Anuwongnukroh ◽  
Yosdhorn Chuankrerkkul ◽  
Surachai Dechkunakorn ◽  
Pornkiat Churnjitapirom ◽  
Theeralaksna Suddhasthira

The archwire is generally used in fixed appliances for orthodontic treatment to correct dental malocclusion. However, it is interesting to know whether general purpose stainless steel wire could replace commercial orthodontic archwire in orthodontic practice for economic reasons. The purpose of this study was to determine the bending properties of general purpose stainless steel wire compared with commercial orthodontic stainless steel wires after forming as an archwire for orthodontic use. The samples used in this study were 90 general purpose and 45 commercial (Highland) round stainless steel wires in 0.016, 0.018, and 0.020 sizes (30 general purpose and 15 commercial wires for each size). All 15 general purpose stainless steel wires with different sizes were formed into orthodontic archwire with a Universal Testing Machine. All samples were tested (three-point bending test) for mechanical properties. The results showed no significant difference between general purpose and commercial orthodontic wires in size 0.016 for 0.1 mm offset bending force, 0.2% yield strength, and springback. Although many mechanical properties of general purpose wires differed from commercial wires, their values conformed to other previous studies within the range of clinical acceptance. In conclusion, orthodontic formed general purpose round stainless steel wires had statistically different (p <0.05) mechanical properties from commercial orthodontic stainless steel wires (Highland) but the mechanical properties were acceptable to use in orthodontic treatment.


2021 ◽  
Vol 316 ◽  
pp. 233-239
Author(s):  
Viktor N. Pustovoit ◽  
Yuri V. Dolgachev ◽  
Yu.M. Dombrovskii

During heat treatment of machine parts and tools, besides the usual task of ensuring a high complex of mechanical and operational properties, there is a problem of distortion of products in the process of heat treatment and the need for editing operations (which are carried out manually and require significant labor costs). The known methods do not solve the problem of removing distortion for thin-walled parts of the ring shape completely. This paper shows the technical possibility of using the energy of a constant magnetic field for the "internal" straightening of products during heat treatment in the temperature range of super-plasticity of transformation. The use of special equipment makes it possible to eliminate virtually the distortion of thin-walled parts of the ring shape and to improve their mechanical properties.


2021 ◽  
pp. 174425912110454
Author(s):  
Neal Holcroft

The thermal properties of closed-cell foam insulation display a more complex behaviour than other construction materials due to the properties of the blowing agent captured in their cellular structure. Over time, blowing agent diffuses out from and air into the cellular structure resulting in an increase in thermal conductivity, a process that is temperature dependent. Some blowing agents also condense at temperatures within the in-service range of the insulation, resulting in non-linear temperature dependent relationships. Moreover, diffusion of moisture into the cellular structure increases thermal conductivity. Standards exist to quantify the effect of gas diffusion on thermal conductivity, however only at standard laboratory conditions. In this paper a new test procedure is described that includes calculation methods to determine Temperature Dependent Long-Term Thermal Conductivity (LTTC(T)) functions for closed-cell foam insulation using as a test material, a Medium-Density Spray Polyurethane Foam (MDSPF). Tests results are provided to show the validity of the method and to investigate the effects of both conditioning and mean test temperature on change in thermal conductivity. In addition, testing was conducted to produce a moisture dependent thermal conductivity function. The resulting functions were used in hygrothermal simulations to assess the effect of foam aging, in-service temperature and moisture content on the performance of a typical wall assembly incorporating MDSPF located in four Canadian climate zones. Results show that after 1 year, mean thermal conductivity increased 15%–16% and after 5 years 23%–24%, depending on climate zone. Furthermore, the use of the LTTC(T) function to calculate the wall assembly U-value improved accuracy between 3% and 5%.


Sign in / Sign up

Export Citation Format

Share Document