scholarly journals Effect of Hydrophobic Treatments on Improving the Salt Frost Resistance of Concrete

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5361
Author(s):  
Guo Li ◽  
Chunhua Fan ◽  
Yajun Lv ◽  
Fujun Fan

Hydrophobic treatment is an important method to improve the waterproof properties of concrete. To evaluate the effectiveness of hydrophobic treatments on improving the salt frost resistance of concrete, two representative commercial ordinary water repellent agents of silane and organosilicone emulsion were selected, and concrete specimens with three water/cement ratios were fabricated. After the application of repellent agents on concrete surfaces, accelerated saline (5% MgCl2) freeze-thaw cycles were conducted on the specimens. The mass losses and relative dynamic modulus of elasticity (RDME) of concrete were tested periodically. The contact angles and water absorption ratios of concrete with and without hydrophobic treatments were also tested. Results showed that the repellent agents could substantially enhance the hydrophobicity of concrete and greatly reduce its water absorption. Different repellent agents exerted diverse improvements on concrete hydrophobicity. Meanwhile, the repellent agents could improve concrete resistance against salt scaling and RDME losses to a certain degree, and concrete with strong hydrophobicity showed relatively high salt frost resistance. However, the ordinary water repellent agents cannot achieve the same enhancement on salt frost resistance of concrete as that on the water hydrophobicity of concrete. With saline freezing and thawing cycles, the hydrophobic layer formed by the repellent agents on superficial concrete was destroyed gradually. As a result, the salt frost resistance of concrete from the hydrophobic treatments was ultimately lost.

Author(s):  
Genadijs Sahmenko ◽  
Sandis Aispurs ◽  
Aleksandrs Korjakins

Traditionally, sculptural and decorative elements of building facades are created from mortar mixes based on lime, gypsum or Portland cement. Generally these materials have porous and permeable structure, which determines their accelerated degradation, especially in the aggressive environment of modern cities. High performance cement composites (HPCC) have been considered for production and restoration of sculptural elements in historical buildings. For this purpose, fine-graded, multi-component and highly workable mixes were elaborated. Mix compositions were modified with micro-fillers, plasticizing and stabilizing admixtures, as well as fibers to improve material ductility and control shrinkage cracking. Basic mechanical properties and durability (such as water absorption, frost resistance) were determined and two types of HPCC were compared (>50 MPa: HPCC and >120 MPa: UHPCC). It has been confirmed that cement composite mixes are characterized by self-consolidating effect, high compressive strength, extremely high resistance versus freezing and thawing cycles and low water absorption. Surface quality was evaluated and initial water absorption (tube tests) were performed for laboratory samples and real sculptural elements after 5 years of exploitation. The results confirmed good potential for using HPCC for creating more attractive and durable architectural shapes and façade elements compared to elements made using traditional cement and lime mortar.


Materials ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 1850
Author(s):  
Jinjun Guo ◽  
Ting Guo ◽  
Shiwei Zhang ◽  
Yan Lu

The freezing and thawing of construction concrete is becoming an increasingly important structural challenge. In this study, a shrinkage-compensating concrete based on a double expansive admixture was developed and its frost resistance was assessed through rapid freezing and thawing cycling. The frost resistance of the concrete was derived through the measurement and calculation of the relative dynamic modulus of elasticity (RDME) and the mass loss rate (MLR), and the freezing- and thawing-cycle microstructures and products of concretes with different expansive agents were analyzed using scanning electron microscopy (SEM). It was shown that changes in the properties of the concrete under freezing and thawing could be divided into three stages: slow-damage stage, fast-damage stage, and stable stage. Compared to concrete without an expansive agent, a single-expansive-agent concrete demonstrated excellent frost resistance during the slow-damage stage, but the frost resistance rapidly decreased during the fast-damage age. After 150 cycles (the stable-damage stage), the concrete with a U-type expansive agent (UEA): MgO expansive agent (MEA) mix proportion of 2:1 had the best frost resistance, with RDME and MLR values 17.35% higher and 25.1% lower respectively, than that of an expansive-agent-free concrete. These test results provide a basis for the study of frost resistance in large-scale hydraulic concrete structures.


Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 101
Author(s):  
Danuta Barnat-Hunek ◽  
Jacek Góra ◽  
Marcin K. Widomski

The aim of the research presented in this paper is to evaluate the feasibility of using hydrophobic agents based on organosilicon compounds for surface protection of lightweight concrete modified with waste polystyrene. The experimental part pertains to the physical and mechanical properties of polystyrene-modified lightweight concrete. The concrete samples were prepared with the following ingredients: CEM I 42.5 R cement, recycled polystyrene (0–2 mm), quartz sand (0–2 mm), coarse river aggregate (2–16 mm), and water. Silane and tetramethoxysilane were employed for surface hydrophobization. Concrete with 20% polystyrene exhibits high porosity (25.22%), which is related to an increase in absorptivity (14.75%) compared to the reference concrete. The hydrophobized concrete is characterized by the lowest surface free energy (SFE) value, which is 7 or 11 times lower than the value of reference concrete, depending on the agents. The test on the contact angle (CA) was performed before and after the frost-resistance test (F–T test). Lower SFE translates into lower adhesive properties, higher resistance of the material to the infiltration of water and corrosive compounds, e.g., salts, and higher resistance to freezing and thawing cycles. Silane and tetramethoxysilane coating raised frost resistance by 54–58% compared to the reference samples. This agent reduced absorptivity by 30%. Recycled polystyrene can be successfully used to produce lightweight concrete (LC) with high durability provided by hydrophobic/icephobic coatings.


2013 ◽  
Vol 275-277 ◽  
pp. 1341-1346
Author(s):  
De Cheng Zhang ◽  
Yan Ping Lv ◽  
Zheng Mao Ye

The Hong Run petrochemical oil depot is located in a saline area in the north of Weifang.This area is severe cold in winter and has large temperature span throughout a year. Due to the area's rigorous environmental conditions, concrete with 50 years durability and strength grade of C40 was fabricated with the ordinary Portland cement, high performance superfine mineral powder and high performance pumping agent. Tests using the onsite concrete samples show that concrete mechanical properties meet the design requirements. After 300 freezing and thawing cycles including accelerated freezing thawing method and single-side freezing thawing method, the quality loss rate and relative dynamic modulus both comply with the design requirements. This suggests that the sample concrete has excellent frost resistance ability.


2015 ◽  
Vol 725-726 ◽  
pp. 505-510
Author(s):  
Olga Pertseva ◽  
Sergey Nikolskiy

The task of the project is obtaining the dependence between the relative decreasing of strength and rate of strain and substantiation of the new method for determination of concrete frost resistance. It has been analytically proved that using concrete’s rate of strain ε as a measure of damage, instead of decreasing of tensile strength R, increases freeze-thaw resistance’s accuracy of estimation a lot under otherwise equal conditions by the time of freeze-thaw cycling. Also it has been experimentally shown that ratio of relative decreasing R to ε in direction, perpendicular to compression, is assumed to be independent on values R and ε for a given concrete and on the ways of achieving them during mechanical or freeze-thaw cycling. To determine the dependence δR/R by ε (z) 8 specimens were tested by non-destructive method (RU 2 490 631) and two baths of 50 specimens by basic method (thermo cycling). Results of the non-destructive method are different from results by basic method for 6,3%. Dependence of relative decreasing in strength by rate of strain is near to linear and, therefore, value of z is constant. Taking this into account patented methods for estimation of concrete’s freeze-thaw resistance as per values R and ε received after freezing and thawing cycles of some specimens and their postlimenary failure by linear compression was substantiated.


2011 ◽  
Vol 9 (3) ◽  
pp. 357-366
Author(s):  
Slavko Zdravkovic ◽  
Dragoslav Stojic ◽  
Dragana Turnic

Various factors are taken as the criteria for determining the susceptibility of materials to frost, such as: porosity and water absorption, volume changes, the number of freezing and thawing cycles. Mortars as a mixture of binder, water and sand, after placing and undergoing bonding and solidification processes, represent extremely porous materials, and the same holds for concrete. When the water turns into ice, it changes its volume measure unit from (V?) into Vt = 1.09 V?. If the concrete that has not completed bonding is exposed to frost, the process is likely to be suspended, and later when the warming starts, followed by the thawing of concrete, it will need the repeated vibrating in order to bind again and harden up without the detrimental effects on its strength. However, there are cases of devastating effects of frost on the hardened concrete. All the mentioned strategies should be kept in mind when performing remediation.


2006 ◽  
Vol 302-303 ◽  
pp. 125-130 ◽  
Author(s):  
Ge Yong ◽  
Yuan Jie ◽  
Wen Cui Yang ◽  
Bao Sheng Zhang

Frost resistance of plain concrete and air-entrained concrete subjected to freeze-thaw cycles in fresh water and 5 % and 7 % sodium sulfate solution are investigated in this paper. The test results show that the frost resistance of concrete is different in the different medium. The properties of concrete frozen in 5 % and 7 % sodium solution are different from that in fresh water, and entraining air into concrete properly can increase the frost resistance significantly whether in fresh water or in sulfate solution. Higher strength concrete could resist the degradation of freezing and thawing cycles in water, but some of them failed suddenly in midspan of specimens under the sulfate solution.


2021 ◽  
Vol 22 (10) ◽  
pp. 447-457
Author(s):  
N. P. Prorokova ◽  
◽  
T. Yu. Kumeeva ◽  
I. V. Kholodkov ◽  
V. M. Bouznik ◽  
...  

The control possibility assessment of the water-repellent properties of polyester (PEF) fabric when its hydrophobizing with tetrafluoroethylene (TFE) telomers due to texturing by applying nanosized SiO2 is discussed. It was established that the use of a compound containing SiO2 nanoparticles and TFE telomers for hydrophobization of PEF fabrics led to an increase in roughness of the coatings, however, a decrease in contact angles of fabric and an increase in its water absorption were observed. This is due to an additional increase in hardness of the coating based on TFE telomers, when combined with SiO2 nanoparticles.


Author(s):  
Mucip Tapan ◽  
Celil Engin

In this study, ultra-light weight concrete (ULWC) with heat-insulating properties is produced by using different size expanded perlite aggregates and various admixtures. The compressive strength, 4 point bending strength, freezing and thawing resistance, water absorption, dry unit weight, ultra sound velocities and thermal conductivity of the samples were determined by applying appropriate tests. The effect of different size expanded perlite aggregate on the properties of ULWC were also investigated in this study and it was found that as the expanded perlite aggregate diameter increased, the void volume uniformity, water absorption percentage and freezing-thawing resistance increased while the unit volume weight of ULWC samples, ultrasound speed velocities, thermal conductivity and compressive strength were decreased. The changes in the masses and compressive strength of ULWC samples subjected to freezing and thawing cycles were examined. The compressive strength loss was found to be between 5 % and 47 % while the weight loss was between 1 % and 3.5 % after 15 freezing and thawing cycles. Finally, the effects of the admixtures on the fresh properties of ULWC were examined and it was determined that the use of 4.5 kg of air-entraining material in one cubic meter of concrete mix is the most ideal ratio and the use of more than 0.01 % by volume of polypropylene fiber is caused settlements in fresh concrete mixtures.


2018 ◽  
Vol 212 ◽  
pp. 01013
Author(s):  
Vadim Balabanov ◽  
Victor Baryshok ◽  
Nikita Epishkin

The sharply continental climate of the Irkutsk region is characterized by wide temperature intervals throughout the year. The repeated cyclicity of freezing and thawing of building materials in the water-saturated state influences the change in technical characteristics and the durability of concrete products and structures. The concrete products’ features in such climatic conditions create the need for the production of concretes with improved indicators of physical and mechanical properties. The effect of modifying additives on the technological characteristics of sulfur concrete is established. The effect of all elements of sulfur concrete on its strength and frost resistance. The composition of sulfuric concrete is obtained, which meets all the requirements and also has high strength and increased frost resistance. Formulations with a certain ratio of structural sulfuric concrete mixtures were developed. As a result of the use of technical sulfur in the composition of concrete products, the problem of utilizing annually accumulating reserves of technical sulfur is partially solved. The strength properties of sulfuric concretes easily compete with high-quality brands of concrete, special types of concretes that have in their composition additives.


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