scholarly journals The Transmittance Modulation of ZnO/Cu/ZnO Transparent Conductive Electrodes Prepared on Glass Substrates

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 3916
Author(s):  
Dooho Choi

With the explosive development of optoelectronic devices, the need for high-performance transparent conductive (TCE) electrodes for optoelectronic devices has been increasing accordingly. The two major TCE requirements are (1) visible light average transmittance higher than 80% and (2) sheet resistance lower than 10 Ω/sq. In this study, we investigated the critical role of the top and bottom ZnO thicknesses for the ZnO/Cu/ZnO electrodes prepared on glass substrates. It was shown that the required Cu thickness to meet the conductivity requirement is 8 nm, which was fixed and then the thicknesses of the top and ZnO layers were independently varied to experimentally determine the optimized conditions for optical transparency. The thicknesses of the top and bottom ZnO layers were both found to significantly affect the peak transmittance as well as the average visible light transmittance. The ZnO/Cu/ZnO electrode exhibits peak and average transmittance of 95.4% and 87.4%, excluding the transmittance of glass substrates, along with a sheet resistance of 9.7 Ω/sq, with a corresponding Haacke’s figure of merit (φH=Tave10Rs) of 0.064, which exceeds the reported value for the ZnO/Cu/ZnO electrodes, manifesting the need of experimental optimization in this study.

2020 ◽  
Vol 13 (05) ◽  
pp. 2051031
Author(s):  
Abulikemu Abulizi ◽  
Hujiabudula Maimaitizi ◽  
Dilinuer Talifu ◽  
Yalkunjan Tursun

A photocatalyst of high-performance hierarchical nitrogen-doped MoS2 (N-MoS2) microsphere was fabricated by an in situ hydrothermal method in the presence of cetyltrimethylammonium bromide (CTAB). The as-prepared N-MoS2 microsphere was self-assembled by extremely thin interleaving petals, where CTAB acts as a nucleation site for the formation of the interleaving petals due to the strong interaction between CTA+ and [Formula: see text]. N-MoS2 showed higher N2 fixation ability (101.2 [Formula: see text] mol/g(cat)h) than the non-doped MoS2 under the visible light irradiation, and the improved photocatalytic activity could be ascribed to that the doped N narrows the band gap, and the surface reflecting and scattering effect caused by the hierarchical structure enhance the light adsorption. The trapping experiment of active species was also investigated to evaluate the role of photogenerated electrons in the photocatalytic reaction process. Meanwhile, the possible mechanism for the formation and excellent photocatalytic performance of N-MoS2 microsphere were also presented.


This paper analyses the critical underpinning role of materials research and testing for contemporary engineering and future technologies. It is obvious that measurements, tests and evaluations of materials and components, i.e. materials metrologies, are crucial to provide the information and data needed to optimize the function of engineering structures. The industrial needs and research trends in materials metrology are reviewed, and recent BAM-developments of measuring techniques for high-technology sectors, like high-temperature technology or high-performance ceramics, are presented. Finally, the relevance of an appropriate metrological base for the establishment of industrial standards, agreed codes of practice and the harmonization of test procedures for the international trade of technical products is discussed.


2019 ◽  
Vol 180 ◽  
pp. 97-104 ◽  
Author(s):  
Ho Jae Lee ◽  
Kyu Hyoung Lee ◽  
Liangwei Fu ◽  
GyeongTak Han ◽  
Hyun-Sik Kim ◽  
...  

Author(s):  
George Cameron Fish ◽  
Juan Manuel Moreno-Naranjo ◽  
Andreas Billion ◽  
Daniel Kratzert ◽  
Erwin Hack ◽  
...  

The mechanism of photoinduced symmetry-breaking charge separation in solid cyanine salts at the base of organic photovoltaic and optoelectronic devices is still debated. Here, we employ femtosecond transient absorption spectroscopy...


2019 ◽  
Vol 94 (10) ◽  
pp. 105816 ◽  
Author(s):  
Mohd Taukeer Khan ◽  
I M Ashraf ◽  
F Abdel-Wahab ◽  
M F Sanaa ◽  
M S Awad Al-Juman ◽  
...  

Author(s):  
Yongkuan Li ◽  
Xinxing Liu ◽  
Dan Wen ◽  
Kai Lv ◽  
Gang Zhou ◽  
...  

Manufacturing high-quality zinc oxide (ZnO) devices demands control of the orientation of ZnO materials due to the spontaneous and piezoelectric polarity perpendicular to the c-plane. However, flexible electronic and optoelectronic devices are mostly built on polymers or glass substrates which lack suitable epitaxy seeds for the orientation control. Applying cubic-structure seeds, it was possible to fabricate polar c-plane and nonpolar m-plane aluminium-doped zinc oxide (AZO) films epitaxially on flexible Hastelloy substrates through minimizing the lattice mismatch. The growth is predicted of c-plane and m-plane AZO on cubic buffers with lattice parameters of 3.94–4.63 Å and 5.20–5.60 Å, respectively. The ∼80 nm-thick m-plane AZO film has a resistivity of ∼11.43 ± 0.01 × 10−4 Ω cm, while the c-plane AZO film shows a resistivity of ∼2.68 ± 0.02 × 10−4 Ω cm comparable to commercial indium tin oxide films. An abnormally higher carrier concentration in the c-plane than in the m-plane AZO film results from the electrical polarity along the c-axis. The resistivity of the c-plane AZO film drops to the order of 10−5 Ω cm at 500 K owing to the semiconducting behaviour. Epitaxial AZO films with low resistivities and controllable orientations on flexible substrates offer optimal transparent electrodes and epitaxy seeds for high-performance flexible ZnO devices.


2011 ◽  
Vol 105 (4) ◽  
pp. 1932-1949 ◽  
Author(s):  
John P. Cunningham ◽  
Paul Nuyujukian ◽  
Vikash Gilja ◽  
Cindy A. Chestek ◽  
Stephen I. Ryu ◽  
...  

Neural prosthetic systems seek to improve the lives of severely disabled people by decoding neural activity into useful behavioral commands. These systems and their decoding algorithms are typically developed “offline,” using neural activity previously gathered from a healthy animal, and the decoded movement is then compared with the true movement that accompanied the recorded neural activity. However, this offline design and testing may neglect important features of a real prosthesis, most notably the critical role of feedback control, which enables the user to adjust neural activity while using the prosthesis. We hypothesize that understanding and optimally designing high-performance decoders require an experimental platform where humans are in closed-loop with the various candidate decode systems and algorithms. It remains unexplored the extent to which the subject can, for a particular decode system, algorithm, or parameter, engage feedback and other strategies to improve decode performance. Closed-loop testing may suggest different choices than offline analyses. Here we ask if a healthy human subject, using a closed-loop neural prosthesis driven by synthetic neural activity, can inform system design. We use this online prosthesis simulator (OPS) to optimize “online” decode performance based on a key parameter of a current state-of-the-art decode algorithm, the bin width of a Kalman filter. First, we show that offline and online analyses indeed suggest different parameter choices. Previous literature and our offline analyses agree that neural activity should be analyzed in bins of 100- to 300-ms width. OPS analysis, which incorporates feedback control, suggests that much shorter bin widths (25–50 ms) yield higher decode performance. Second, we confirm this surprising finding using a closed-loop rhesus monkey prosthetic system. These findings illustrate the type of discovery made possible by the OPS, and so we hypothesize that this novel testing approach will help in the design of prosthetic systems that will translate well to human patients.


1988 ◽  
Vol 93 (1-4) ◽  
pp. 792-802 ◽  
Author(s):  
A.W. Nelson ◽  
P.C. Spurdens ◽  
S. Cole ◽  
R.H. Walling ◽  
R.H. Moss ◽  
...  

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