scholarly journals One-Pot Synthesis and High Electrochemical Performance of CuS/Cu1.8S Nanocomposites as Anodes for Lithium-Ion Batteries

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3797 ◽  
Author(s):  
Lin-Hui Wang ◽  
Yan-Kun Dai ◽  
Yu-Feng Qin ◽  
Jun Chen ◽  
En-Long Zhou ◽  
...  

CuS and Cu1.8S have been investigated respectively as anodes of lithium-ion batteries because of their abundant resources, no environment pollution, good electrical conductivity, and a stable discharge voltage plateau. In this work, CuS/Cu1.8S nanocomposites were firstly prepared simultaneously by the one-pot synthesis method at a relatively higher reaction temperature 200 °C. The CuS/Cu1.8S nanocomposites anodes exhibited a high initial discharge capacity, an excellent reversible rate capability, and remarkable cycle stability at a high current density, which could be due to the nano-size of the CuS/Cu1.8S nanocomposites and the assistance of Cu1.8S. The high electrochemical performance of the CuS/Cu1.8S nanocomposites indicated that the CuxS nanomaterials will be a potential lithium-ion battery anode.

2018 ◽  
Vol 2 (11) ◽  
pp. 2526-2531 ◽  
Author(s):  
Jiaqin Yang ◽  
Can Guo ◽  
Jing Zhang ◽  
Lirong Xu

Hierarchical structures are assembled by various building blocks, which can enhance the electrochemical performance with the features of both micromaterials and nanomaterials.


2022 ◽  
Vol 9 ◽  
Author(s):  
Long-Long Ren ◽  
Lin-Hui Wang ◽  
Yu-Feng Qin ◽  
Qiang Li

In order to solve the poor cycle stability and the pulverization of cobalt sulfides electrodes, a series of amorphous and crystalline cobalt sulfides were prepared by one-pot solvothermal synthesis through controlling the reaction temperatures. Compared to the crystalline cobalt sulfide electrodes, the amorphous cobalt sulfide electrodes exhibited superior electrochemical performance. The high initial discharge and charge capacities of 2,132 mAh/g and 1,443 mAh/g at 200 mA/g were obtained. The reversible capacity was 1,245 mAh/g after 200 cycles, which is much higher than the theoretical capacity. The specific capability was 815 mAh/g at 800 mA/g and increased to 1,047 mAh/g when back to 100 mA/g, indicating the excellent rate capability. The outstanding electrochemical performance of the amorphous cobalt sulfide electrodes could result from the unique characteristics of more defects, isotropic nature, and the absence of grain boundaries for amorphous nanostructures, indicating the potential application of amorphous cobalt sulfide as anodes for lithium-ion batteries.


2015 ◽  
Vol 3 (20) ◽  
pp. 10767-10776 ◽  
Author(s):  
Mingxia Gao ◽  
Dingsheng Wang ◽  
Xuqing Zhang ◽  
Hongge Pan ◽  
Yongfeng Liu ◽  
...  

A hybrid micron/submicron-sized Si@FeSiy/SiOx structure is developed by ball-milling of Si and Fe powders via ammonia-assisted one-pot synthesis. It shows superior electrochemical performance as an anode material for lithium-ion batteries.


2017 ◽  
Vol 5 (35) ◽  
pp. 18577-18584 ◽  
Author(s):  
Guangxia Wang ◽  
Yongming Sui ◽  
Meina Zhang ◽  
Man Xu ◽  
Qingxin Zeng ◽  
...  

Copper oxides composited with TiO2 in hollow nanocages exhibit improved electrochemical performance as anode materials for lithium-ion batteries.


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