scholarly journals Parametric Study on Microwave-Assisted Pyrolysis Combined KOH Activation of Oil Palm Male Flowers Derived Nanoporous Carbons

Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2876
Author(s):  
Napat Kaewtrakulchai ◽  
Kajornsak Faungnawakij ◽  
Apiluck Eiad-Ua

Oil palm male flowers (PMFs), an abundant agricultural waste from oil palm plantation in Thailand, have been utilized as an alternative precursor to develop nanoporous carbons (NPCs) via microwave-assisted pyrolysis combined potassium hydroxide (KOH) activation. The influences of relevant processing variables, such as activating agent ratio, microwave power, and activation time on the specific pore characteristics, surface morphology, and surface chemistry of PMFs derived nanoporous carbons (PMFCs) have been investigated to explore the optimum preparation condition. The optimum condition under a microwave radiation power of 700 W, activation holding time of 6 min, and activating agent ratio of 2:1 obtained the PMFC with the highest Brunauer–Emmett–Teller (BET) surface area and total pore volume approximately of 991 m2/g and 0.49 cm3/g, composed of a carbon content of 74.56%. Meanwhile, PMFCs have a highly microporous structure of about 71.12%. Moreover, activating agent ratio and microwave radiation power indicated a significant influence on the surface characteristics of PMFCs. This study revealed the potential of oil palm male flowers for the NPCs’ production via microwave-assisted KOH activation with a short operating-time condition.

2017 ◽  
Vol 41 (24) ◽  
pp. 15373-15383 ◽  
Author(s):  
Chunfeng Du ◽  
Yongtao Xue ◽  
Zhansheng Wu ◽  
Zhilin Wu

In this work, macadamia nut shell-based activated carbon (MNSAC) was prepared using macadamia nut shells (MNS) through KOH activation under microwave radiation.


2016 ◽  
Vol 697 ◽  
pp. 76-79 ◽  
Author(s):  
Wei Si ◽  
Cang Xiong ◽  
Yi Wen Jiang ◽  
Zhi Feng Xing ◽  
Wei Pan

YAG and Yb:YAG transparent ceramic nanopowders for laser crystal were synthesized by microwave-assisted alkoxide hydrolysis precipitation method. The YAG and Yb:YAG nanopowders were characterized by differential thermal analysis and thermo gravimetric analysis (DTA-TG), infrared spectrum (IR), X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) and photoluminescence (PL) spectrum. The results show that the crystallizing temperature of the precursor of YAG and Yb:YAG is about 930 °C. The pure phase YAG and Yb:YAG nanopowders can be obtained at microwave radiation power of 385 W, microwave radiation time of 30 min and sintering temperature of 1100 °C. The average particle size of YAG is about 120 nm. Yb:YAG is uniform sphere and the average sizes is about 100 nm. The intensity of luminescence of Yb:YAG nanopowders decreased with the increasing of microware time. The maximum luminous intensity of the Yb:YAG nanopowders can be obtained when the microwave radiation is 30 min.


2018 ◽  
Vol 37 (1) ◽  
pp. 59-68 ◽  
Author(s):  
Song Cheng ◽  
Libo Zhang ◽  
Shengzhou Zhang ◽  
Hongying Xia ◽  
Jinhui Peng

AbstractThe spent phenolic resin is as raw material for preparing high surface area activated carbon (HSAAC) by microwave-assisted KOH activation. The effects of microwave power, activation duration and impregnation ratio (IR) on the iodine adsorption capability and yield of HSAAC were investigated. The surface characteristics of HSAAC were characterized by nitrogen adsorption isotherms, FTIR, SEM and TEM. The operating variables were optimized utilizing the response surface methodology (RSM) and were identified to be microwave power of 700 W, activation duration of 15 min and IR of 4, corresponding to a yield of 51.25 % and an iodine number of 2,384 mg/g. The pore structure parameters of the HSAAC, i. e., Brunauer–Emmett–Teller (BET) surface area, total pore volume, and average pore diameter were estimated to be 4,269 m2/g, 2.396 ml/g and 2.25 nm, respectively, under optimum conditions. The findings strongly support the feasibility of microwave-assisted KOH activation for preparation of HSAAC from spent phenolic resin.


2018 ◽  
Vol 24 (2) ◽  
pp. 87-96
Author(s):  
Iput Pradiko ◽  
Eko Novandy Ginting ◽  
Nuzul Hijri Darlan ◽  
Winarna Winarna ◽  
Hasril Hasan Siregar

El Niño 2015 is one of the strongest El Niño. Drought stress due to El Niño could affect oil palm performances. This study was conducted to determine rainfall pattern and oil palm performance in Sumatra and Borneo Island during El Niño 2015. Data employed in this study is monthly rainfall data, Southern Oscillation Index (SOI) January-December 2015, andoil palm performances. Pearson correlation between SOI and rainfall data was used to analyze rainfall pattern, while oil palm performances were observed based on morphological conditions. Result shows that southern part of Sumatra and mostly part of Borneo suffer from more dry spell, dry month, and water deficit such as 37-133 days, 3-5 months, and 349-524 mm respectively. Analysis of rainfall pattern shows that Jambi, South Sumatra, Lampung, Central, South, and East Borneo are significantly (r ≥ +0,60) affected by El Niño 2015. Oil palms in southern part of Sumatra and mostly part of Borneo are suffer from drought stressmarked by the emergence of more than two spear fronds, appearing of many male flowers, malformations on bunches, fronds tend to hanging down, and lower fronds tend to dry.


Author(s):  
Muhammad Fakhrul Syukri Abd Aziz ◽  
Nur Fashya Musa ◽  
Ulises Sedran ◽  
Richard Pujro ◽  
Zainul Akmar Zakaria

2021 ◽  
Author(s):  
Chunying Li ◽  
Xianming Meng ◽  
Mengfei Tian ◽  
Shen Li ◽  
Yao Tian ◽  
...  

Abstract Pruning of Juglans mandshurica produces a lot of waste branches which are potentially rich source of juglone. However, they are usually discarded as waste. Given that, the water-in-oil microemulsion was proposed, aiming at developing a novel and efficient microemulsion-based microwave-assisted extraction(MBMAE)method. By which juglone in the Juglans mandshurica waste branches could be obtained. In our experiment, the waste branches powder was added to the MBMAE system. Under the best microemulsion system: (tween 80: n-propanol : n-hexane : water=27% : 13.5% : 4.5% : 55%), the PH of the microemulsion solution of 5.6, microemulsion - Juglans mandshurica branches powder of 20:1 (mL/g), operating temperature of 40°C and operating time of 63 s, operating power of 400 W, the juglone yield was 4.58 mg/g. The results were that the extraction yield applying the MBMAE method were 1.86-fold and 6.65-fold that of microwave-assisted extraction applying ethanol (Ethanol-MAE) and heat reflux extraction by ethanol (Ethanol-HRE), respectively. Obviously, the MBMAE method could be used as an alternative to traditional extraction methods to extract juglone.Statement of Novelty A large number of waste branches from Juglans mandshurica pruning are often discarded as waste. Based on the concept of green development, this work proposes for the first time the extraction and utilization of juglone from the waste branches of Juglans mandshurica. However, a certain problem such as low efficiency, high cost, and complicated operation is existing in traditional extraction method for juglone. Consequently, a special microemulsion system for juglone was established for the first time, and on this basis, the application of MBMAE method to the extraction of juglone was also proposed for the first time. It provides data support for the extraction of juglone from other materials or plants.


Author(s):  
Nissa Nurfajrin Solihat ◽  
Fahriya Puspita Sari ◽  
Lucky Risanto ◽  
Sita Heris Anita ◽  
Fitria Fitria ◽  
...  

2020 ◽  
Vol 17 (2) ◽  
pp. 81
Author(s):  
Van Basten Tambunan ◽  
Bandung Sahari ◽  
Damayanti Buchori ◽  
Purnama Hidayat

<p>The African oil palm weevil,<strong> </strong><em>Elaeidobius kamerunicus</em> is an effective pollinator of oil palm. Each individual palm produces exclusively male or female inflorescence so that the success of pollination depends on the ability of the pollinator to transfer pollen from male to female flowers. The objective of this research was to study the amount of pollen carried by <em>E. kamerunicus</em> between male and female inflorescences (pollen load) and the amount of pollen carried on each part of the weevil’s body (pollen distribution). Fifty each of male and female  <em>E. kamerunicus</em> individuals were collected from male and female flowers on trees in 3 locations: Siantar (North Sumatra), Dramaga (West Java), and Morowali (Central Sulawesi). Data on pollen load and pollen distribution on the weevil’s body were analyzed using <em>ImageJ</em> software. Results show that <em>E. kamerunicus</em> individuals collected more pollen from male flowers than from female flowers. In addition, male insects carried more pollen on their bodies than female insects. Pollen distribution on weevil body parts was highest on the elytra, followed by the thorax, abdomen, legs, and head respectively.</p>


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