scholarly journals Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(N,N-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency

Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2440 ◽  
Author(s):  
Krzysztof Artur Bogdanowicz ◽  
Beata Jewłoszewicz ◽  
Agnieszka Iwan ◽  
Karolina Dysz ◽  
Wojciech Przybyl ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Electrochemical Impedance ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Good Time ◽  
Glass Substrates ◽  
Current Voltage ◽  
One Step

Planar perovskite solar cells were fabricated on F-doped SnO2 (FTO) coated glass substrates, with 4,4’-((1E,1’E)-((1,2,4-thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(N,N-di-p-tolylaniline) (bTAThDaz) as hole transport material. This imine was synthesized in one step reaction, starting from commercially available and relatively inexpensive reagents. Electrochemical, optical, electrical, thermal and structural studies including thermal images and current-voltage measurements of the full solar cell devices characterize the imine in details. HOMO-LUMO of bTAThDaz were investigated by cyclic voltammetry (CV) and energy-resolved electrochemical impedance spectroscopy (ER-EIS) and were found at −5.19 eV and −2.52 eV (CV) and at −5.5 eV and −2.3 eV (ER-EIS). The imine exhibited 5% weight loss at 156 °C. The electrical behavior and photovoltaic performance of the perovskite solar cell was examined for FTO/TiO2/perovskite/bTAThDaz/Ag device architecture. Constructed devices exhibited good time and air stability together with quite small effect of hysteresis. The observed solar conversion efficiency was 14.4%.

Efficient perovskite solar cells with negligible hysteresis achieved by sol–gel-driven spinel nickel cobalt oxide thin films as the hole transport layer

2019 ◽  
Vol 7 (24) ◽  
pp. 7288-7298 ◽  
Author(s):  
Ju Ho Lee ◽  
Young Wook Noh ◽  
In Su Jin ◽  
Sang Hyun Park ◽  
Jae Woong Jung
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Sol Gel ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Critical Issue ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Current Voltage

Current–voltage hysteresis is a critical issue that impacts the photovoltaic performance of perovskite solar cells, and thus, it is imperative to develop high-efficiency perovskite solar cells without hysteresis behavior.

scholarly journals Electrochemical Impedance Spectroscopy Analysis of Hole Transporting Material Free Mesoporous and Planar Perovskite Solar Cells

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1635
Author(s):  
Sumayya M. Abdulrahim ◽  
Zubair Ahmad ◽  
Jolly Bahadra ◽  
Noora J. Al-Thani
Keyword(s):  
Solar Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Large Area ◽  
The Future ◽  
Hole Transporting Material

The future photovoltaic technologies based on perovskite materials are aimed to build low tech, truly economical, easily fabricated, broadly deployable, and trustworthy solar cells. Hole transport material (HTM) free perovskite solar cells (PSCs) are among the most likely architectures which hold a distinctive design and provide a simple way to produce large-area and cost-effective manufacture of PSCs. Notably, in the monolithic scheme of the HTM-free PSCs, all layers can be printed using highly reproducible and morphology-controlled methods, and this design has successfully been demonstrated for industrial-scale fabrication. In this review article, we comprehensively describe the recent advancements in the different types of mesoporous (nanostructured) and planar HTM-free PSCs. In addition, the effect of various nanostructures and mesoporous layers on their performance is discussed using the electrochemical impedance spectroscopy (EIS) technique. We bring together the different perspectives that researchers have developed to interpret and analyze the EIS data of the HTM-free PSCs. Their analysis using the EIS tool, the limitations of these studies, and the future work directions to overcome these limitations to enhance the performance of HTM-free PSCs are comprehensively considered.

scholarly journals CuI/Spiro-OMeTAD Double-Layer Hole Transport Layer to Improve Photovoltaic Performance of Perovskite Solar Cells

Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 978
Author(s):  
Chaoqun Lu ◽  
Weijia Zhang ◽  
Zhaoyi Jiang ◽  
Yulong Zhang ◽  
Cong Ni
Keyword(s):  
Solar Cells ◽  
Double Layer ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Perovskite Layer

The hole transport layer (HTL) is one of the main factors affecting the efficiency and stability of perovskite solar cells (PSCs). However, obtaining HTLs with the desired properties through current preparation techniques remains a challenge. In the present study, we propose a new method which can be used to achieve a double-layer HTL, by inserting a CuI layer between the perovskite layer and Spiro-OMeTAD layer via a solution spin coating process. The CuI layer deposited on the surface of the perovskite film directly covers the rough perovskite surface, covering the surface defects of the perovskite, while a layer of CuI film avoids the defects caused by Spiro-OMetad pinholes. The double-layer HTLs improve roughness and reduce charge recombination of the Spiro-OMeTAD layer, thereby resulting in superior hole extraction capabilities and faster hole mobility. The CuI/Spiro-OMeTAD double-layer HTLs-based devices were prepared in N2 gloveboxes and obtained an optimized PCE (photoelectric conversion efficiency) of 17.44%. Furthermore, their stability was improved due to the barrier effect of the inorganic CuI layer on the entry of air and moisture into the perovskite layer. The results demonstrate that another deposited CuI film is a promising method for realizing high-performance and air-stable PSCs.

On the efficiency of perovskite solar cells with a back reflector: effect of a hole transport material

2021 ◽  
Author(s):  
F. Bonnín-Ripoll ◽  
Ya. B. Martynov ◽  
R. G. Nazmitdinov ◽  
G. Cardona ◽  
R. Pujol-Nadal
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Solar Cell ◽  
Thin Film Solar Cell ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Optimal Thickness ◽  
Back Reflector

A thorough optical + electrical + Lambertian scattering analysis determines the optimal thickness of a perovskite thin-film solar cell revealing its high efficiency with inorganic HTMs.

Surface treatment via Li-bis-(trifluoromethanesulfonyl) imide to eliminate the hysteresis and enhance the efficiency of inverted perovskite solar cells

2017 ◽  
Vol 5 (39) ◽  
pp. 10280-10287 ◽  
Author(s):  
Cong Chen ◽  
Guang Yang ◽  
Junjie Ma ◽  
Xiaolu Zheng ◽  
Zhiliang Chen ◽  
...  
Keyword(s):  
Solar Cells ◽  
Surface Treatment ◽  
Power Conversion ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Long Term Stability

We showed that perovskite solar cells employing Li-treated NiOxas a hole transport layer demonstrated excellent photovoltaic performance, and obtained a power conversion efficiency of up to 18.03%. In addition, the device possessed good long-term stability.

scholarly journals Analysis of the role of hole transport layer materials to the performance of perovskite solar cell

2018 ◽  
Vol 67 ◽  
pp. 01021 ◽  
Author(s):  
Istighfari Dzikri ◽  
Michael Hariadi ◽  
Retno Wigajatri Purnamaningsih ◽  
Nji Raden Poespawati
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Open Circuit ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer

Research in solar cells is needed to maximize Indonesia’s vast solar potential that can reach up to 207.898 MW with an average radiation of 4.8 kWh/m2/day. Organometallic perovskite solar cells (PSCs) have gained immense attention due to their rapid increase in efficiency and compatibility with low-cost fabrication methods. Understanding the role of hole transport layer is very important to obtain highly efficient PSCs. In this work, we studied the effect of Hole Transport Layer (HTL) to the performance of perovskite solar cell. The devices with HTL exhibit substantial increase in power conversion efficiency, open circuit voltage and short circuit current compared to the device without HTL. The best performing device is PSC with CuSCN as HTL layer, namely Voc of 0.24, Isc of 1.79 mA, 0.27 FF and efficiency of 0.09%.

scholarly journals One-step facile synthesis of a simple carbazole-cored hole transport material for high-performance perovskite solar cells

Nano Energy ◽  
2017 ◽  
Vol 40 ◽  
pp. 163-169 ◽  
Author(s):  
Xinxing Yin ◽  
Lei Guan ◽  
Jiangsheng Yu ◽  
Dewei Zhao ◽  
Changlei Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Facile Synthesis ◽  
One Step

Perovskite solar cells with a DMSO-treated PEDOT:PSS hole transport layer exhibit higher photovoltaic performance and enhanced durability

Nanoscale ◽  
2017 ◽  
Vol 9 (12) ◽  
pp. 4236-4243 ◽  
Author(s):  
Di Huang ◽  
Tenghooi Goh ◽  
Jaemin Kong ◽  
Yifan Zheng ◽  
Suling Zhao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer

scholarly journals Numerical simulation of perovskite solar cell with different material as electron transport layer using SCAPS-1D Software

2021 ◽  
Vol 24 (3) ◽  
pp. 341-347
Author(s):  
K. Bhavsar ◽  
◽  
P.B. Lapsiwala ◽  
Keyword(s):  
Numerical Simulation ◽  
Solar Cells ◽  
Solar Cell ◽  
Electron Transport ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Transport Layer ◽  
Electron Transport Layer

Perovskite solar cells have become a hot topic in the solar energy device area due to high efficiency and low cost photovoltaic technology. However, their function is limited by expensive hole transport material (HTM) and high temperature process electron transport material (ETM) layer is common device structure. Numerical simulation is a crucial technique in deeply understanding the operational mechanisms of solar cells and structure optimization for different devices. In this paper, device modelling for different perovskite solar cell has been performed for different ETM layer, namely: TiO2, ZnO, SnO2, PCBM (phenyl-C61-butyric acid methyl ester), CdZnS, C60, IGZO (indium gallium zinc oxide), WS2 and CdS and effect of band gap upon the power conversion efficiency of device as well as effect of absorber thickness have been examined. The SCAPS 1D (Solar Cell Capacitance Simulator) has been a tool used for numerical simulation of these devices.

scholarly journals Dibenzo-Tetraphenyl Diindeno as Hole Transport Layer for Perovskite Solar Cells Fabrication

2020 ◽  
Author(s):  
Meenakshi Pegu ◽  
Laura Calio ◽  
Mehrad Ahmadpour ◽  
Horst-Günter Rubahn ◽  
Samrana Kazim ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Band Gap ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Promising Alternative ◽  
Building Integrated Photovoltaics ◽  
Polycyclic Aromatic

<p>Semi-transparent perovskite solar cells have the competitive edge of being employed for building integrated photovoltaics due to their aesthetic benefits as light harvesting windows / facades. Perovskites have received considerable attention in recent years as a thin film photovoltaic alternative, that can also be tweaked for its transparency, evolving from potentially high bandgaps that are suited for semi-transparent solar cell fabrication. Due to the existing trade of between the efficiency and transparency of a perovskite solar cell, tuning the band gap can address this by making a bridge between the aforementioned parameters. We report our findings on the use of a wide-bandgap perovskite MAPbBr<sub>3</sub>, with a rational energetic level hole transport materials based on polycyclic aromatic hydrocarbon molecules that can be a promising alternative class of p-type material. In the present work, DBP (Dibenzo{[f,f' ]-4,4',7,7'-tetraphenyl}diindeno[1,2,3-cd :1',2',3'-lm]perylene, was evaluated with high band gap as well as with (FAPbI<sub>3</sub>)<sub>0.85</sub>(MAPbBr<sub>3</sub>)<sub>0.15 </sub>perovskites<sub> </sub>for the fabrication of solar cell. DBP based solar cells yielded competitive power conversion efficiencies as compared to classical HTMs.</p>

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