scholarly journals NiO/Carbon Aerogel Microspheres with Plum-Pudding Structure as Anode Materials for Lithium Ion Batteries

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2363
Author(s):  
Renqing Guo ◽  
Xiaohua Huang ◽  
Yan Lin ◽  
Yiqi Cao
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Sol Gel ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Carbon Aerogel ◽  
Cycling Performance ◽  
Initial Charge

To enhance the electrochemical performance of nickel oxide as anode materials for lithium ion batteries, NiO/carbon aerogel microspheres with a plum-pudding structure were designed and prepared by a sol-gel technique followed by two calcination processes under different atmospheres. Carbon aerogel microspheres (pudding) can act as a buffering and conductive matrix to enhance the structural stability and conductivity of the embedded NiO particles (plums), which are quite advantageous to the cycling performance and rate capability. Consequently, NiO/carbon aerogel microspheres with a plum-pudding structure deliver an initial charge capacity of 808 mAh g−1 and a reversible capacity retention of 85% after 100 cycles. The enhancement in electrochemical performance relative to pure NiO microspheres suggests that the design of a plum-pudding structure is quite effective.

Synthesis and Electrochemical Performance of SnO2/Graphene Hybrid Anode for Lithium Ion Batteries

2013 ◽  
Vol 1540 ◽  
Author(s):  
Chia-Yi Lin ◽  
Chien-Te Hsieh ◽  
Ruey-Shin Juang
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Homogeneous Distribution

ABSTRACTAn efficient microwave-assisted polyol (MP) approach is report to prepare SnO2/graphene hybrid as an anode material for lithium ion batteries. The key factor to this MP method is to start with uniform graphene oxide (GO) suspension, in which a large amount of surface oxygenate groups ensures homogeneous distribution of the SnO2 nanoparticles onto the GO sheets under the microwave irradiation. The period for the microwave heating only takes 10 min. The obtained SnO2/graphene hybrid anode possesses a reversible capacity of 967 mAh g-1 at 0.1 C and a high Coulombic efficiency of 80.5% at the first cycle. The cycling performance and the rate capability of the hybrid anode are enhanced in comparison with that of the bare graphene anode. This improvement of electrochemical performance can be attributed to the formation of a 3-dimensional framework. Accordingly, this study provides an economical MP route for the fabrication of SnO2/graphene hybrid as an anode material for high-performance Li-ion batteries.

Design and synthesis of a 3-D hierarchical molybdenum dioxide/nickel/carbon structured composite with superior cycling performance for lithium ion batteries

2016 ◽  
Vol 4 (2) ◽  
pp. 605-611 ◽  
Author(s):  
Qing Xia ◽  
Hailei Zhao ◽  
Zhihong Du ◽  
Zijia Zhang ◽  
Shanming Li ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Molybdenum Dioxide ◽  
Promising Candidate ◽  
Design And Synthesis ◽  
High Reversible Capacity

3-D hierarchical MoO2/Ni/C, with high reversible capacity and excellent rate capability, is a promising candidate for anode materials of lithium ion batteries.

A comparative study of ordered mesoporous carbons with different pore structures as anode materials for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (53) ◽  
pp. 42922-42930 ◽  
Author(s):  
Diganta Saikia ◽  
Tzu-Hua Wang ◽  
Chieh-Ju Chou ◽  
Jason Fang ◽  
Li-Duan Tsai ◽  
...  
Keyword(s):  
Comparative Study ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Stability ◽  
Mesoporous Carbons ◽  
Ordered Mesoporous Carbons ◽  
Ordered Mesoporous

Ordered mesoporous carbons CMK-3 and CMK-8 with different mesostructures are evaluated as anode materials for lithium-ion batteries. CMK-8 possesses higher reversible capacity, better cycling stability and rate capability than CMK-3.

Building sponge-like robust architectures of CNT–graphene–Si composites with enhanced rate and cycling performance for lithium-ion batteries

2015 ◽  
Vol 3 (7) ◽  
pp. 3962-3967 ◽  
Author(s):  
Xiaolei Wang ◽  
Ge Li ◽  
Fathy M. Hassan ◽  
Matthew Li ◽  
Kun Feng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycling Stability ◽  
Great Promise ◽  
Practical Applications ◽  
Excellent Cycling Stability

High-performance robust CNT–graphene–Si composites are designed as anode materials with enhanced rate capability and excellent cycling stability for lithium-ion batteries. Such an improvement is mainly attributed to the robust sponge-like architecture, which holds great promise in future practical applications.

Electrochemical Performance Cr Doped Spinel LiMn2O4 Cathode for Lithium Ion Batteries

2014 ◽  
Vol 636 ◽  
pp. 49-53
Author(s):  
Si Qi Wen ◽  
Liang Chao Gao ◽  
Jia Li Wang ◽  
Lei Zhang ◽  
Zhi Cheng Yang ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Electrochemical Impedance ◽  
Sol Gel ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycle Performance ◽  
X Ray Diffraction ◽  
X Ray ◽  
Discharge Test

To improve the cycle performance of spinel LiMn2O4as the cathode of 4 V class lithium ion batteries, spinel were successfully prepared using the sol-gel method. The dependence of the physicochemical properties of the spinel LiCrxMn2-xO4(x=0,0.05,0.1,0.2,0.3,0.4) powders powder has been extensively investigated by using X-ray diffraction (XRD), scanning electron microscope (SEM), charge-discharge test and electrochemical impedance spectroscopy (EIS). The results show that as Mn is replaced by Cr, the initial capacity decreases, but the cycling performance improves due to stabilization of spinel structure. Of all, the LiCr0.2Mn1.8O4has best electrochemical performance, 107.6 mAhg-1discharge capacity, 96.1% of the retention after 50 cycles.

Enhanced electrochemical performance of hierarchical CoFe2O4/MnO2/C nanotubes as anode materials for lithium-ion batteries

2015 ◽  
Vol 3 (23) ◽  
pp. 12328-12333 ◽  
Author(s):  
Junjie Zhou ◽  
Ting Yang ◽  
Minglei Mao ◽  
Weiji Ren ◽  
Qiuhong Li
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Facile Preparation ◽  
Enhanced Electrochemical Performance ◽  
C Nanotubes

We report a facile preparation of MnO2 nanosheet-coated CoFe2O4 nanofibers containing carbon for lithium ion batteries. The CoFe2O4/MnO2/C nanotubes exhibit a reversible capacity of 713.6 mA h g−1 at 100 mA g−1 after 250 cycles.

Hierarchical NiCoO2 nanosheets supported on amorphous carbon nanotubes for high-capacity lithium-ion batteries with a long cycle life

2014 ◽  
Vol 2 (32) ◽  
pp. 13069-13074 ◽  
Author(s):  
Xin Xu ◽  
Bitao Dong ◽  
Shujiang Ding ◽  
Chunhui Xiao ◽  
Demei Yu
Keyword(s):  
Carbon Nanotubes ◽  
Lithium Ion Batteries ◽  
Amorphous Carbon ◽  
Anode Materials ◽  
High Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycle Life ◽  
Long Cycle Life

NiCoO2 nanosheets@amorphous CNT composites show enhanced cycling performance and rate capability as anode materials for lithium-ion batteries.

High-Performance Anode Materials with Superior Structure of Fe3O4/FeS/rGO Composite for Lithium Ion Batteries

NANO ◽  
2020 ◽  
Vol 15 (10) ◽  
pp. 2050128 ◽  
Author(s):  
Ruirui Gao ◽  
Suqin Wang ◽  
Zhaoxiu Xu ◽  
Hongbo Li ◽  
Shuiliang Chen ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
High Performance ◽  
Composite Electrode ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Charging And Discharging Processes ◽  
New Perspective

In this work, we developed a simple one-step hydrothermal method to successfully prepare Fe3O4/FeS-reduced graphene oxide (Fe3O4/FeS/rGO) composite directly, which is a novel Lithium-ion batteries (LIBs) anode material. The characterization of Fe3O4/FeS/rGO composite demonstrates that octahedral Fe3O4/FeS particles are uniformly deposited on the rGO, leading to a strong synergy between them. The excellent structural design can make Fe3O4/FeS/rGO composite to have higher reversible capacity (744.7[Formula: see text]mAh/g at 0.1[Formula: see text]C after 50 cycles), excellent cycling performance and superior rate capability. This outstanding electrochemical behavior can be attributed to the conductivity network of rGO, which improves the composite electrode conductivity, facilitates the diffusion and transfer of ions and prevents the aggregation and pulverization of Fe3O4/FeS particles during the charging and discharging processes. Moreover, the Fe3O4/FeS/rGO electrode surface is covered with a thin solid-electrolyte interface (SEI) film and the octahedral structure of Fe3O4/FeS particles is still clearly visible, which indicates that composite electrode has excellent interface stability. We believe that the design of this composite structure will provide a new perspective for the further study of other transition metal oxides for LIBs.

Polyoxometalate-based metallogels as anode materials for lithium ion batteries

2019 ◽  
Vol 48 (28) ◽  
pp. 10422-10426 ◽  
Author(s):  
Xing Meng ◽  
Hai-Ning Wang ◽  
Yan-Hong Zou ◽  
Lu-Song Wang ◽  
Zi-Yan Zhou
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
High Rate ◽  
High Rate Capability ◽  
High Reversible Capacity ◽  
First Time ◽  
Good Cycling Stability

POM-based metallogels are employed as anode materials for the first time, which exhibit high reversible capacity, high rate capability, and good cycling stability.

Structure and electrochemical properties of Sm-doped Li4Ti5O12 as anode material for lithium-ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15492-15500 ◽  
Author(s):  
Zhanyu Li ◽  
Jianling Li ◽  
Yuguang Zhao ◽  
Kai Yang ◽  
Fei Gao ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Discharge Capacity ◽  
Anode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance

Sm doping has a great impact on discharge capacity, rate capability and cycling performance of LTO anode materials for lithium-ion batteries.

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