scholarly journals Spin Coating and Micro-Patterning Optimization of Composite Thin Films Based on PVDF

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1342 ◽  
Author(s):  
Anh Ngoc Nguyen ◽  
Jeanne Solard ◽  
Huyen Thi Thanh Nong ◽  
Chirine Ben Osman ◽  
Andres Gomez ◽  
...  

We optimize the elaboration of very thin film of poly(vinylidene fluoride) (PVDF) polymer presenting a well-controlled thickness, roughness, and nano-inclusions amount. We focused our effort on the spin coating elaboration technique which is easy to transfer to an industrial process. We show that it is possible to obtain continuous and smooth thin films with mean thicknesses of 90 nm by properly adjusting the concentration and the viscosity of the PVDF solution as well as the spin rate and the substrate temperature of the elaboration process. The electro-active phase content versus the magnetic and structural properties of the composite films is reported and fully discussed. Last but not least, micro-patterning optical lithography combined with plasma etching has been used to obtain well-defined one-dimensional micro-stripes as well as squared-rings, demonstrating the easy-to-transfer silicon technology to polymer-based devices.

2001 ◽  
Vol 665 ◽  
Author(s):  
Feng Xia ◽  
H.S. Xu ◽  
Babak Razavi ◽  
Q. M. Zhang

ABSTRACTFerroelectric polymer thin films are attractive for a wide range of applications such as MEMS, IR sensors, and memory devices. We present the results of a recent investigation on the thickness dependence of the ferroelectric properties of poly(vinylidene fluoridetrifluoroethylene) copolymer spin cast films on electroded Si substrate. We show that as the film thickness is reduced, there exist two thickness regions. For films at thickness above 100 nm, the thickness dependence of the ferroelectric properties can be attributed to the interface effect. However, for thinner films, there is a large change in the ferroelectric properties such as the polarization level, the coercive field, and polarization switching speed, which is related to the large drop of the crystallinity in the ultrathin film region (below 100 nm). The results from Xray, dielectric measurement, and AFM all indicate that there is a threshold thickness at about 100 nm below which the crystallinity in the film reduces abruptly.


Author(s):  
Saurav Arora

Until few years, the so-called implausible science, homeopathy, was on the verge of being rejected on conventional physicochemical grounds. The mere selection of ultrahigh dilutions (UHD) (homeopathic potencies) for experimentation by mainstream scientists seemed impossible, but the curiosity to explore the science behind homeopathy kept igniting intellectual alma mater who subjected homeopathy to laboratories and test tubes, to know beyond its clinical application. Still, there exist a huge gap and a challenge to convince a conventional scientist to go beyond his domains and look for something which is apparently invisible (beyond Avogadro). But gradually we are overcoming this dogma and exploring the finer aspects and applications of UHDs. Much research has been undertaken, at least, to protect the identity of UHDs, and we are now verge of proving the plausibility of homeopathy from every aspect. This issue of International Journal of High Dilution Research features two interesting articles on nature of UHDs and their unconventional application. The first article by NC Sukul et al aimed to decipher the nature of the water structure of UHDs of two commonly used homeopathic drugs Natrum muriaticum and Sulphur by Laser Raman Spectroscopy. This work is in the series undertaken by the group, who earlier experimented using Nuclear Magnetic Resonance; Electronic, Vibrational and Raman spectroscopy to shown differences in UHDs of various drugs. The present experiment could differentiate the intensities (potencies) of Nat-m and Sulph when compared to their controls, on the basis of hydrogen bond strength and free OH groups. The second article by Nandy et al proposes a new dimension to the application of UHD. In an interesting manner, the author used UHDs of Ferrum metallicum and Zincum oxidatum to improve the electrical properties of the electroactive Poly (vinylidene fluoride-hexafluoropropylene) (PVDF-HFP). The PVDF-HFP composite films were synthesized in their usual way, but an incorporation of Ferrum and Zinc-o could make the film as homeo-PVDF-composite. This enhancement of the electrical properties and are possibly due to the presence of nanoparticle, as hypothesized by the group. The nature and application of UHDs are promising but challenging areas, which can only be validated through extensive research and validation. The realm of UHDs is expanding, and the day is not far when plausibility of homeopathy would be proved from every aspect, but at the same time we should also keep the momentum of research at pace in clinical research too!


2010 ◽  
Vol 519 (4) ◽  
pp. 1441-1444 ◽  
Author(s):  
Sharon Roslyn Oh ◽  
Kui Yao ◽  
Choi Lan Chow ◽  
Francis Eng Hock Tay

RSC Advances ◽  
2018 ◽  
Vol 8 (50) ◽  
pp. 28825-28835 ◽  
Author(s):  
Beom-Jun Ju ◽  
Ji-Hyun Oh ◽  
Changsang Yun ◽  
Chung Hee Park

Flexible and breathable electrospun PVDF web with both piezoelectricity and superhydrophobicity for smart textiles was fabricated by a simple process, plasma etching and water immersion, without any additional coatings.


2020 ◽  
Vol 52 (12) ◽  
pp. 1150-1155
Author(s):  
Sabine Apelt ◽  
Susanne Höhne ◽  
Petra Uhlmann ◽  
Ute Bergmann

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