scholarly journals Dual and Multi-Emission Hybrid Micelles Realized through Coordination-Driven Self-Assembly

Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 440
Author(s):  
Youxiong Zheng ◽  
Yan Tang ◽  
Jianwei Yu ◽  
Lan Xie ◽  
Huiyou Dong ◽  
...  

Building novel functional nanomaterials with a polymer is one of the most dynamic research fields at present. Here, three amphiphilic block copolymers of 8-hydroxyquinoline derivative motifs (MQ) with excellent coordination function were synthesized by Reversible Addition-Fragmentation Chain Transfer Polymerization (RAFT) polymerization. The coordination micelles were prepared through the self-assembly process, which the MQ motifs were dispersed in the hydrophobic polystyrene (PSt) blocks and hydrophilic Poly(N-isopropylacrylamide (PNIPAM)) blocks, respectively. The dual-emission micelles including the intrinsic red light emission of quantum dots (QDs) and the coordination green light emission of Zn2+-MQ complexes were built by introducing the CdSe/ZnS and CdTe/ZnS QDs in the core and shell precisely in the coordination micelles through the coordination-driven self-assembly process. Furthermore, based on the principle of three primary colors that produce white light emission, vinyl carbazole units (Polyvinyl Carbazole, PVK) with blue light emission were introduced into the hydrophilic PNIPAM blocks to construct the white light micelles that possess special multi-emission properties in which the intrinsic red light emission of QDs, the coordination green light of Zn2+-MQ complexes, and the blue light emission of PVK were synergized. The dual and multi-emission hybrid micelles have great application prospects in ratiometric fluorescent probes and biomarkers.

2021 ◽  
Vol 8 ◽  
Author(s):  
Peian Zhang ◽  
Suwen Lu ◽  
Zhongjie Liu ◽  
Ting Zheng ◽  
Tianyu Dong ◽  
...  

Different light qualities have various impacts on the formation of fruit quality. The present study explored the influence of different visible light spectra (red, green, blue, and white) on the formation of quality traits and their metabolic pathways in grape berries. We found that blue light and red light had different effects on the berries. Compared with white light, blue light significantly increased the anthocyanins (malvidin-3-O-glucoside and peonidin-3-O-glucoside), volatile substances (alcohols and phenols), and soluble sugars (glucose and fructose), reduced the organic acids (citric acid and malic acid), whereas red light achieved the opposite effect. Transcriptomics and metabolomics analyses revealed that 2707, 2547, 2145, and 2583 differentially expressed genes (DEGs) and (221, 19), (254, 22), (189, 17), and (234, 80) significantly changed metabolites (SCMs) were filtered in the dark vs. blue light, green light, red light, and white light, respectively. According to Gene Ontology (GO) and Kyoto Encyclopedia of Genes and Genomes (KEGG) analyses, most of the DEGs identified were involved in photosynthesis and biosynthesis of flavonoids and flavonols. Using weighted gene co-expression network analysis (WGCNA) of 23410 highly expressed genes, two modules significantly related to anthocyanins and soluble sugars were screened out. The anthocyanins accumulation is significantly associated with increased expression of transcription factors (VvHY5, VvMYB90, VvMYB86) and anthocyanin structural genes (VvC4H, Vv4CL, VvCHS3, VvCHI1, VvCHI2, VvDFR), while significantly negatively correlated with VvPIF4. VvISA1, VvISA2, VvAMY1, VvCWINV, VvβGLU12, and VvFK12 were all related to starch and sucrose metabolism. These findings help elucidate the characteristics of different light qualities on the formation of plant traits and can inform the use of supplemental light in the field and after harvest to improve the overall quality of fruit.


1992 ◽  
Vol 283 ◽  
Author(s):  
X. Y. Hou ◽  
G. Shi ◽  
W. Wang ◽  
F. L. Zhang ◽  
P. H. Hao ◽  
...  

ABSTRACTThrough a post treatment of light emitting porous silicon in boilingwater, a large blue shift of its photoluminescence (PL) spectrum hasbeen observed and a stable blue-green light emission at the peak wavelength down to 500 nm is achieved. The effect of boiling water treatment is suggested to be a kind of oxidation, which could reduce thesize of the Si column, fill up some micropores and strengthen the Siskeleton. The photoluminescence microscopic observation shows that the surface of blue light emitting porous silicon is composed of manysmall uniformly light-emitting domains at the size of several tens of μm. Fourier transform infrared reflection (FTIR) measurements show that the formation of Si-H bonds is not responsible for the visible luminescence in the very thin Si wires.


2012 ◽  
Vol 64 (3) ◽  
pp. 13-18 ◽  
Author(s):  
Marek Jerzy ◽  
Piotr Zakrzewski ◽  
Anita Schroeter-Zakrzewska

The pot cultivar of <i>Chrysanthemum</i> × <i>grandiflorum</i> 'Leticia Time Yellow' was cultivated and stored in a growth room under fluorescent light of white, blue, green, yellow and red colour. Quantum irradiance was 30 μmol · m<sup>-2</sup> × s<sup>-1</sup>. The colour of light exerted a significant influence on the opening of closed inflorescence buds and on post-harvest longevity of pot chrysanthemums grown earlier in an unheated plastic tunnel. Under florescent lamps emitting blue light at a wavelength of 400-580 nm, inflorescence buds opened and coloured the earliest. The number of developed flower heads was the greatest under blue and white light. Flower heads developing in blue light were bigger than flower heads developing in white and green light. In red light at a wavelength of 600-700 nm, plants flowered latest and they produced the smallest flower heads. Post-harvest longevity was preserved longest in chrysanthemums kept under blue, white and green light. In red and yellow light, the flowers were overblown earliest.


2021 ◽  
Vol 4 (1) ◽  
pp. 73-78
Author(s):  
Idrus Umar

The purpose of the study was to determine the effect of giving different colors of light on carcass percentage and carcass weight in Kampung Super chickens. The research design used was a completely randomized design (CRD). A total of 80 Kampung Super chickens were used in this study. The research treatments were P1 (white light color), P2 (yellow light color), P3 (green light color), P4 (red light color), P5 (blue light color). The results of the study of the highest carcass presentation were found in the treatment that was given red light with an average value of 62.455%. The highest carcass weight was found in the same treatment, which was given a red light with an average value of 674.75 g/head. The provision of different light colors did not have a significant effect on the carcass percentage and carcass weight of the finisher phase super free-range chicken. 


2021 ◽  
Vol 186 ◽  
pp. 109025
Author(s):  
João Humberto Dias Campos ◽  
Meiry Edivirges Alvarenga ◽  
Maykon Alves Lemes ◽  
José Antônio do Nascimento Neto ◽  
Freddy Fernandes Guimarães ◽  
...  

Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1211
Author(s):  
Barbara Frąszczak ◽  
Monika Kula-Maximenko

The spectrum of light significantly influences the growth of plants cultivated in closed systems. Five lettuce cultivars with different leaf colours were grown under white light (W, 170 μmol m−2 s−1) and under white light with the addition of red (W + R) or blue light (W + B) (230 μmol m−2 s−1). The plants were grown until they reached the seedling phase (30 days). Each cultivar reacted differently to the light spectrum applied. The red-leaved cultivar exhibited the strongest plasticity in response to the spectrum. The blue light stimulated the growth of the leaf surface in all the plants. The red light negatively influenced the length of leaves in the cultivars, but it positively affected their number in red and dark-green lettuce. It also increased the relative chlorophyll content and fresh weight gain in the cultivars containing anthocyanins. When the cultivars were grown under white light, they had longer leaves and higher value of the leaf shape index. The light-green cultivars had a greater fresh weight. Both the addition of blue and red light significantly increased the relative chlorophyll content in the dark-green cultivar. The spectrum enhanced with blue light had positive influence on most of the parameters under analysis in butter lettuce cultivars. These cultivars were also characterised by the highest absorbance of blue light.


RSC Advances ◽  
2015 ◽  
Vol 5 (6) ◽  
pp. 4707-4715 ◽  
Author(s):  
Qiwei Zhang ◽  
Haiqin Sun ◽  
Tao Kuang ◽  
Ruiguang Xing ◽  
Xihong Hao

Materials emitting red light (∼611 nm) under excitation with blue light (440–470 nm) are highly desired for fabricating high-performance white light-emitting diodes (LEDs).


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