scholarly journals Phenolic Resin Foam Composites Reinforced by Acetylated Poplar Fiber with High Mechanical Properties, Low Pulverization Ratio, and Good Thermal Insulation and Flame Retardant Performance

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 148 ◽  
Author(s):  
Jian Liu ◽  
Liuliu Wang ◽  
Wei Zhang ◽  
Yanming Han
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Thermal Insulation ◽  
Cell Structure ◽  
Value Added ◽  
Chemical Structures ◽  
Phenolic Foam ◽  
Flame Retardant Properties ◽  
Novel Strategy ◽  
Insulation Performance

Phenolic foam composites (PFs) are of substantial interest due to their uniform closed-cell structure, low thermal conductivity, and good thermal insulation performance. However, their disadvantages of a high pulverization rate and poor mechanical properties restrict their application in building exterior insulation. Therefore, the toughening of these composites is necessary. In this paper, poplar fiber was treated with an acetylation reagent, and the acetylated fiber was used to prepare modified phenolic foams (FTPFs); this successfully solved the phenomenon of the destruction of the foam structure due to the agglomeration of poplar fiber in the resin substrate. The foam composites were comprehensively evaluated via the characterization of their chemical structures, surface morphologies, mechanical properties, thermal conductivities, and flame retardant properties. It was found that the compressive strength and compressive modulus of FTPF-5% respectively increased by 28.5% and 37.9% as compared with those of PF. The pulverization ratio was reduced by 32.3%, and the thermal insulation performance and flame retardant performance (LOI) were improved. Compared with other toughening methods for phenolic foam composites, the phenolic foam composites modified with surface-compatibilized poplar fiber offer a novel strategy for the value-added utilization of woody fiber, and improve the toughness and industrial viability of phenolic foam.

scholarly journals Lignin-Based Phenolic Foam Reinforced by Poplar Fiber and Isocyanate-Terminated Polyurethane Prepolymer

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1068
Author(s):  
Guoliang Chen ◽  
Jian Liu ◽  
Wei Zhang ◽  
Yanming Han ◽  
Derong Zhang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Thermal Insulation ◽  
Abrasion Resistance ◽  
Chemical Structures ◽  
Phenolic Foam ◽  
Flame Retardant Properties ◽  
Novel Strategy ◽  
Hybrid Reinforcement ◽  
Polyurethane Prepolymer

Phenolic foams (PFs) are lightweight (<200 kg/m3), high-quality, and inexpensive thermal insulation materials whose heat and fire resistance are much better than those of foam plastics such as polyurethane and polystyrene. They are especially suitable for use as insulation in chemical, petroleum, construction, and other fields that are prone to fires. However, PFs have poor mechanical properties, poor abrasion resistance, and easy pulverization. In this paper, a polyurethane prepolymer was treated with an isocyanate, and then the isocyanate-terminated polyurethane prepolymer and poplar powder were used to prepare modified lignin-based phenolic foams (PUPFs), which improved the abrasion resistance and decreased the pulverization of the foam. The foam composites were comprehensively evaluated by characterizing their chemical structures, surface morphologies, mechanical properties, thermal conductivities, and flame-retardant properties. The pulverization ratio was reduced by 43.5%, and the thermal insulation performance and flame-retardancy (LOI) were improved. Compared with other methods to obtain lignin-based phenolic foam composites with anti-pulverization and flame-retardant properties, the hybrid reinforcement of foam composites with an isocyanate-terminated polyurethane prepolymer and poplar powder offers a novel strategy for an environmentally friendly alternative to the use of woody fibers.

The Influence of Formaldehyde/Phenol Ratio on Properties of Foamable Phenolic Resin and Phenolic Foam

2011 ◽  
Vol 250-253 ◽  
pp. 523-527
Author(s):  
Wei Zhang ◽  
Yu Feng Ma ◽  
Fu Xiang Chu ◽  
Chun Peng Wang
Keyword(s):  
Flame Retardant ◽  
Phenolic Resin ◽  
Oxygen Index ◽  
Foam Cell ◽  
Cell Structure ◽  
Molar Ratio ◽  
Free Phenol ◽  
Mixed Acid ◽  
Phenolic Foam ◽  
Flame Retardant Properties

The foamable phenolic resin was prepared by gradual copolymerization of formaldehyde, paraformaldehyde and phenol using sodium hydroxide (NaOH) as catalyst, by way of adding NaOH, paraformaldehyde in different steps. The environmental protection vesicant, foam stabilizer and mixed acid curing agent were mixed with the foamable phenolic resin to prepare flame-retardant insulation phenolic foam. The influence of the formaldehyde/phenol molar ratio on the activity, toxic residue of foamable phenolic resin was investigated. Besides, the foam cell structure, insulation and flame-retardant properties of the phenolic foam were also studied. The results showed that as the molar ratio of formaldehyde to phenol was 2.0, the free phenol content was 2.3% and hydroxymethyl content was 34.83%, the thermal conductivity was 0.046w/mk, oxygen index was 54.3% and carbon monoxide (CO) peak production was as high as 1.8584 kg/kg, which was suitable to be used as insulation and flame-retardant materials in buildings.

The Influence of Amount of Wood Fiber on New Flame-Retardant Melamine-Urea-Formaldehyde (MUF) Composite Foam

2011 ◽  
Vol 393-395 ◽  
pp. 1012-1017 ◽  
Author(s):  
Yu Feng Ma ◽  
Wei Zhang ◽  
Ling Li ◽  
Ming Ming Zhang ◽  
Zeng Hui Cheng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Cell Shape ◽  
Urea Formaldehyde ◽  
Wood Fiber ◽  
Cell Size Distribution ◽  
Composite Foam ◽  
Composite Foams ◽  
Flame Retardant Properties ◽  
Irregular Cell

New composite foams were prepared by co-foaming of Melamine-Urea-Formaldehyde (MUF) resin and wood fiber in the closed mould at 70°C. The effects of amount of wood fiber on mechanical properties, brittleness, flame-retardant, insulation and microscopic structures of wood fiber-MUF foam were investigated. Results indicated that the flame-retardant properties increased, and the brittleness and mechanical properties decreased with the increase of the amount of wood fiber in composite foams. The addition of wood fiber resulted in more uniform cell size distribution and irregular cell shape, but had little effect on insulation properties.

Flammability and mechanical properties of poly(styrene–butadiene–styrene) copolymer–containing intumescent flame retardants

2015 ◽  
Vol 30 (6) ◽  
pp. 816-826 ◽  
Author(s):  
Yiren Huang ◽  
Jianwei Yang ◽  
Zhengzhou Wang
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Flame Retardants ◽  
Oxygen Index ◽  
Limiting Oxygen Index ◽  
Styrene Butadiene Styrene ◽  
Flame Retardant Properties ◽  
Intumescent Flame Retardants ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Flame-retardant properties of ammonium polyphosphate (APP) and its two microcapsules, APP with a shell of melamine–formaldehyde (MF) resin (MFAPP) and APP with a shell of epoxy resin (EPAPP), were studied in styrene–butadiene–styrene (SBS). The results indicate that APP after the microencapsulation leads to an increase in limiting oxygen index in SBS compared with APP. When dipentaerythritol is incorporated into the SBS composites containing the APP microcapsules, a further improvement in flame retardancy of the composites is observed. The microencapsulation does not result in much improvement of mechanical properties. Moreover, the effect of a compatibilizer (SBS grafted with maleic anhydride) on flame-retardant and mechanical properties of SBS/APP composites was investigated.

scholarly journals Synthesis of a DOPO-triazine additive and its flame-retardant effect in rigid polyurethane foam

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 235-243 ◽  
Author(s):  
Lin Liu ◽  
Rui Lv
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Cell Structure ◽  
Rigid Polyurethane Foam ◽  
Flame Resistance ◽  
Limiting Oxygen Index ◽  
Flame Retarded ◽  
Flame Retardant Properties ◽  
Mechanical Performances ◽  
Halogen Free

AbstractA DOPO (9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide)-based halogen-free flame retardant (ODOPM-CYC) was synthesized and incorporated in rigid polyurethane foam (RPUF). The structure of ODOPM-CYC was characterized by Fourier transform infrared spectra (FTIR), 1H NMR and 31P NMR. The effects of ODOPM-CYC on the flame resistance, mechanical performances, thermal properties and cell structure of RPUF were also investigated. The results showed that the incorporation of ODOPM-CYC strikingly enhanced flame retardant properties of RPUF. The flame retarded RPUF acquired a limiting oxygen index (LOI) value of 26% and achieved UL-94 V-0 rating with the phosphorus content of 3 wt%. The smoke production rate (SPR) also showed an obvious decrease and total smoke release (TSR) was 39.8% lower than that of neat RPUF. Besides, the results demonstrated that the incorporation of ODOPM-CYC provided RPUF better thermal stability but did not show any obvious influence on its thermal conductivity.

scholarly journals Nanoreinforcements of Two-Dimensional Nanomaterials for Flame Retardant Polymeric Composites: An Overview

2019 ◽  
Vol 2019 ◽  
pp. 1-25 ◽  
Author(s):  
Shaolin Lu ◽  
Wei Hong ◽  
Xudong Chen
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Flame Retardants ◽  
Polymer Materials ◽  
Two Dimensional ◽  
Environmental Friendliness ◽  
Fire Hazards ◽  
Uniform Dispersion ◽  
Physical Barriers ◽  
Flame Retardant Properties

Polymer materials are ubiquitous in daily life. While polymers are often convenient and helpful, their properties often obscure the fire hazards they may pose. Therefore, it is of great significance in terms of safety to study the flame retardant properties of polymers while still maintaining their optimal performance. Current literature shows that although traditional flame retardants can satisfy the requirements of polymer flame retardancy, due to increases in product requirements in industry, including requirements for durability, mechanical properties, and environmental friendliness, it is imperative to develop a new generation of flame retardants. In recent years, the preparation of modified two-dimensional nanomaterials as flame retardants has attracted wide attention in the field. Due to their unique layered structures, two-dimensional nanomaterials can generally improve the mechanical properties of polymers via uniform dispersion, and they can form effective physical barriers in a matrix to improve the thermal stability of polymers. For polymer applications in specialized fields, different two-dimensional nanomaterials have potential conductivity, high thermal conductivity, catalytic activity, and antiultraviolet abilities, which can meet the flame retardant requirements of polymers and allow their use in specific applications. In this review, the current research status of two-dimensional nanomaterials as flame retardants is discussed, as well as a mechanism of how they can be applied for reducing the flammability of polymers.

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