scholarly journals Damage Mechanism of Cu6Sn5 Intermetallics Due to Cyclic Polymorphic Transitions

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4127
Author(s):  
Zhihao Zhang ◽  
Cunwei Wei ◽  
Huijun Cao ◽  
Ye Zhang
Keyword(s):  
Three Dimensional ◽  
Structural Evolution ◽  
Damage Mechanism ◽  
Polymorphic Transition ◽  
High Melting ◽  
High Melting Point ◽  
Polymorphic Transitions ◽  
Abrupt Changes ◽  
3D Package ◽  
Strain Oscillations

The formation of high-melting-point Cu6Sn5 interconnections is crucial to overcome the collapse of Sn-based micro-bumps and to produce reliable intermetallic interconnections in three-dimensional (3D) packages. However, because of multiple reflows in 3D package manufacturing, Cu6Sn5 interconnections will experience cyclic polymorphic transitions in the solid state. The repeated and abrupt changes in the Cu6Sn5 lattice due to the cyclic polymorphic transitions can cause extreme strain oscillations, producing damage at the surface and in the interior of the Cu6Sn5 matrix. Moreover, because of the polymorphic transition-induced grain splitting and superstructure phase formation, the reliability of Cu6Sn5 interconnections will thus face great challenges in 3D packages. In addition, the Cu6Sn5 polymorphic transition is structure-dependent, and the η′↔η polymorphic transition will occur at the surface while the η′↔ηs↔η polymorphic transition will occur in the deep matrix. This study can provide in-depth understanding of the structural evolution and damage mechanism of Cu6Sn5 interconnections in real 3D package manufacturing.

scholarly journals Damage Mechanism of Cu6Sn5 Intermetallics Due to Cyclic Polymorphic Transitions

2019 ◽  
Author(s):  
Zhihao Zhang ◽  
Cunwei Wei ◽  
Huijun Cao ◽  
Ye Zhang
Keyword(s):  
Abrupt Change ◽  
Three Dimensional ◽  
Structural Evolution ◽  
Damage Mechanism ◽  
Polymorphic Transition ◽  
High Melting ◽  
High Melting Point ◽  
Polymorphic Transitions ◽  
3D Package ◽  
Strain Oscillations

The formation of high-melting-point Cu6Sn5 interconnections is crucial to overcome the collapse of Sn-based micro-bumps and produce reliable intermetallic interconnections in three-dimensional (3D) package. However, because of the multiple reflows in 3D package manufacturing, Cu6Sn5 interconnections will experience the cyclic polymorphic transitions in the solid state. The repeated and abrupt change in the Cu6Sn5 lattice due to the cyclic polymorphic transitions can cause extreme strain oscillations, producing damages at the surface and in the interior of the Cu6Sn5 matrix. Moreover, because of the polymorphic-transition-induced grain splitting and superstructure phase formation, the reliability of Cu6Sn5 interconnections will thus face great challenges in 3D package. In addition, the Cu6Sn5 polymorphic transition is structure-dependent, and the η′↔η polymorphic transition will occur at the surface while the η′↔ηs↔η polymorphic transition will occur in the deep matrix. Our results can provide in-depth understandings of structural evolution and damage mechanism of Cu6Sn5 interconnections in real 3D package manufacturing.

CRM MOLYBDENUM-50 RHENIUM

Alloy Digest ◽  
1970 ◽  
Vol 19 (12) ◽  
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Powder Metallurgy ◽  
Melting Point ◽  
Physical Properties ◽  
Heat Treating ◽  
Electrical Contacts ◽  
High Melting ◽  
High Melting Point ◽  
Temperature Performance

Abstract CRM MOLYBDENUM-50 RHENIUM is a high-melting-point alloy for applications such as electronics tube components, electrical contacts, thermionic converters, thermocouples, heating elements and rocket thrusters. All products are produced by powder metallurgy. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Mo-11. Producer or source: Chase Brass & Copper Company Inc..

CRM RHENIUM

Alloy Digest ◽  
1970 ◽  
Vol 19 (8) ◽  
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Powder Metallurgy ◽  
Melting Point ◽  
Heat Treating ◽  
Electrical Contacts ◽  
High Melting ◽  
High Melting Point ◽  
Temperature Performance ◽  
Commercially Pure

Abstract CRM RHENIUM is a commercially pure, high-melting-point metal for applications such as electronics tube components, electrical contacts, thermionic converters, thermocouples, heating elements and rocket thrusters. All products are produced by powder metallurgy. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Re-1. Producer or source: Chase Brass & Copper Company Inc..

PLATINUM

Alloy Digest ◽  
1970 ◽  
Vol 19 (11) ◽  
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Heat Treating ◽  
Industrial Applications ◽  
High Melting ◽  
High Melting Point ◽  
White Metal ◽  
Temperature Performance ◽  
Wide Range ◽  
Corrosion And Oxidation

Abstract PLATINUM is a soft, ductile, white metal which can be readily worked either hot or cold. It has a wide range of industrial applications because of its excellent corrosion and oxidation resistance and its high melting point. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Pt-1. Producer or source: Matthey Bishop Inc..

WIELAND DURO TUNGSTEN

Alloy Digest ◽  
2020 ◽  
Vol 69 (10) ◽  
Keyword(s):  
Melting Point ◽  
Physical Properties ◽  
Tensile Properties ◽  
Modulus Of Elasticity ◽  
Radiation Shielding ◽  
High Melting ◽  
High Modulus ◽  
High Melting Point ◽  
Structural Applications ◽  
Very High

Abstract Wieland Duro Tungsten is unalloyed tungsten produced from pressed-and-sintered billets. The high melting point of tungsten makes it an obvious choice for structural applications exposed to very high temperatures. Tungsten is used at lower temperatures for applications that can benefit from its high density, high modulus of elasticity, or radiation shielding capability. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on machining. Filing Code: W-34. Producer or source: Wieland Duro GmbH.

Facile synthesis of high‐melting point spherical TiC and TiN powders at low temperature

2019 ◽  
Vol 103 (2) ◽  
pp. 889-898 ◽  
Author(s):  
Maoqiao Xiang ◽  
Miao Song ◽  
Qingshan Zhu ◽  
Chaoquan Hu ◽  
Yafeng Yang ◽  
...  
Keyword(s):  
Melting Point ◽  
Low Temperature ◽  
High Melting ◽  
High Melting Point ◽  
Facile Synthesis

Screening of high melting point phase change materials (PCM) in solar thermal concentrating technology based on CLFR

Solar Energy ◽  
2005 ◽  
Vol 79 (3) ◽  
pp. 332-339 ◽  
Author(s):  
Akira Hoshi ◽  
David R. Mills ◽  
Antoine Bittar ◽  
Takeo S. Saitoh
Keyword(s):  
Melting Point ◽  
Phase Change ◽  
Phase Change Materials ◽  
Solar Thermal ◽  
High Melting ◽  
High Melting Point

Observation of Rheed Intensity Oscillations During PbSe/CaF2/Si(111) MBE

1996 ◽  
Vol 441 ◽  
Author(s):  
W. K. Liu ◽  
X. M. Fang ◽  
P. J. McCann ◽  
M. B. Santos
Keyword(s):  
Activation Energy ◽  
Melting Point ◽  
Substrate Temperature ◽  
High Melting ◽  
Arrhenius Behavior ◽  
High Activation ◽  
High Melting Point ◽  
Mbe Growth ◽  
Sublimation Energy ◽  
Initial Nucleation

AbstractRHEED intensity oscillations observed during MBE growth of CaF2 on Si(111) and PbSe on CaF2/Si(111) are presented. The effects of substrate temperature and initial nucleation procedure are investigated. Strong temporal oscillations of the specular beam intensity are found to be most readily observed at temperatures below 200°C for both CaF2 and PbSe. Growth rates measured as a function of cell temperatures exhibit Arrhenius behavior with activation energies of 5.0 eV and 1.93 eV for CaF2 and PbSe, respectively. The relatively high activation energy obtained for CaF2 is consistent with the high melting point and sublimation energy of ionic fluorides.

A study of pest oxidation in polycrystalline MoSi2

1992 ◽  
Vol 7 (10) ◽  
pp. 2747-2755 ◽  
Author(s):  
C.G. McKamey ◽  
P.F. Tortorelli ◽  
J.H. DeVan ◽  
C.A. Carmichael
Keyword(s):  
High Temperature ◽  
Melting Point ◽  
Stoichiometric Ratio ◽  
Low Density ◽  
High Melting ◽  
Phase Boundaries ◽  
High Melting Point ◽  
Good Oxidation Resistance ◽  
Intermediate Temperature Range ◽  
Physical Defects

MoSi2 is a promising high-temperature material with low density (6.3 g/cm3), high melting point (2020 °C), and good oxidation resistance at temperatures to about 1900 °C. However, in the intermediate temperature range between 400 and 600 °C, it is susceptible to a “pest” reaction which causes catastrophic disintegration by a combination of oxidation and fracture. In this study, we have used polycrystalline MoSi2, produced by arc-casting of the pure elements and by cold and hot pressing of alloy powders, to characterize the pest reaction and to determine the roles of composition, grain or phase boundaries, and physical defects on the oxidation and fracture of specimens exposed to air at 500 °C. It was found that pest disintegration occurs through transport of oxygen into the interior of the specimen along pre-existing cracks and/or pores, where it reacts to form MoO3 and SiO2. The internal stress produced during the formation of MoO3 results in disintegration to powder. Near the stoichiometric ratio, the susceptibility to pest disintegration increases with increasing molybdenum content and with decreasing density. Silicon-rich alloys were able to form protective SiO2 and showed no indication of disintegration, even at densities as low as 60%.

Processing of Zinc-Based MgAl2O4 Composite and Effect of Fly Ash Addition

2007 ◽  
Vol 336-338 ◽  
pp. 1203-1206 ◽  
Author(s):  
Metin Gürü ◽  
M. Korçak ◽  
Süleyman Tekeli ◽  
Ahmet Güral
Keyword(s):  
Tensile Strength ◽  
Fly Ash ◽  
Melting Point ◽  
Low Density ◽  
High Melting ◽  
Spinel Oxide ◽  
High Melting Point ◽  
Corrosion Resistant ◽  
Coal Power ◽  
Resistant Composite Material

The properties of ceramic-metal (Cermet) composites as tensile strength, hardness and resistance to corrosion and high temperature are superior than ceramics and metals. Because of the enhanced characteristics of cermets, they are commonly used in various applications and industries. The main objective of this study is to produce a cheap, easy produced, strong and high corrosion resistant composite material. For these purposes, zinc is used for its natural capacity against corrosion, low density, low melting point and softness. Magnesium aluminates spinel oxide (MgAl2O4) is chosen because of its high melting point and low density. Fly ash is a waste from coal power plant having puzzolanic properties. In this study, the effect of various amounts of zinc and fly ash addition on density and hardness behaviour of zinc-based MgAl2O4 composites was investigated. The experimental results showed that zinc and fly ash addition improved the hardness behavior of zincbased MgAl2O4 composite.

Sign in / Sign up

Export Citation Format

Share Document