scholarly journals Dielectric and Impedance Studies of (Ba,Ca)TiO3 Ceramics Obtained from Mechanically Synthesized Powders

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4036
Author(s):  
Kamil Feliksik ◽  
Lucjan Kozielski ◽  
Izabela Szafraniak-Wiza ◽  
Tomasz Goryczka ◽  
Małgorzata Adamczyk-Habrajska

Mechanochemical synthesis offers unique possibility of perovskite phase formation at ambient conditions that is very attractive (simplifies production, allows strict stoichiometry control and brings economic benefits). In this work the mechanochemical synthesis has been used for preparation ofBa1−xCaxTiO3 (0.2 ≤ x ≤ 0.3) powders from simple oxides. The 20 h milled powders have been uniaxially pressed and sintered in order to get the ceramic samples. The sample morphologies have been observed by scanning electron microscopy. Dielectric and impedance studies have been performed on ceramics. The obtained results indicate that the two mechanism of doping occurred. The first one is observed for the lower calcium concentration (below 0.3) and consists of the introduction of calcium ion into the A site of the perovskite structure. The second one is observed for the higher calcium concentration (equal 0.3). In this case the calcium ions partially occupies the B site in the perovskite structure. Both cases have different influence on the final properties of the ceramics because they induce different defects.

2014 ◽  
Vol 70 (a1) ◽  
pp. C267-C267 ◽  
Author(s):  
Tiziana Boffa Ballaran ◽  
Kanchana Kularatne ◽  
Reidar Trønnes

The two known polymorphs of CaIrO3 crystallize int the orthorhombic space groups Pbnm and Cmcm. These compounds have been the focus of much research in the Earth sciences community because they are isostructural with MgSiO3 perovskite and post-perovskite structures which are likely the most abundant minerals in the Earth's lower mantle. CaIrO3 post-perovskite is stable at ambient conditions and transforms at 1-3 GPa and at temperatures above 13500C to the CaIrO3 perovskite structure providing an ideal low pressure and low temperature analogue for the MgSiO3 perovskite to post-perovskite phase transformation which occurs at the extreme conditions of 125 GPa and 2500 K. However, in order to assess whether the CaIrO3 compounds can be used as analogues of MgSiO3 phases, a correct knowledge of their atomic structures and their response to changes in pressure and temperature is essential. In this study the structural behavior of both CaIrO3 polymorphs has been investigated using single-crystal X-ray diffraction at different pressures up to 10 GPa. The orthorhombic distortion of CaIrO3 perovskite derives from the cubic perovskite aristotype by tilting of the octahedral units. These tilts are very large and their variation with pressure is clearly different from the tilting reported for other Ca-oxide perovskites giving rise to a much stiffer structure. The CaIrO3 post-perovskite phase has a layered structure consisting of alternating sheets of Ca atoms and distorted IrO6 octahedra which share edges to form rows running parallel to [100]. With increasing pressure the octahedral tilting remains practically constant and compression of the post-perovskite structure occurs as a result of compression of Ca layers. With increasing temperature, instead, the octahedral tilting increases giving rise to smaller distances between oxygens of adjacent octahedra whose repulsion likely causes the transformation to the CaIrO3 perovskite structure.


2021 ◽  
Vol 205 ◽  
pp. 114176
Author(s):  
Sangwook Kim ◽  
Hyunwook Nam ◽  
Ichiro Fujii ◽  
Shintaro Ueno ◽  
Chikako Moriyoshi ◽  
...  

2011 ◽  
Vol 249 (3) ◽  
pp. 423-434 ◽  
Author(s):  
Yuichi Shimakawa ◽  
Takashi Saito
Keyword(s):  

2021 ◽  
Author(s):  
Alexei A. Belik ◽  
Roger D Johnson ◽  
Dmitry Khalyavin

Perovskite-structure AMnO3 manganites played an important role in the development of numerous physical concepts such as double exchange, small polarons, electron-phonon coupling, and Jahn−Teller effects, and they host a variety...


2021 ◽  
Vol 21 (103) ◽  
pp. 18552-18573
Author(s):  
Naphis Mokaya Bitange ◽  
◽  
GN Chemining’wa ◽  
JL Ambuko ◽  
WO Owino ◽  
...  

Mango (Mangifera indica L) production in Kenya directly supports approximately 200,000 farmers and many other beneficiaries. Despite this, its production suffers from post-harvest losses due to the fruits' short shelf life in ambient conditions. Calcium maintains cell integrity, strengthens the cell wall, membrane structure, and thus increases shelf life. A completely randomized block design with a split plot arrangement was used to compare the effect of spraying and immersion of ‘Van Dyke' mango fruits at maturity or 15 days later in calcium chloride at different concentrations (0.5%, 1%, 1.5%, or 0%) and times on the fruit ripening rate and organoleptic acceptance. The peel firmness (N), total soluble solids (0Brix), flesh color (Ho), beta carotene (mg/100ml), and carbon dioxide evolution (ml/kg/hr) of fruits were determined at time 0 and every two days for up to eight days in ambient conditions. Additionally, organoleptic characteristics, flesh firmness, calcium concentration (g/mg), and their correlations were determined. Fruits immersed in calcium chloride at maturity had higher retained peel firmness (10.6 N, 10.3 N), deeper flesh color (37.45, 36.78), lower total soluble solids (14, 13.8), a lower carbon dioxide evolution (30.7 ml/kg/hr), higher beta carotene and higher flesh calcium concentration than fruits exposed to other treatments. Fruits sprayed at maturity outperformed those sprayed 15 days later in the studied parameters. Flesh calcium content correlated positively with flesh firmness (r= 0.913, r= 0.852), flesh color (r= 0.828, r= 0.841), fruit aroma (r=0.8199, r=0.841), and negatively with skin shriveling (r=-0.778, r=-0.806) and fruit flavor (r=-0.811, r=-0.829). Flesh firmness correlated negatively with skin shriveling (r=-0.868, r=-0.788) and fruit flavor (r=-0.8869, r=-0.821), but positively with peel color (r=0.9115, r=0.856) and aroma (r=0.907, r=0.848). Skin shriveling was found to have a negative relationship with peel color (r=-0.944, r=-0.93) and aroma (r=-0.944, r=-0.938), but a positive relationship with fruit flavor (r=0.933, r=0.947). Peel color correlated positively with aroma (r=0.979, r=0.977) and negatively with fruit flavor (r=-0.962, r=-0.950), respectively. Despite the effectiveness of post-harvest calcium chloride immersion in extending fruit shelf life, optimal use is advised to avoid deteriorated pulp flavor and increased shriveling. More research is needed to determine how calcium chloride can be made available to the fruit while it is still attached to the tree.


2016 ◽  
Vol 4 (1) ◽  
Author(s):  
Suyanta Suyanta ◽  
Hanafi Idham Kholid ◽  
Bambang S

This research aims are to separate of Ca and Fe metal ion in source water, with local zeolite and active carbon by adsorption column technic. Efficiency of separation are control by adsorption time and size of zeolite. Method that used was column adsorption with a flow system in which sample is applied to the filtration tube containing zeolite and active carbon. Initial and final concentrations of the samples were analyzed using Atomic Adsorption Spectrophotometer instrument. The results obtained shows that ability adsorption of zeolite to Ca and Fe metal ion are a good. Zeolite 1 (10 mesh) can reduce iron concentration until 93.98 % and zeolite 2 (5mesh) until 98.88% for 1 – 4 week range time. Whereas reducing of calcium concentration is not good, until 2 week period time adsorption of calcium ion is about 50%. Keywords: adsorption, zeolite, source water


2010 ◽  
Vol 177 ◽  
pp. 29-31
Author(s):  
Hao Wu ◽  
Cheng Chen ◽  
Dan Yu Jiang ◽  
Tao Feng ◽  
Qiang Li

This paper presents a novel mechanochemical synthesis technique for making nano-structured Pb(Mg1/3Nb2/3)O3 (PMN) ferroelectric material without annealing treatment in a much shorter time and at much lower temperature than those reported in the literature, by using the starting precursors MgO, PbO, and Nb2O5. Specimens of various milling time (3-6h) are characterized from XRD patterns to track and analyze the synthesizing procedure of this mechanochemical processing route. The time used to make the desired PMN powders varies with different milling power. When the constituent oxides were mechanically activated at 1.8KW milling power for 6h, the perovskite phase PMN powder was obtained; while it was formed when milling at 3KW for only 3h. Typical SEM images of the as-received PMN powders show that the powders are aggregated of nano-particles of about 100nm in size.


1980 ◽  
Vol 239 (3) ◽  
pp. F244-F249
Author(s):  
H. D. Humes ◽  
C. F. Simmons ◽  
B. M. Brenner

Experiments were performed on 26 acutely thyroparathyroidectomized (TPTX) Sprague-Dawley rats undergoing maximum water diuresis to determine whether the rise in urinary osmolality (Uosmol) in response to a submaximal dose of antidiuretic hormone (ADH) is modified by exogenous administration of parathyroid hormone (PTH). During administration of a submaximal dose of PTH to 11 TPTX rats, the ADH-induced increase in Uosmol averaged 267 +/- 15 mosmol, or twice the average increment of 131 +/- 18 mosmol observed when the same dose of ADH was given prior to PTH infusion (P < 0.001). This difference could not be attributed to changes in endogenous ADH release, renal hemodynamics, or solute excretion, and was not observed in a second group of eight other water-diuretic TPTX rats given sham PTH infusion. A third group of seven water-diuretic TPTX rats were studied with verapamil, a compound known to antagonize calcium ion entry into cells. Pretreatment of these rats with intravenous verapamil abolished the PTH potentiation of the Uosmol response to ADH described above. We conclude, therefore, that PTH enhances the Uosmol response to ADH, perhaps via a mechanism requiring a PTH-mediated change in the cellular calcium concentration or content of cells important in the urinary concentrating process.


1982 ◽  
Vol 243 (2) ◽  
pp. G134-G140
Author(s):  
W. J. Snape

The purpose of this study was to compare the effect of altering the extracellular calcium ion concentration on bethanechol or octapeptide of cholecystokinin (OP-CCK) stimulation of the isolated transverse colon of the cat. Myoelectric activity was recorded with monopolar glass-pore electrodes. Bethanechol (10(-6) M) stimulated an increase in the number of slow waves with superimposed spike potentials to 85.5 +/- 5.3% (P less than 0.001) compared with the basal spike activity (8.9 +/- 1.4%). OP-CCK (4 x 10(-9)) also increased spike activity (80.7 +/- 3.8%, P less than 0.001), which was not inhibited by atropine, phentolamine, or propranolol. Addition of 0.0 mM calcium solution to the colonic smooth muscle abolished both slow-wave and spike activity, which returned after replacing 0.25 mM calcium in the solution. Bethanechol stimulated a greater increase in spike activity as the concentration of calcium was increased. OP-CCK stimulation of colonic spike activity was more sensitive to the extracellular calcium concentration than bethanechol stimulation. Verapamil had a minimal effect on bethanechol stimulation of colonic spike activity, but it inhibited the OP-CCK stimulation. These studies suggest that 1) OP-CCK appears to stimulate colonic smooth muscle directly and 2) OP-CCK requires the presence of a greater amount of extracellular ionic calcium in order to stimulate colonic spike activity compared with bethanechol.


2012 ◽  
Vol 24 (11) ◽  
pp. 2235-2239 ◽  
Author(s):  
You-wen Long ◽  
Takateru Kawakami ◽  
Wei-tin Chen ◽  
Takashi Saito ◽  
Tetsu Watanuki ◽  
...  

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