scholarly journals Organic Solvent-Free Olefins and Alcohols (ep)oxidation Using Recoverable Catalysts Based on [PM12O40]3− (M = Mo or W) Ionically Grafted on Amino Functionalized Silica Nanobeads

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3278 ◽  
Author(s):  
Yun Wang ◽  
Florence Gayet ◽  
Pascal Guillo ◽  
Dominique Agustin
Keyword(s):  
Organic Solvent ◽  
Solid State Nmr ◽  
Solvent Free ◽  
Solution Nmr ◽  
Nano Silica ◽  
Morphological Studies ◽  
Straightforward Method ◽  
Recoverable Catalysts ◽  
Nmr Methods ◽  
Catalytic Performances

Catalyzed organic solvent-free (ep)oxidation were achieved using H3PM12O40 (M = Mo or W) complexes ionically grafted on APTES-functionalized nano-silica beads obtained from straightforward method (APTES = aminopropyltriethoxysilane). Those catalysts have been extensively analyzed through morphological studies (Dynamic Light Scattering (DLS), TEM) and several spectroscopic qualitative (IR, multinuclear solid-state NMR) and quantitative (1H and 31P solution NMR) methods. Interesting catalytic results were obtained for the epoxidation of cyclooctene, cyclohexene, limonene and oxidation of cyclohexanol with a lower [POM]/olefin ratio. The catalysts were found to be recyclable and reused during three runs with similar catalytic performances.

Organic Solvent-Free Reworkable Photocrosslinking System

2007 ◽  
Vol 2 (2) ◽  
pp. 303-306
Author(s):  
Haruyuki Okamura ◽  
Yoshimi Tajima ◽  
Tadahiro Ohba ◽  
Kanji Suyama ◽  
Masamitsu Shirai
Keyword(s):  
Organic Solvent ◽  
Solvent Free

Ultrasonic cavitation driven fabrication of organic solvent free lignin/prochloraz nano capsules to promote resistance to photolysis and rain wash, and provide extended release performance

Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jingtian Chen ◽  
Miao Wang ◽  
Yong Qian ◽  
Shanyuan Tan ◽  
Huan Wang ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Uv Irradiation ◽  
Encapsulation Efficiency ◽  
Extended Release ◽  
Ultrasonic Cavitation ◽  
Solvent Free ◽  
Loading Capacity ◽  
One Pot ◽  
Continuous Release ◽  
Mango Leaves

Abstract Lignin is a natural macromolecular sun blocker and provides an ideal protection material for pesticides that have poor photostability. In this study, alkali lignin/prochloraz capsules (AL-P) were prepared via one-pot ultrasonic cavitation. The results demonstrated that the produced AL-P were uniform spheres with sizes of 170–375 nm. The prochloraz encapsulation efficiency (EE) and loading capacity (LC) reached as high as 91.8 and 98.5%, respectively. Adding a small of surfactant reduced the size of the capsules, but both EE and LC were decreased. AL-P exhibited excellent extended release performance. The cumulative release of AL-P in the first 45 h was 76.1% and continuous release was maintained after 96 h. The resulting AL-P have improved photostability under UV irradiation radiation. Finally, AL-P capsules were sprayed on the mango leaves and bananas to act as preservatives, AL-P capsules had stronger rain wash resistance and were better preserved demonstrating their industrial applicability. Together, organic solvent free AL-P capsules demonstrate a method to improve the efficiency of photosensitive pesticides.

Organic Solvent-Free Preparation of Chitosan Nanofibers with High Specific Surface Charge and Their Application in Biomaterials

2021 ◽  
Vol 13 (10) ◽  
pp. 12347-12358
Author(s):  
Sihan Zhang ◽  
Guanglei Zhao ◽  
Jiming Wang ◽  
Chong Xie ◽  
Wenquan Liang ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Specific Surface ◽  
Surface Charge ◽  
Solvent Free

Organic-solvent-free electromembrane extraction based on semi-interpenetrating polymer networks

2021 ◽  
Author(s):  
Hang Mei ◽  
Huajing Liu ◽  
Qianqian Shang ◽  
Ying Dong ◽  
Stig Pedersen-Bjergaard ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Polymer Networks ◽  
Interpenetrating Polymer Networks ◽  
Solvent Free ◽  
Electromembrane Extraction ◽  
Acidic Analytes

A versatile organic-solvent-free electromembrane extraction (EME) system, which could be successfully used for the extraction of both basic and acidic analytes, is proposed based on semi-interpenetrating polymer networks.

Pegylated Nanocapsules Produced by an Organic Solvent-Free Method: Evaluation of their Stealth Properties

2006 ◽  
Vol 23 (9) ◽  
pp. 2190-2199 ◽  
Author(s):  
Arnaud Béduneau ◽  
Patrick Saulnier ◽  
Nicolas Anton ◽  
François Hindré ◽  
Catherine Passirani ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Solvent Free ◽  
Method Evaluation

scholarly journals Green synthesis of new lawsone enaminones and their Z/E(CC)-isomerization induced by organic solvent

RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12990-12994
Author(s):  
Abolfazl Olyaei ◽  
Amir Mohamadi ◽  
Nilufar Rahmani
Keyword(s):  
Organic Solvent ◽  
Green Synthesis ◽  
Aromatic Amines ◽  
Solvent Free ◽  
Triethyl Orthoformate ◽  
Guanidinium Chloride ◽  
New Class ◽  
Solvent Free Conditions

The synthesis of a new class of lawsone enaminone derivatives by using lawsone, triethyl orthoformate and aromatic amines in the presence of guanidinium chloride under solvent-free conditions has been developed.

Solid state NMR of membrane proteins: methods and applications

2021 ◽  
Author(s):  
Vivien Yeh ◽  
Boyan B. Bonev
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Membrane Proteins ◽  
Solid State Nmr ◽  
Lipid Membrane ◽  
Cell Function ◽  
Membrane Lipid ◽  
Pharmacological Intervention ◽  
Nmr Methods ◽  
Informative Approach

Membranes of cells are active barriers, in which membrane proteins perform essential remodelling, transport and recognition functions that are vital to cells. Membrane proteins are key regulatory components of cells and represent essential targets for the modulation of cell function and pharmacological intervention. However, novel folds, low molarity and the need for lipid membrane support present serious challenges to the characterisation of their structure and interactions. We describe the use of solid state NMR as a versatile and informative approach for membrane and membrane protein studies, which uniquely provides information on structure, interactions and dynamics of membrane proteins. High resolution approaches are discussed in conjunction with applications of NMR methods to studies of membrane lipid and protein structure and interactions. Signal enhancement in high resolution NMR spectra through DNP is discussed as a tool for whole cell and interaction studies.

scholarly journals Synthesis of photoreactive solvent-free acrylic pressure-sensitive adhesives in the recovered system

2007 ◽  
Vol 9 (2) ◽  
pp. 5-9 ◽  
Author(s):  
Roland Milker ◽  
Zbigniew Czech ◽  
Marta Wesołowska
Keyword(s):  
Organic Solvent ◽  
Solvent Free ◽  
The Novel ◽  
Pressure Sensitive Adhesive ◽  
Adhesive Film ◽  
Pressure Sensitive Adhesives ◽  
Pressure Sensitive ◽  
Wide Range ◽  
Protective Films ◽  
New Type

Synthesis of photoreactive solvent-free acrylic pressure-sensitive adhesives in the recovered system The present paper discloses a novel photoreactive solvent-free acrylic pressure-sensitive adhesive (PSA) systems, especially suitable for the so much adhesive film applications as the double-sided, single-sided or carrier-free technical tapes, self-adhesive labels, protective films, marking and sign films and wide range of medical products. The novel photoreactive solvent-free pressure-sensitive adhesives contain no volatile organic compounds (residue monomers or organic solvent) and comply with the environment and legislation. The synthesis of this new type of acrylic PSA is conducted in common practice by solvent polymerisation. After the organic solvent are removed, there remains a non-volatile, solvent-free highly viscous material, which can be processed on a hot-melt coating machine at the temperatures of about 100 to 140°C.

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