scholarly journals Electrospun Nanofibers Applied to Dye Solar Sensitive Cells: A Review

Materials ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3190 ◽  
Author(s):  
Jesse Gerardo López-Covarrubias ◽  
Laura Soto-Muñoz ◽  
Ana Leticia Iglesias ◽  
Luis Jesús Villarreal-Gómez

In recent decades, there has been an increase in the research for the development and improvement of dye sensitized solar cells (DSSCs), owing to their singular advantages such as greater efficiency in energy conversion and overall performance in adverse environmental conditions. Therefore, work is carried out to enhance the energy efficiency of the components of the DSSCs: photoanode, counter-electrode, electrolyte, and dye sensitizer layer. Electrospun nanofibers in particular, have showed to be a novel alternative as components in DSSCs, mainly for energy conversion and as collector materials due in part to their tridimensional structure, high contact surface area and conductivity. Moreover, the incorporation of metallic compounds into nanofibers is advantageously employed in the electrospinning technique, owing to their conductivity and optical properties. Therefore, the present work consists of a detailed recompilation of the use of electrospun nanofibers loaded with metallic compounds and their application in DSSCs. The functionality of the components of DSSCs, parameters and experimental conditions of electrospinning, such as the intrinsic aspects in the polymer solution, are discussed and applied to the photoanode, counter-electrode and electrolyte of the DSSC. Lastly, the use of the electrospinning technique in combination with the use of metallic compounds could provide a great approach for the developing of DSSCs, with superior efficiency, high stability and durability.

RSC Advances ◽  
2015 ◽  
Vol 5 (54) ◽  
pp. 43611-43619 ◽  
Author(s):  
K. Saranya ◽  
A. Subramania ◽  
N. Sivasankar

Earth-abundant bimetallic (Fe–Ni) nanoparticle-embedded carbon nanofibers (CNFs) have been prepared by electrospinning technique and used as counter electrode (CE) material for dye-sensitized solar cells (DSSCs).


2014 ◽  
Vol 2 (41) ◽  
pp. 17253-17257 ◽  
Author(s):  
Xiao Chen ◽  
Yu Hou ◽  
Shuang Yang ◽  
Xiao Hua Yang ◽  
Hua Gui Yang

A novel strategy was introduced to prepare Pt–SnO2 nanocomposite in one step. Pt–SnO2 nanocomposite counter electrode based dye-sensitized solar cells achieve an energy conversion efficiency of 8.83%, better than that for SnO2 CE and comparable with Pt CE based DSCs.


2008 ◽  
Vol 1102 ◽  
Author(s):  
Prakash Joshi ◽  
Yu Xie ◽  
Jeremiah Mwaura ◽  
Mike Ropp ◽  
David Galipeau ◽  
...  

AbstractWe report dye-sensitized solar cells using low cost carbon nanoparticles as an alternative to platinum as a counter-electrode catalyst for triiodide reduction. The counter carbon-electrode was deposited onto fluorine-doped tin oxide (FTO) by spin coating from an aqueous colloidal suspension of the blend of carbon nanoparticles and TiO2 nanocrystals. DSSC devices were fabricated using a stable Ru complex dye (Z-907) as the sensitizer. The cells based on carbon-nanoparticle counter electrode were made and then compared with those cells from platinum counter electrode at similar fabrication conditions. The results have shown that the device performance in terms of short circuit current density (Jsc), open circuit voltage (Voc) and energy conversion efficiency (η) from the cells based on carbon nanoparticle counter electrode were comparable to those from platinum counter-electrode devices. The carbon nanoparticle based cells have achieved an overall energy conversion efficiency of 5.55% under one sun AM 1.5 illumination (100 mW/cm2). The carbon nanoparticles showed significant potential as a low cost alternative to the current widely-used platinum.


RSC Advances ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 8307-8310 ◽  
Author(s):  
Xiao Chen ◽  
Jian Wei Guo ◽  
Yu Hou ◽  
Yu Hang Li ◽  
Shuang Yang ◽  
...  

PtO–MWCNTs nanocomposites were prepared and applied as the counter electrode in dye-sensitized solar cells (DSCs) for the first time. Excellent energy conversion efficiency indicated that the nanocomposite was a promising electrocatalyst for DSCs.


2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Mojgan Kouhnavard ◽  
Norasikin Ahmad Ludin ◽  
Babak Vazifehkhah Ghaffari ◽  
Kamaruzzaman Sopian ◽  
Norshazlinah Abdul Karim ◽  
...  

This study presents a new cost-effective metal-free counter electrode (CE) for dye-sensitized solar cells (DSSCs). CE was prepared by doctor blading a hydrophilic carbon (HC) particle on a fluorine-doped tin oxide substrate. Thereafter, HC CE was characterized using X-ray diffraction, profilometry, four-point probe testing, and cyclic voltammetry. A 2 µm thick HC CE revealed a comparable catalytic activity to that of the Pt electrode under the same experimental conditions. DSSC based on HC CE was analyzed and showedJscof 6.87 mA/cm2close to that of DSSC with Pt CE (7.0 mA/cm2). More importantly, DSSC based on HC CE yielded a power conversion efficiency (η) of 2.93% under AM 1.5 irradiation (100 mW/cm2), which was comparable to that of DSSC based on standard Pt CE. These findings suggest that HC CE could be a promising CE for low-cost DSSCs.


Author(s):  
Winda Rahmalia ◽  
Imelda H. Silalahi ◽  
Thamrin Usman ◽  
Jean-François Fabre ◽  
Zéphirin Mouloungui ◽  
...  

AbstractIn this research, treated metakaolinite (TMK) was introduced into the TiO2 photoelectrode to fabricated dye-sensitized solar cells (DSSCs). The photovoltaic cells have four main natural components, i.e., a photosensitizer (carotenoid bixin), photoelectrode (TiO2/kaolinite), electrolyte (glycerine carbonate derivative), and counter-electrode (carbon). Their stability, reusability, and equivalent circuit were studied. The presence of 5% of TMK in anatase TiO2 paste decreased the TiO2 band gap from 3.21 to 3.16 eV. The result showed that the presence of 5% of TMK in TiO2 paste was more favorable to obtain higher energy conversion efficiency. Under a light intensity of 200 W/m2, it produced an energy conversion yield of 0.086%. The combination of the electrolyte and the TMK demonstrated a synergistic effect to improve the electrical properties of the DSSC. The energy storage function worked well until the third day of analysis. The DSSC based on TiO2/TMK photoelectrode exhibited 16 times better stability than pure TiO2-based photoelectrode. The Faraday charge transfer processes showed that the TiO2/TMK photoelectrode is not in direct contact with the carbon counter-electrode.


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