scholarly journals Fractal Cracking Patterns in Concretes Exposed to Sulfate Attack

Materials ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 2338 ◽  
Author(s):  
Jinwei Yao ◽  
Jiankang Chen ◽  
Chunsheng Lu
Keyword(s):  
Crack Nucleation ◽  
Fractal Dimensions ◽  
Sulfate Attack ◽  
Growth Patterns ◽  
X Ray Diffraction ◽  
Delayed Ettringite Formation ◽  
Crack Evolution ◽  
X Ray ◽  
Surface Cracking ◽  
Ettringite Formation

Sulfate attack tests were performed on concrete samples with three water-to-cement ratios, and micro-crack growth patterns on concrete surfaces were recorded. The expansive stress and crack nucleation caused by delayed ettringite formation (DEF) were studied using X-ray diffraction and scanning electron microscopy. By means of a digital image processing technology, fractal dimensions of surface cracking patterns were determined, which monotonously increase during corrosion. Moreover, it is shown that the change of fractal dimensions is directly proportional to accumulation of DEF, and therefore, a simple theoretical model could be proposed to describe the micro-crack evolution in concretes under sulfate attack.

Heat Curing and Delayed Ettringite Formation

1994 ◽  
Vol 370 ◽  
Author(s):  
M.C. Lewis ◽  
Karen L. Scrivener ◽  
S. Kelham
Keyword(s):  
Heat Treatment ◽  
Elevated Temperature ◽  
X Ray Diffraction ◽  
Delayed Ettringite Formation ◽  
X Ray ◽  
Preliminary Results ◽  
Ettringite Formation ◽  
Heat Curing ◽  
Xrd Studies ◽  
Over Time

AbstractThis paper reports some preliminary results from a study of the effect of elevated temperature curing on mortars and the phenomenon of delayed ettringite formation (DEF). Mortars made from cements with sulphate levels of 3%, 4%, and 5% and with 5% sulphate and added alkali were cured at 20 and 90° C and subsequently stored in water. Expansion measurements showed a pessimum effect with increasing S03 content. Mortars which expanded showed a corresponding decrease in strength. X-ray diffraction (XRD) studies indicated that no ettringite is present after heat treatment but re-forms over time within the material. However, the ultimate levels of ettringite reached do not correspond to the magnitude of expansion observed. X-ray microanalysis shows that immediately after the heat treatment the aluminate species and most of the sulphate species are incorporated within the C-S-H gel. The concentrations of these species decrease during expansion, such that at the end of expansion the amounts remaining correspond to the presence of AFm phase mixed with C-S-H.

Phase composition depth profiles using spatially resolved energy dispersive X-ray diffraction

2004 ◽  
Vol 37 (6) ◽  
pp. 967-976 ◽  
Author(s):  
Andrew C. Jupe ◽  
Stuart R. Stock ◽  
Peter L. Lee ◽  
Nikhila N. Naik ◽  
Kimberly E. Kurtis ◽  
...  
Keyword(s):  
Phase Composition ◽  
Spatial Resolution ◽  
Zinc Coating ◽  
High Energy ◽  
Sulfate Attack ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Spatially Resolved ◽  
Composition Profiles

Spatially resolved energy dispersive X-ray diffraction, using high-energy synchrotron radiation (∼35–80 keV), was used nondestructively to obtain phase composition profiles along the radii of cylindrical cement paste samples to characterize the progress of the chemical changes associated with sulfate attack on the cement. Phase distributions were acquired to depths of ∼4 mm below the specimen surface with sufficient spatial resolution to discern features less than 200 µm thick. The experimental and data analysis methods employed to obtain quantitative composition profiles are described. The spatial resolution that could be achieved is illustrated using data obtained from copper cylinders with a thin zinc coating. The measurements demonstrate that this approach is useful for nondestructively visualizing the sometimes complex transformations that take place during sulfate attack on cement-based materials. These transformations can be spatially related to microstructure as seen by computed microtomography.

Influence of High Temperature Annealing on Microstructure Evolution of Ni-24Fe-14Cr-8Mo Superalloy

2021 ◽  
Vol 904 ◽  
pp. 117-123
Author(s):  
Yi Cui ◽  
Yun Fei Zhang ◽  
Yan Guang Han ◽  
Da Lv
Keyword(s):  
High Temperature ◽  
Microstructure Evolution ◽  
Testing Machine ◽  
Aging Treatment ◽  
Growth Patterns ◽  
High Temperature Annealing ◽  
Rockwell Hardness ◽  
Hardness Testing ◽  
X Ray Diffraction ◽  
X Ray

The effect of high temperature annealing on microstructure evolution of Ni-24Fe-14Cr-8Mo alloy was investigated through Optical Microscopy (OM), Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and Rockwell Hardness Testing Machine. Three kinds of grain growth patterns were found at different annealing temperatures due to carbides precipitation and dissolution. After a combination of high temperature annealing and aging treatment, the hardness versus time curves performed a parabolic pattern. The highest hardness was achieved under 1070°C/60 minutes treatment, and the desirable annealing time should be 60 minutes to 90 minutes.

Deterioration of concrete containing limestone powder exposed to sulfate attack at ambient temperature

2021 ◽  
Vol 11 (5) ◽  
pp. 724-731
Author(s):  
Hemin Liu ◽  
Qian Huang ◽  
Liang Zhao
Keyword(s):  
Ambient Temperature ◽  
Sulfate Solution ◽  
Sulfate Attack ◽  
Limestone Powder ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mineral Phases ◽  
Adverse Influence ◽  
Powder Content ◽  
Scanning Electron

This study investigates the deterioration of concrete containing limestone powder exposed to sulfate solution under ambient temperature (20~25 °C). Microstructure and mineral phases within the attacked concrete were measured by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). It was found that the addition of limestone powder increased the initial porosity of concrete. Consequently, a larger amount of SO2–4 ions diffused into the concrete containing limestone powder, and their degree of deterioration caused by sulfate attack increased with the increase in limestone powder content. At ambient temperature, gypsum and ettringite were the major attack products, respectively within the surface and nearsurface portions of concrete containing limestone powder, which was consistent with the products of sulfate attack within concrete without limestone powder. Therefore, the type and distribution of the attack products in concrete had not been revised due to the addition of limestone powder. Nevertheless, the adverse influence of limestone powder on the sulfate resistance of concrete, even at ambient temperature, should be considered. Furthermore, effective measures should be implemented to improve the durability of concrete containing limestone powder in this environment.

scholarly journals Pore size analyses of cement paste exposed to external sulfate attack and delayed ettringite formation

2019 ◽  
Vol 123 ◽  
pp. 105766 ◽  
Author(s):  
Yushan Gu ◽  
Renaud-Pierre Martin ◽  
Othman Omikrine Metalssi ◽  
Teddy Fen-Chong ◽  
Patrick Dangla
Keyword(s):  
Pore Size ◽  
Cement Paste ◽  
Sulfate Attack ◽  
Delayed Ettringite Formation ◽  
Ettringite Formation

X-Ray Diffraction Study of Particulate Tannery Waste Solidified in Cement

2006 ◽  
Vol 530-531 ◽  
pp. 478-484 ◽  
Author(s):  
Carolina A. Pinto ◽  
Francisco Rolando Valenzuela-Díaz ◽  
John J. Sansalone ◽  
Jo Dweck ◽  
Frank K. Cartledge ◽  
...  
Keyword(s):  
Portland Cement ◽  
Calcium Sulfate ◽  
Type Ii ◽  
X Ray Diffraction ◽  
Leather Industry ◽  
X Ray ◽  
Tannery Waste ◽  
Ettringite Formation ◽  
Chromium Adsorption ◽  
Inorganic Waste

The leather industry creates a large quantity of organic and inorganic waste containing chromium. This research examines stabilization of particulate tannery waste in type II Portland cement. Several clays, Brazilian polycationic smectite modified in laboratory and commercial clays were used as additives with the aim of optimizing chromium adsorption. Tannery waste was added in quantities of 10, 15 and 20% relative to cement mass. The solidification components were analyzed separately and in combination in the solidified mixes using X ray diffraction. The analysis showed that reactions between the waste and the cement occurred, and that the tannery waste modified the final compounds of the system. Calcium sulfate present in the waste increased ettringite formation. Chromium also reacted with cement, since compounds with chromium and calcium were identified. Substitution of aluminum and silicon by chromium was also observed.

D008 External Sulfate Attack on Cement Examined by Spatially Resolved Energy Dispersive Synchrotron X-ray Diffraction and Computed Microtomography

2003 ◽  
Vol 18 (2) ◽  
pp. 181-181
Author(s):  
A. P. Wilkinson ◽  
A. C. Jupe ◽  
K. E. Kurtis ◽  
N. N. Naik ◽  
S. D. Shastri ◽  
...  
Keyword(s):  
Sulfate Attack ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Spatially Resolved ◽  
Computed Microtomography

The Effect on Concrete Resistivity of Sulfate Content in Water

2012 ◽  
Vol 1488 ◽  
Author(s):  
Luis Emilio Rendon ◽  
Montserrat Rendon ◽  
Norma Ramirez
Keyword(s):  
Research Work ◽  
Sulfate Attack ◽  
Industrial Processes ◽  
X Ray Diffraction ◽  
X Ray ◽  
Naturally Occurring ◽  
Sulfate Solutions ◽  
External Sources ◽  
Internal Sources ◽  
Concrete Resistivity

ABSTRACTSulfate attack on concrete has been studied worldwide for more than 60 years. However, the mechanisms of attack are still not entirely understood, and deterioration of concrete from sulfates still occurs. The source of the sulfates may be either external or internal. External sources are the naturally occurring sulfates in the environment or those sulfates that are the product of industrial processes or various human activities (e.g. fertilizers often release sulfates into the soil and groundwater). Internal sources of sulfates may include the sulfates introduced in the cements from which concrete is made. The purpose of this study is to find out the amount of sulfates that concrete can withstand in the water. Standards tests have been developed to evaluate the resistance of concretes to sulfate attack. Some, but not all of these tests, take into account the mechanisms of sulfate attack so far discovered in research work. The tests range from those that monitor changes in the strength of concrete specimens after set periods of immersion in known compositions sulfate solutions, to those that use x- ray diffraction to examine concrete specimens for expansive products (e.g. ettringite and thaumasite) that have resulted from sulfate attack.

Accelerate Thaumasite Formation in Cement-Limestone Powder Paste by Internal Adding Method

2011 ◽  
Vol 250-253 ◽  
pp. 22-27 ◽  
Author(s):  
Chang Cheng Li ◽  
Yan Yao ◽  
Ling Wang
Keyword(s):  
Magnesium Sulfate ◽  
Sodium Sulfate ◽  
Calcium Sulfate ◽  
Sulfate Attack ◽  
Limestone Powder ◽  
Resonance Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cement Based Materials ◽  
Internal Sulfate Attack

Cement-limestone powder pastes added with 10% magnesium sulfate, sodium sulfate, and calcium sulfate respectively were stored in water at (5±2) °C to accelerate thaumasite formation. The pastes were inspected visually at intervals. And the formation of thaumasite was identified and confirmed by X-ray diffraction (XRD), infrared spectroscopy (IR), and nuclear magnetic resonance spectroscopy (NMR). The results show that internal adding sulfate in cement-limestone powder paste is an efficient way to accelerate thaumasite formation, and the accelerated effect is magnesium sulfate> sodium sulfate> calcium sulfate. Cement-limestone paste containing 10% magnesium sulfate totally turns into grey-white mushy materials after 6 months immersion, and products are mainly thaumasite and gypsum. In addition, the amount of thaumasite increases along with time of internal sulfate attack in 15 months. XRD, IR, and NMR are powerful and reliable tools for identification of thaumasite in cement-based materials.

scholarly journals Fractal Dimension Calculation of a Manganese-Chromium Bimetallic Nanocomposite Using Image Processing

2015 ◽  
Vol 2015 ◽  
pp. 1-9
Author(s):  
Amir Lashgari ◽  
Shahriar Ghamami ◽  
Saeedeh Shahbazkhany ◽  
Guillermo Salgado-Morán ◽  
Daniel Glossman-Mitnik
Keyword(s):  
Image Processing ◽  
Fractal Dimension ◽  
Fractal Dimensions ◽  
Process Time ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sem Image ◽  
Bimetallic Materials ◽  
Bimetallic Nanocomposite ◽  
Manganese Chromium

Bimetallic materials, which have the ability to convert heat change into mechanical movement, normally consist of two bonded strips of dissimilar metals that expand at different rates. We describe how we made a manganese-chromium (Mn-Cr) bimetallic nanocomposite using the centrifuge method and a low-to-high approach. We conducted scanning electron microscope (SEM) imaging, energy-dispersive X-ray spectroscopy (EDX) analysis, and X-ray diffraction spectra of the nanocomposite to prove its identity. We examined how centrifuge speed, process time, and the use of an “intruder agent” affected the properties of the material. The fractal dimension is a significant factor that can be used to approximate the surface roughness, the texture segmentation, and an image of the studied compounds. We calculated the technique of fractal dimensions using image-processing values on a computer and histogram plot with the SEM image of the Mn-Cr bimetallic nanocomposite using MATLAB software. We applied the Statistical Package for the Social Sciences software for statistics data extracted from the SEM image of the nanocomposite and obtained the following results: mean = 1.778, median = 1.770, max = 1.98, min = 1.60, skewness = 0.177, range = 0.38, and harmonic mean = 1.771 for fractal dimension of the SEM image.

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