scholarly journals Efficiency and Compatibility of Selected Alkoxysilanes on Porous Carbonate and Silicate Stones

Materials ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 156 ◽  
Author(s):  
Matea Ban ◽  
Elisabeth Mascha ◽  
Johannes Weber ◽  
Andreas Rohatsch ◽  
José Delgado Rodrigues
Keyword(s):  
Mercury Intrusion Porosimetry ◽  
General Trend ◽  
Tetraethyl Orthosilicate ◽  
Capillary Water ◽  
Vapour Permeability ◽  
Treatment Performance ◽  
Mechanical And Physical Properties ◽  
Visual Impact ◽  
Kinetics Of ◽  
Active Content

This study compares the consolidation efficiency and compatibility of three selected alkoxysilanes on two porous carbonate and silicate substrates. Emphasis was given to artificially induced microstructural defects and subsequent restoration of mechanical and physical properties. Two newly engineered formulations (1) a TiO2 modified tetraethyl-orthosilicate in isopropanol with 70% active content and (2) a TiO2 modified alkyl-trialkoxysilane in isopropanol with 75% active content were compared to a commercial product (3), a solvent free tetraethyl-orthosilicate with 99% active content. Treatments were evaluated by scanning electron microscopy, mercury intrusion porosimetry, colour impact and their effect on dynamic modulus of elasticity, splitting tensile- and flexural strengths, capillary water absorption and water vapour permeability. A key outcome was that mechanical strength gain induced by treatments is primarily governed by a stone’s texture and microstructure, and secondarily by the gel deposition rate of consolidants. Likewise, the kinetics of the gel-forming reaction during curing is dependent not only on the product but also on the substrate. Therefore, the moisture related properties and the visual impact develop during time. There is no general trend on how it evolves in time, which can lead to incorrect interpretations of treatment compatibility. The results prove that wide-ranging treatment performance is obtained when applying the same products on different substrates.

Kinetics of autocatalytic hydrolysis of tetraethyl orthosilicate in the presence of aluminium nitrate

1984 ◽  
Vol 25 (3-4) ◽  
pp. 177-179 ◽  
Author(s):  
B. Z. Shalumov ◽  
A. M. Bessarabov ◽  
M. V. Mikheev ◽  
L. A. Gornostaeva ◽  
B. I. Polyakov
Keyword(s):  
Tetraethyl Orthosilicate ◽  
Aluminium Nitrate ◽  
Kinetics Of ◽  
Hydrolysis Of

Denitrification of industrial wastewater with sulfur and limestone packed column

2002 ◽  
Vol 46 (11-12) ◽  
pp. 99-104 ◽  
Author(s):  
R. Nugroho ◽  
H. Takanashi ◽  
M. Hirata ◽  
T. Hano
Keyword(s):  
Industrial Wastewater ◽  
Dominant Species ◽  
Elemental Sulfur ◽  
Packed Column ◽  
Steel Production ◽  
Thiobacillus Denitrificans ◽  
Autotrophic Denitrification ◽  
Treatment Performance ◽  
Biofilm Process ◽  
Kinetics Of

An autotrophic denitrification system was developed for nitrate contaminated industrial wastewater whose C/N ratio was very low. The microbes containing Thiobacillus denitrificans as a dominant species were attached on the surface of granular elemental sulfur packed in a column. Elemental sulfur was used as an electron donor for autotrophic denitrification. The granules of limestone were mixed with the granular sulfur to moderate the decrease of alkalinity during autotrophic denitrification. The stoichiometry and basic kinetics of denitrification were studied in column runs. The effects of minerals such as phosphorus on treatment performance were clarified. The wastewater from steel production plants was treated by the present biofilm process. Low extent of nitrogen removal was caused by the lack of minerals.

scholarly journals Kinetic Study of Aluminum Sulphate and Ammonium Aluminum Sulphate Coagulants in Wastewater Treatment

2007 ◽  
Vol 3 (3) ◽  
pp. 222-228
Author(s):  
Lugard Ukiwe ◽  
C.I.A. Nwoko ◽  
Okere-Chijioke M
Keyword(s):  
Wastewater Treatment ◽  
Kinetic Study ◽  
Kinetic Parameters ◽  
Rate Constant ◽  
General Trend ◽  
First Order ◽  
Coagulation Performance ◽  
Aluminum Sulphate ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

An investigation into the kinetics of two inorganic coagulant namely: aluminum sulphate octadecahydrate (Al2(SO4)3.18H2O) an ammonium aluminum sulphate dodecahydrate (NH4Al(SO4)2.12H2O) was studied to determine the effect of certain kinetic parameters on coagulation performance of the above mentioned coagulants. Results of analysis obtained revealed that the rate constant (k) for Al2(SO4)3.18H2O was 5.727s-1, while that for NH4Al(SO4)2.12H2O was 2.282s-1. However, the order of the reaction (xn) of Al2(SO4)3.18H2O and NH4Al(SO4)2.12H2O with the wastewater was 1.0 and 1.0, respectively, indicating that both reactions were first order. Considering the mechanism of the reaction, the general trend observed indicated that the Al2(SO4)3.18H2O reaction was thrice as fast as the NH4Al(SO4)2.12H2O reaction. This fact together with the larger value of k for Al2(SO4)3.18H2O obtained in the experiment lend credence to the widely held believe that Al2(SO4)3.18H2O is a more effective coagulant than NH4Al(SO4)2.12H2O in wastewater treatment.

Water-Resistance of Mortars with Lightweight Aggregates

2014 ◽  
Vol 634 ◽  
pp. 46-53 ◽  
Author(s):  
António Soares ◽  
Maria Júlio ◽  
Inês Flores-Colen ◽  
Laura Ilharco ◽  
Jorge de Brito ◽  
...  
Keyword(s):  
Absorption Coefficient ◽  
Water Absorption ◽  
Bulk Density ◽  
Silica Aerogel ◽  
Water Resistance ◽  
Lightweight Aggregates ◽  
Capillary Water ◽  
Water Absorption Coefficient ◽  
Vapour Permeability ◽  
Capillary Water Absorption

The incorporation of lightweight aggregates in cement-based coating mortars contributes to a better performance of some of their physical properties, influencing their hygrothermal behaviour. This paper analyses the effect of some lightweight aggregates (expanded clay, granulated cork and silica aerogel) on the following mortars’ characteristics: porosity, bulk density, capillary water absorption coefficient, drying index and water vapour permeability. The experimental results showed that low percentages of incorporation of lightweight aggregates led to more porous mortars with lower bulk density, higher capillary water absorption coefficient and greater drying facility, relative to the reference cement-based mortar. The incorporation of silica aerogel in cement-based mortars resulted in major differences in terms of water resistance, with significant benefits in terms of the drying process due to their porous structure.

Direct observations of radiation-enhanced transformations in glass

1983 ◽  
Vol 41 ◽  
pp. 354-355
Author(s):  
J. F. DeNatale ◽  
D. G. Howitt
Keyword(s):  
Glass Matrix ◽  
Diffusion Mechanism ◽  
Bubble Formation ◽  
Silicate Glasses ◽  
Phase Decomposition ◽  
Direct Observations ◽  
Thin Foils ◽  
Oxygen Bubble ◽  
Electron Energy Loss ◽  
Kinetics Of

The electron irradiation of silicate glasses containing metal cations produces various types of phase separation and decomposition which includes oxygen bubble formation at intermediate temperatures figure I. The kinetics of bubble formation are too rapid to be accounted for by oxygen diffusion but the behavior is consistent with a cation diffusion mechanism if the amount of oxygen in the bubble is not significantly different from that in the same volume of silicate glass. The formation of oxygen bubbles is often accompanied by precipitation of crystalline phases and/or amorphous phase decomposition in the regions between the bubbles and the detection of differences in oxygen concentration between the bubble and matrix by electron energy loss spectroscopy cannot be discerned (figure 2) even when the bubble occupies the majority of the foil depth.The oxygen bubbles are stable, even in the thin foils, months after irradiation and if van der Waals behavior of the interior gas is assumed an oxygen pressure of about 4000 atmospheres must be sustained for a 100 bubble if the surface tension with the glass matrix is to balance against it at intermediate temperatures.

Irradiation behavior of pyrolytic silicon carbide

1983 ◽  
Vol 41 ◽  
pp. 72-73
Author(s):  
R. J. Lauf
Keyword(s):  
Silicon Carbide ◽  
Fission Products ◽  
Thermodynamics And Kinetics ◽  
Neutron Fluences ◽  
Fuel Particles ◽  
Sic Coatings ◽  
Irradiation Behavior ◽  
Kinetics Of ◽  
Htgr Fuel

Fuel particles for the High-Temperature Gas-Cooled Reactor (HTGR) contain a layer of pyrolytic silicon carbide to act as a miniature pressure vessel and primary fission product barrier. Optimization of the SiC with respect to fuel performance involves four areas of study: (a) characterization of as-deposited SiC coatings; (b) thermodynamics and kinetics of chemical reactions between SiC and fission products; (c) irradiation behavior of SiC in the absence of fission products; and (d) combined effects of irradiation and fission products. This paper reports the behavior of SiC deposited on inert microspheres and irradiated to fast neutron fluences typical of HTGR fuel at end-of-life.

The Ordered Phase Formation in Ti-Al-Ga Alloys

1970 ◽  
Vol 28 ◽  
pp. 440-441
Author(s):  
Shiro Fujishiro ◽  
Harold L. Gegel
Keyword(s):  
Thermal Stability ◽  
High Temperature ◽  
Titanium Alloys ◽  
Growth Kinetics ◽  
Stoichiometric Composition ◽  
Good Potential ◽  
Alpha Titanium ◽  
Cold Rolled ◽  
Kinetics Of ◽  
Thermal Stability Of

Ordered-alpha titanium alloys having a DO19 type structure have good potential for high temperature (600°C) applications, due to the thermal stability of the ordered phase and the inherent resistance to recrystallization of these alloys. Five different Ti-Al-Ga alloys consisting of equal atomic percents of aluminum and gallium solute additions up to the stoichiometric composition, Ti3(Al, Ga), were used to study the growth kinetics of the ordered phase and the nature of its interface.The alloys were homogenized in the beta region in a vacuum of about 5×10-7 torr, furnace cooled; reheated in air to 50°C below the alpha transus for hot working. The alloys were subsequently acid cleaned, annealed in vacuo, and cold rolled to about. 050 inch prior to additional homogenization

Ion Beam Induced Interfacial Reactions in Molybdenum Thin Films on Silicon

1981 ◽  
Vol 39 ◽  
pp. 162-163
Author(s):  
L. J. Chen ◽  
L. S. Hung ◽  
J. W. Mayer
Keyword(s):  
Ion Beam ◽  
Chemical Vapor ◽  
Interfacial Reactions ◽  
Practical Applications ◽  
Microelectronic Devices ◽  
Recent Emergence ◽  
Chemical Vapor Deposited ◽  
Atomic Mixing ◽  
Silicon Interface ◽  
Kinetics Of

When an energetic ion penetrates through an interface between a thin film (of species A) and a substrate (of species B), ion induced atomic mixing may result in an intermixed region (which contains A and B) near the interface. Most ion beam mixing experiments have been directed toward metal-silicon systems, silicide phases are generally obtained, and they are the same as those formed by thermal treatment.Recent emergence of silicide compound as contact material in silicon microelectronic devices is mainly due to the superiority of the silicide-silicon interface in terms of uniformity and thermal stability. It is of great interest to understand the kinetics of the interfacial reactions to provide insights into the nature of ion beam-solid interactions as well as to explore its practical applications in device technology.About 500 Å thick molybdenum was chemical vapor deposited in hydrogen ambient on (001) n-type silicon wafer with substrate temperature maintained at 650-700°C. Samples were supplied by D. M. Brown of General Electric Research & Development Laboratory, Schenectady, NY.

In situ study of electron beam-induced chemical vapor deposition of Au in an environmental TEM

1995 ◽  
Vol 53 ◽  
pp. 256-257
Author(s):  
J. Drucker ◽  
R. Sharma ◽  
J. Kouvetakis ◽  
K.H.J. Weiss
Keyword(s):  
Electron Beam ◽  
Chemical Vapor Deposition ◽  
Vapor Deposition ◽  
Quantum Effect ◽  
Line Drawing ◽  
Chemical Vapor ◽  
Environmental Cell ◽  
Engineering Changes ◽  
Kinetics Of

Patterning of metals is a key element in the fabrication of integrated microelectronics. For circuit repair and engineering changes constructive lithography, writing techniques, based on electron, ion or photon beam-induced decomposition of precursor molecule and its deposition on top of a structure have gained wide acceptance Recently, scanning probe techniques have been used for line drawing and wire growth of W on a silicon substrate for quantum effect devices. The kinetics of electron beam induced W deposition from WF6 gas has been studied by adsorbing the gas on SiO2 surface and measuring the growth in a TEM for various exposure times. Our environmental cell allows us to control not only electron exposure time but also the gas pressure flow and the temperature. We have studied the growth kinetics of Au Chemical vapor deposition (CVD), in situ, at different temperatures with/without the electron beam on highly clean Si surfaces in an environmental cell fitted inside a TEM column.

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