scholarly journals Non-Isothermal Crystallization Kinetics of Short Glass Fiber Reinforced Poly (Ether Ether Ketone) Composites

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2094 ◽  
Author(s):  
Xujing Yang ◽  
Yazhuo Wu ◽  
Kai Wei ◽  
Wenjun Fang ◽  
Haofei Sun

Due to its excellent chemical and temperature resistances, short glass fiber reinforced poly (ether ether ketone) composite (SGF/PEEK) is a promising material for application in automotive lightweight. Processing conditions, such as cooling rate, need to be well controlled to obtain the optimal crystallite morphology of PEEK composites. Thus, in this paper, the non-isothermal crystallization kinetics and melting behavior of SGF/PEEK were investigated by differential scanning calorimetry (DSC) at different cooling rates, and the crystallite sizes were evaluated by the X-ray diffraction technique (XRD). Crystallization kinetics models and effective activation energies were evaluated to determine the crystallization parameters of the composites. The results suggest that a lower cooling rate enlarges the size of crystallites and enhances the uniformity of size distribution. The addition of glass fibers improves the nucleation rate owing to heterogeneous nucleation while decreasing the growth rate due to retarded movement of the polymer chain. The combined Avrami-Ozawa equation was shown to describe accurately the non-isothermal crystallization. The absolute value of the crystallization activation energy for SGF/PEEK is lower than that of pure PEEK.

1994 ◽  
Vol 1 (3) ◽  
pp. 183-195 ◽  
Author(s):  
Jiang Zhou ◽  
Alberto D'Amore ◽  
Yuming Yang ◽  
Tianbai He ◽  
Binyao Li ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1569
Author(s):  
Selim Mrzljak ◽  
Alexander Delp ◽  
André Schlink ◽  
Jan-Christoph Zarges ◽  
Daniel Hülsbusch ◽  
...  

Short glass fiber reinforced plastics (SGFRP) offer superior mechanical properties compared to polymers, while still also enabling almost unlimited geometric variations of components at large-scale production. PA6-GF30 represents one of the most used SGFRP for series components, but the impact of injection molding process parameters on the fatigue properties is still insufficiently investigated. In this study, various injection molding parameter configurations were investigated on PA6-GF30. To take the significant frequency dependency into account, tension–tension fatigue tests were performed using multiple amplitude tests, considering surface temperature-adjusted frequency to limit self-heating. The frequency adjustment leads to shorter testing durations as well as up to 20% higher lifetime under fatigue loading. A higher melt temperature and volume flow rate during injection molding lead to an increase of 16% regarding fatigue life. In situ Xray microtomography analysis revealed that this result was attributed to a stronger fiber alignment with larger fiber lengths in the flow direction. Using digital volume correlation, differences of up to 100% in local strain values at the same stress level for different injection molding process parameters were identified. The results prove that the injection molding parameters have a high influence on the fatigue properties and thus offer a large optimization potential, e.g., with regard to the component design.


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2250
Author(s):  
Mohammad Amjadi ◽  
Ali Fatemi

Short glass fiber-reinforced (SGFR) thermoplastics are used in many industries manufactured by injection molding which is the most common technique for polymeric parts production. Glass fibers are commonly used as the reinforced material with thermoplastics and injection molding. In this paper, a critical plane-based fatigue damage model is proposed for tension–tension or tension–compression fatigue life prediction of SGFR thermoplastics considering fiber orientation and mean stress effects. Temperature and frequency effects were also included by applying the proposed damage model into a general fatigue model. Model predictions are presented and discussed by comparing with the experimental data from the literature.


2011 ◽  
Vol 127 ◽  
pp. 110-114
Author(s):  
Rui Zeng ◽  
Chang Long Du ◽  
Jing Zhao ◽  
Rui Xu

In order to make the switch valve in abrasive-liquid device of premixed abrasive water jet cutting system work normally, the sealing bush which ensures the pressure constant and the switch smooth is needed. The structure, material and craft of the switch valve sealing bush are studied in this paper. The different weight content of short glass fiber reinforced nylon is tested in the environment of no lubricant, water lubricant and oil lubricant. The result shows that in oil lubricant environment, the 33% weight content of short glass fiber reinforced nylon composites have the best capabilities and the least resistance of friction. The experimental result proves that the sealing bush made by the prepared short glass fiber reinforced nylon composites can meet the require of the premixed abrasive water jet cutting system, according to which the sealing bush is producted and assembled to the abrasive-liquid device.


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