scholarly journals Entrained Metal Aerosol Emissions from Air-Fired Biomass and Coal Combustion for Carbon Capture Applications

Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1819 ◽  
Author(s):  
Karen Finney ◽  
János Szuhánszki ◽  
Leilani Darvell ◽  
Benjamin Dooley ◽  
Kris Milkowski ◽  
...  
Keyword(s):  
Flue Gas ◽  
Inductively Coupled Plasma ◽  
Carbon Capture ◽  
Optical Emission ◽  
Pilot Scale ◽  
Biomass Energy ◽  
Emission Spectrometry ◽  
Biomass Combustion ◽  
Toxic Heavy Metals ◽  
Aerosol Emissions

Biomass energy with CO2 capture could achieve net negative emissions, vital for meeting carbon budgets and emission targets. However, biomass often has significant quantities of light metals/inorganics that cause issues for boiler operation and downstream processes; including deposition, corrosion, and solvent degradation. This study investigated the pilot-scale combustion of a typical biomass used for power generation (white wood) and assessed the variations in metal aerosol release compared to bituminous coal. Using inductively coupled plasma optical emission spectrometry, it was found that K aerosol levels were significantly greater for biomass than coal, on average 6.5 times, with peaks up to 10 times higher; deposition could thus be more problematic, although Na emissions were only 20% of those for coal. Transition metals were notably less prevalent in the biomass flue gas; with Fe and V release in particular much lower (3–4% of those for coal). Solvent degradation may therefore be less severe for biomass-generated flue gases. Furthermore, aerosol emissions of toxic/heavy metals (As/Cd/Hg) were absent from biomass combustion, with As/Cd also not detected in the coal flue gas. Negligible Cr aerosol concentrations were found for both. Overall, except for K, metal aerosol release from biomass combustion was considerably reduced compared to coal.

scholarly journals Determination of heavy metals and selenium content in chicken liver at Erbil city, Iraq

2020 ◽  
Vol 9 (3) ◽  
Author(s):  
Hoshyar Saadi Ali ◽  
Dhary Alewy Almashhadany ◽  
Hawraz Sami Khalid
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Optical Emission ◽  
Critical Issue ◽  
Chicken Liver ◽  
Poultry Meat ◽  
Emission Spectrometry ◽  
Toxic Heavy Metals

Heavy metal contamination of poultry meat is a critical issue for human health due to associated risks of cytotoxicity and systemic pathologies after ingestion of such metals. A total of twenty chicken liver samples were collected from markets of Erbil city and analyzed for ten heavy metals contents by Inductively Coupled Plasma Optical Emission Spectrometry. The targeted metals were cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), mercury (Hg), zinc (Zn) and selenium (Se). The average concentrations (mg/kg) of targeted trace elements were 0.06±0.027, 0.06±0.05, 2.05±0.34, 1.85±0.47, 0.15±0.17, and 33.53±5.24 for Co, Cr, Cu, Mn, Ni, and Zn respectively. Copper (Cu) levels significantly exceeded the maximum permissible limit of WHO. Moreover, the average concentrations of toxic heavy metals and selenium were 0.07±0.037, 0.278±0.10, 0.11±0.083, and 2.01±0.454 mg/kg for Cd, Pb, Hg, and Se respectively. Hg and Pb levels exceeded the permissible limits of WHO. Higher levels of Cu and Hg in poultry may pose a serious threat to consumers which demand countermeasures and precautions to be taken. Iraqi Standards Authority and relevant official institutions are strongly recommended to regulate safe disposal of heavy metal waste in the environment to reduce animal exposure to such metals.

Metals in Mytillus galloprovincialis (Lamarck 1819) and Ensis directus (Conrad 1883): Risk Assessment

2018 ◽  
Vol 81 (10) ◽  
pp. 1622-1626 ◽  
Author(s):  
ENRIQUE LOZANO-BILBAO ◽  
SONGLIAN MÉNDEZ ◽  
GONZALO LOZANO ◽  
ARTURO HARDISSON ◽  
DAILOS GONZÁLEZ-WELLER ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Essential Elements ◽  
Emission Spectrometry ◽  
Human Consumption ◽  
Toxic Heavy Metals ◽  
Inductively Coupled ◽  
Mediterranean Mussel ◽  
Plasma Optical Emission Spectrometry ◽  
Daily Intakes

ABSTRACT The study has been conducted with inductively coupled plasma optical emission spectrometry to determine the content of toxic heavy metals, macroelements, and essential elements in two species of bivalves of commercial interest in the Canary Islands: the Mediterranean mussel (Mytillus galloprovincialis, Lamarck 1819) and the razor clam (Ensis directus, Conrad 1883). The study included 40 samples corresponding to 20 specimens of each species acquired from fishmongers on the island of Tenerife. E. directus had higher levels of metals, except for B, Cd, Na, and Zn (0.98, 0.02, 2,006.93, and 15.07 mg/kg, respectively) compared with those in M. galloprovincialis, B, Cd, Na, and Zn (2.67, 0.12, 2,267.7, and 22.27 mg/kg, respectively). In both bivalve molluscs, the maximum limits established by European legislation on food for human consumption were not exceeded. Likewise, the estimated daily intakes for the toxic metals Pb and Cd were below the admissible daily intakes.

scholarly journals Heavy Metals in Several Soybean Varieties Cultivated in the Transylvanian Plain, Romania

2020 ◽  
Vol 77 (1) ◽  
pp. 74
Author(s):  
Rajmund MICHALSKI ◽  
Marcel M. DUDA ◽  
Paula N. ȘERDEAN ◽  
Joanna KERNERT ◽  
Katarzyna GRYGOYC ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Emission Spectrometry ◽  
Cultivated Plants ◽  
Soybean Seeds ◽  
Toxic Heavy Metals ◽  
Soybean Genotype ◽  
Inductively Coupled ◽  
Cultivated Soybean

Soybeans are species of legume that has become one of the most widely consumed food in the world, because they are easy to cultivate and very beneficial for human health. The quality of the cultivated plants, including the content of toxic heavy metals depends to a large extent on the contaminants present in the soils in which they are grown and the method of fertilization. Through this research we aim to highlight the degree of accumulation of cadmium, chromium, cobalt, copper, nickel, lead and zinc in relation with the cultivated soybean genotype and fertilization. Three soy varieties (Cristina, Felix and Onix) were cultivated in an experimental field located at Cojocna Experimental Didactic Center of the University of Agricultural Sciences and Veterinary Medicine of Cluj-Napoca. The above-mentioned heavy metals were determined from the harvested mature soybean seeds using inductively coupled plasma-optical emission spectrometry, using an Avio 200 instrument. The obtained results demonstrated that the accumulation of heavy metals in soybean seeds is influenced by the cultivated genotype and fertilization; the Onix variety is more prone to the accumulation of heavy metals, while the highest values of the above listed metals were recorded in the case of fertilizing with „Fertitel”.

scholarly journals Heavy metal contamination and genotoxicity assessment of anthelmintic medicinal plants in Assam, India

2021 ◽  
Author(s):  
Amar Deep Soren ◽  
Arun Kumar Yadav
Keyword(s):  
Heavy Metals ◽  
Medicinal Plants ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Optical Emission ◽  
Essential Elements ◽  
Emission Spectrometry ◽  
Asparagus Racemosus ◽  
Toxic Heavy Metals ◽  
Inductively Coupled

Abstract Medicinal plants possess several metals obtained naturally or through pollution. The study evaluates the genotoxic potentials and the presence of essential elements and toxic heavy metals in Sesbania sesban var. bicolor (leaves), Cyperus compressus (roots) and Asparagus racemosus (roots), which are used as anthelmintics in the traditional medicine of the Santhals in India. Genotoxicity study was performed as per Organization for Economic Co-operation and Development (OECD) guidelines in rats. Element contents were evaluated using inductively coupled plasma-optical emission spectrometry (ICP-OES). Administration of S. sesban var. bicolor (400 mg/kg), C. compressus (700 mg/kg) and A. racemosus (500 mg/kg) did not cause any abnormalities in the chromosomes. Elemental analysis revealed the presence of lead (5.00 ± 0.05, 4.98 ± 0.01, 4.99 ± 0.07 ppm), cadmium (4.99 ± 0.04, 4.90 ± 0.03, 5.00 ± 0.08 ppm) and arsenic (0.98 ± 0.03, 0.41 ± 0.05, 0.92 ± 0.03 ppm), respectively. Although genotoxic potentials were lacking, the presence of toxic heavy metals in them is a cause of concern.

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