scholarly journals First Order Reversal Curve Study of SmFe2 Melt-Spun Ribbons

Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1804 ◽  
Author(s):  
María Grijalva-Castillo ◽  
Carlos Santillán-Rodríguez ◽  
Renee Sáenz-Hernández ◽  
María Botello-Zubíate ◽  
José Matutes-Aquino
Keyword(s):  
Amorphous Phase ◽  
Crystalline Phase ◽  
Melt Spinning ◽  
Continuous Distribution ◽  
Average Crystallite Size ◽  
Nominal Composition ◽  
First Order ◽  
Interaction Field ◽  
Irreversible Magnetization

First-order reversal curves (FORC) and the FORC distribution provide a detailed characterization of the relative proportions of reversible and irreversible components of the magnetization of a material, revealing the dominant interactions in the system. Alloys with the nominal composition SmFe2 were obtained by melt-spinning with a cooper wheel velocity of 30 m/s. X-ray powder diffraction analysis showed a greater part consisting of an amorphous phase and a very small amount of SmFe2 crystalline phase with an average crystallite size of 8 nm. A constant acceleration Mössbauer spectrum, measured at room temperature in transmission mode, was fitted to a continuous distribution of effective fields at the nucleus of the amorphous phase (about 84% of the total area), plus two sextets for the non-equivalent sites of Fe in the SmFe2 crystalline phase. 91 first-order reversal curves were collected in a Quantum Design PPMS-VSM with reversal fields from –800 mT to +800 mT and using a calibration field of 850 mT. The obtained FORC diagrams showed a combined effect of a local interaction field and a mean interaction field, and showed that the reversible magnetization is a function of both, the applied magnetic field and the irreversible magnetization.

Amorphous phase formation in Al70Si17Fe13 alloy

1987 ◽  
Vol 2 (4) ◽  
pp. 427-430 ◽  
Author(s):  
L. A. Bendersky ◽  
F. S. Biancaniello ◽  
R. J. Schaefer
Keyword(s):  
Metallic Glass ◽  
Rapid Solidification ◽  
Amorphous Phase ◽  
Phase Formation ◽  
Crystalline Phase ◽  
Intermetallic Phases ◽  
First Order ◽  
Primary Intermetallic Phases ◽  
Amorphous Phase Formation

The alloy Al70Si17Fe13 was subjected to a range of rapid solidification conditions and the resulting microstructures were evaluated. It was found that when solidification was sufficiently rapid to bypass the formation of primary intermetallic phases, the alloy consisted of spherical regions of amorphous (or microquasicrystalline) material surrounded by a crystalline phase(s). This microstructure is interpreted as the result of solidification of the amorphous phase from the melt by a first-order transformation. The structure of the amorphous phase is different from that of a liquid (or usual metallic glass).

scholarly journals Fabrication and Characterization of Quinary High Entropy-Ultra-High Temperature Diborides

Ceramics ◽  
2021 ◽  
Vol 4 (2) ◽  
pp. 108-120
Author(s):  
Simone Barbarossa ◽  
Roberto Orrù ◽  
Valeria Cannillo ◽  
Antonio Iacomini ◽  
Sebastiano Garroni ◽  
...  
Keyword(s):  
High Temperature ◽  
Single Phase ◽  
Nominal Composition ◽  
High Entropy ◽  
Chemical Complexity ◽  
Alternative Processing ◽  
Plasma Sintering ◽  
High Temperature Synthesis ◽  
Spark Plasma

Due to their inherent chemical complexity and their refractory nature, the obtainment of highly dense and single-phase high entropy (HE) diborides represents a very hard target to achieve. In this framework, homogeneous (Hf0.2Nb0.2Ta0.2Mo0.2Ti0.2)B2, (Hf0.2Zr0.2Ta0.2Mo0.2Ti0.2)B2, and (Hf0.2Zr0.2Nb0.2Mo0.2Ti0.2)B2 ceramics with high relative densities (97.4, 96.5, and 98.2%, respectively) were successfully produced by spark plasma sintering (SPS) using powders prepared by self-propagating high-temperature synthesis (SHS). Although the latter technique did not lead to the complete conversion of initial precursors into the prescribed HE phases, such a goal was fully reached after SPS (1950 °C/20 min/20 MPa). The three HE products showed similar and, in some cases, even better mechanical properties compared to ceramics with the same nominal composition attained using alternative processing methods. Superior Vickers hardness and elastic modulus values were found for the (Hf0.2Nb0.2Ta0.2Mo0.2Ti0.2)B2 and the (Hf0.2Zr0.2Ta0.2Mo0.2Ti0.2)B2 systems, i.e., 28.1 GPa/538.5 GPa and 28.08 GPa/498.1 GPa, respectively, in spite of the correspondingly higher residual porosities (1.2 and 2.2 vol.%, respectively). In contrast, the third ceramic, not containing tantalum, displayed lower values of these two properties (25.1 GPa/404.5 GPa). However, the corresponding fracture toughness (8.84 MPa m1/2) was relatively higher. This fact can be likely ascribed to the smaller residual porosity (0.3 vol.%) of the sintered material.

scholarly journals Characterization of Dissipative Structures for First-Order Symmetric Hyperbolic System with General Relaxation

Mathematics ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 728
Author(s):  
Yasunori Maekawa ◽  
Yoshihiro Ueda
Keyword(s):  
Hyperbolic System ◽  
Dissipative Structure ◽  
Dissipative Structures ◽  
Algebraic Characterization ◽  
Symmetric Hyperbolic System ◽  
Full Generality ◽  
Order Linear ◽  
First Order

In this paper, we study the dissipative structure of first-order linear symmetric hyperbolic system with general relaxation and provide the algebraic characterization for the uniform dissipativity up to order 1. Our result extends the classical Shizuta–Kawashima condition for the case of symmetric relaxation, with a full generality and optimality.

scholarly journals On Consensus Index of Triplex Star-Like Networks: A Graph Spectra Approach

Symmetry ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1248
Author(s):  
Da Huang ◽  
Jian Zhu ◽  
Zhiyong Yu ◽  
Haijun Jiang
Keyword(s):  
Algebraic Connectivity ◽  
Multi Agent Systems ◽  
Graph Spectra ◽  
Asymptotic Behaviors ◽  
Agent Systems ◽  
First Order ◽  
Laplacian Spectra ◽  
Multi Agent ◽  
Consensus Index

In this article, the consensus-related performances of the triplex multi-agent systems with star-related structures, which can be measured by the algebraic connectivity and network coherence, have been studied by the characterization of Laplacian spectra. Some notions of graph operations are introduced to construct several triplex networks with star substructures. The methods of graph spectra are applied to derive the network coherence, and some asymptotic behaviors of the indices have been derived. It is found that the operations of adhering star topologies will make the first-order coherence increase a constant value under the triplex structures as parameters tend to infinity, and the second-order coherence have some equality relations as the node related parameters tend to infinity. Finally, the consensus related indices of the triplex systems with the same number of nodes but non-isomorphic graph structures have been compared and simulated to verify the results.

Processing by Pulsed Laser Deposition and Structural, Morphological and Chemical Characterization of Bi-Pb-Sr-Ca-Cu-O and Bi-Pb-Sb-Sr-Ca-Cu-O Thin Films

2010 ◽  
Vol 75 ◽  
pp. 202-207
Author(s):  
Victor Ríos ◽  
Elvia Díaz-Valdés ◽  
Jorge Ricardo Aguilar ◽  
T.G. Kryshtab ◽  
Ciro Falcony
Keyword(s):  
Thin Films ◽  
Pulsed Laser Deposition ◽  
Room Temperature ◽  
Pulsed Laser ◽  
Chemical Characterization ◽  
Laser Deposition ◽  
Nominal Composition ◽  
Deposition Parameters ◽  
The Relationship

Bi-Pb-Sr-Ca-Cu-O (BPSCCO) and Bi-Pb-Sb-Sr-Ca-Cu-O (BPSSCCO) thin films were grown on MgO single crystal substrates by pulsed laser deposition. The deposition was carried out at room temperature during 90 minutes. A Nd:YAG excimer laser ( = 355 nm) with a 2 J/pulse energy density operated at 30 Hz was used. The distance between the target and substrate was kept constant at 4,5 cm. Nominal composition of the targets was Bi1,6Pb0,4Sr2Ca2Cu3O and Bi1,6Pb0,4Sb0,1Sr2Ca2Cu3OSuperconducting targets were prepared following a state solid reaction. As-grown films were annealed at different conditions. As-grown and annealed films were characterized by XRD, FTIR, and SEM. The films were prepared applying an experimental design. The relationship among deposition parameters and their effect on the formation of superconducting Bi-system crystalline phases was studied.

scholarly journals Numerical Characterization of Cohesive and Non-Cohesive ‘Sediments’ under Different Consolidation States Using 3D DEM Triaxial Experiments

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1252
Author(s):  
Hadar Elyashiv ◽  
Revital Bookman ◽  
Lennart Siemann ◽  
Uri ten Brink ◽  
Katrin Huhn
Keyword(s):  
Mechanical Response ◽  
Burial Depth ◽  
Cohesive Sediments ◽  
Third Order ◽  
First Order ◽  
Numerical Characterization ◽  
Response To Stress ◽  
Bond Strengths ◽  
Individual Bond

The Discrete Element Method has been widely used to simulate geo-materials due to time and scale limitations met in the field and laboratories. While cohesionless geo-materials were the focus of many previous studies, the deformation of cohesive geo-materials in 3D remained poorly characterized. Here, we aimed to generate a range of numerical ‘sediments’, assess their mechanical response to stress and compare their response with laboratory tests, focusing on differences between the micro- and macro-material properties. We simulated two endmembers—clay (cohesive) and sand (cohesionless). The materials were tested in a 3D triaxial numerical setup, under different simulated burial stresses and consolidation states. Variations in particle contact or individual bond strengths generate first order influence on the stress–strain response, i.e., a different deformation style of the numerical sand or clay. Increased burial depth generates a second order influence, elevating peak shear strength. Loose and dense consolidation states generate a third order influence of the endmember level. The results replicate a range of sediment compositions, empirical behaviors and conditions. We propose a procedure to characterize sediments numerically. The numerical ‘sediments’ can be applied to simulate processes in sediments exhibiting variations in strength due to post-seismic consolidation, bioturbation or variations in sedimentation rates.

scholarly journals Characterization of ferrite nanoparticles for preparation of biocomposites

2017 ◽  
Vol 8 ◽  
pp. 1257-1265 ◽  
Author(s):  
Urszula Klekotka ◽  
Magdalena Rogowska ◽  
Dariusz Satuła ◽  
Beata Kalska-Szostko
Keyword(s):  
Chemical Method ◽  
Ferrite Nanoparticles ◽  
Chemical Activity ◽  
Nominal Composition ◽  
X Ray Diffraction ◽  
Wet Chemical Method ◽  
X Ray ◽  
Transmission Electron ◽  
Wet Chemical

Ferrite nanoparticles with nominal composition Me0.5Fe2.5O4 (Me = Co, Fe, Ni or Mn) have been successfully prepared by the wet chemical method. The obtained particles have a mean diameter of 11–16 ± 2 nm and were modified to improve their magnetic properties and chemical activity. The surface of the pristine nanoparticles was functionalized afterwards with –COOH and –NH2 groups to obtain a bioactive layer. To achieve our goal, two different modification approaches were realized. In the first one, glutaraldehyde was attached to the nanoparticles as a linker. In the second one, direct bonding of such nanoparticles with a bioparticle was studied. In subsequent steps, the nanoparticles were immobilized with enzymes such as albumin, glucose oxidase, lipase and trypsin as a test bioparticles. The characterization of the nanoparticles was acheived by transmission electron microscopy, X-ray diffraction, energy dispersive X-ray and Mössbauer spectroscopy. The effect of the obtained biocomposites was monitored by Fourier transform infrared spectroscopy. The obtained results show that in some cases the use of glutaraldehyde was crucial (albumin).

Sign in / Sign up

Export Citation Format

Share Document