scholarly journals Comparative Effect of Self- or Dual-Curing on Polymerization Kinetics and Mechanical Properties in a Novel, Dental-Resin-Based Composite with Alkaline Filler

Materials ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 108 ◽  
Author(s):  
Nicoleta Ilie
Keyword(s):  
Mechanical Properties ◽  
Flexural Strength ◽  
Mechanical Stability ◽  
Polymerization Kinetics ◽  
Dental Resin ◽  
Polymerization Kinetic ◽  
Double Bond Conversion ◽  
Light Curing ◽  
Dual Curing ◽  
The Impact

Dental bulk-fill restorations with resin-composites (RBC) are increasing in popularity, but doubts concerning insufficient curing in depth still disconcert clinicians. An alternative might be offered by modern dual-cured RBCs, which additionally provide bioactive properties. This study assessed the impact of additional light-curing on polymerization kinetics, the degree of conversion (DC) and mechanical properties of a novel, dual-cured RBC with alkaline fillers. Since the bioactivity of a material often implies a release of compounds, the mechanical stability in simulated clinical environments was also evaluated. Polymerization kinetics and DC were assessed at 2- and 4-mm specimen depths in real-time up to one hour (n = 6). Incident and transmitted irradiance and radiant exposure were recorded at 2- and 4-mm depths. Micro-mechanical profiles (n = 6) were assessed in 100-µm steps along 6-mm deep specimens at 24 h post-polymerization. Flexural strength and modulus (n = 10) were determined up to three months of immersion in neutral (6.8) and acidic (4) pH conditions. DC variation in time was best described by a sigmoidal function (R2 > 0.98), revealing a retarded (3.4 ± 0.4 min) initiation in C=C double bond conversion in self-cured versus dual-cured specimens. The setting reaction kinetic was identical at 2- and 4-mm depths for the self-cure mode. For the dual-cure mode, polymerization initiated at 2-mm depth instantly with light-irradiation, while being retarded (0.8 min) at 4-mm depth. The material behaves similarly, irrespective of curing mode or depth, later than 11 min after mixing. Flexural strength and modulus was comparable to regular RBCs and maintained up to three months in both neutral and acidic conditions. Additional light-curing initially accelerates the polymerization kinetic and might help shorten the restauration procedure by hardening the material on demand, however with no effect on the final properties.

scholarly journals A Comparative Study of the Mechanical Properties of Selected Dental Composites with a Dual-Curing System with Light-Curing Composites

Coatings ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1255
Author(s):  
Monika Domarecka ◽  
Agata Szczesio-Wlodarczyk ◽  
Michał Krasowski ◽  
Magdalena Fronczek ◽  
Tomasz Gozdek ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Flexural Strength ◽  
Comparative Study ◽  
Wide Spectrum ◽  
Shrinkage Stress ◽  
Three Point Bending ◽  
Light Curing ◽  
Dual Curing ◽  
Diametral Tensile Strength

Dual-curing composites have a wide spectrum of use in practice (rebuilding, reconstruction, and luting). The characterization of this type of material and comparative study of selected mechanical properties with light-cured materials were carried out for this paper. In this study, we used six materials with a dual-cure system—Bulk EZ, Fill-Up!, StarFill 2B, Rebilda DC, MultiCore Flow, Activa Bioactive-Restorative—and three light-cured materials—Filtek Bulk Fill Posterior, Charisma Classic, and G-aenial Universal Flo. The materials were conditioned for 24 h in water at 37 °C before testing. Selected material properties were determined: three-point bending flexural strength, diametral tensile strength, hardness, microhardness, and shrinkage stress. The highest three-point bending flexural strength (TPB) was 137.0 MPa (G-aenial Universal Flo), while the lowest amounted to 86.5 MPa (Activa Bioactive). The diametral tensile strength (DTS) values were in a range from 39.2 MPa (Rebilda DC) to 54.1 MPa (Charisma Classic). The lowest hardness (HV) value of 26 was obtained by the Activa Bioactive material, while the highest values were recorded for Filtek Bulk Fill Posterior and Charisma Classic-53. The shrinkage stress of the tested materials ranged from 6.3 MPa (Charisma Classic) to 13.2 MPa (G-aenial Universal Flo). Dual-curing composites were found to have similar properties to light-cured composites.

scholarly journals Effect of Accelerated Aging on Some Mechanical Properties and Wear of Different Commercial Dental Resin Composites

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2769
Author(s):  
Jonne Oja ◽  
Lippo Lassila ◽  
Pekka K. Vallittu ◽  
Sufyan Garoushi
Keyword(s):  
Mechanical Properties ◽  
Flexural Strength ◽  
Accelerated Aging ◽  
Wear Depth ◽  
Resin Composites ◽  
Expiration Date ◽  
Dental Resin ◽  
Hydrothermal Aging ◽  
Dental Resin Composites

The aim of current in vitro research was to determine the effect of hydrothermal accelerated aging on the mechanical properties and wear of different commercial dental resin composites (RCs). In addition, the effect of expiration date of the composite prior its use was also evaluated. Five commercially available RCs were studied: Conventional RCs (Filtek Supreme XTE, G-aenial Posterior, Denfil, and >3y expired Supreme XTE), bulk-fill RC (Filtek Bulk Fill), and short fiber-reinforced RC (everX Posterior). Three-point flexural test was used for determination of ultimate flexural strength (n = 8). A vickers indenter was used for testing surface microhardness. A wear test was conducted with 15,000 chewing cycles using a dual-axis chewing simulator. Wear pattern was analyzed by a three-dimensional (3D) noncontact optical profilometer. Degree of C=C bond conversion of monomers was determined by FTIR-spectrometry. The specimens were either dry stored for 48 h (37 °C) or boiled (100 °C) for 16 h before testing. Scanning electron microscopy (SEM) was used to evaluate the microstructure of each material. Data were analyzed using ANOVA (p = 0.05). Hydrothermal aging had no significant effects on the surface wear and microhardness of tested RCs (p > 0.05). While flexural strength significantly decreased after aging (p < 0.05), except for G-aenial Posterior, which showed no differences. The lowest average wear depth was found for Filtek Bulk Fill (29 µm) (p < 0.05), while everX Posterior and Denfil showed the highest wear depth values (40, 39 µm) in both conditions. Passing the expiration date for 40 months did not affect the flexural strength and wear of tested RC. SEM demonstrated a significant number of small pits on Denfil’s surface after aging. It was concluded that the effect of accelerated aging may have caused certain weakening of the RC of some brands, whereas no effect was found with one brand of RC. Thus, the accelerated aging appeared to be more dependent on material and tested material property.

A novel recycled polyethylene terephthalate/polyamide 11 (rPET/PA11) thermoplastic blend

2021 ◽  
pp. 147776062110010
Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flexural Strength ◽  
Polyethylene Terephthalate ◽  
Practical Implication ◽  
Polyamide 11 ◽  
Recycled Polyethylene ◽  
Twin Screw ◽  
Electron Microscopy Analysis ◽  
The Impact

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.

Effect of Filler Compositions on the Mechanical Properties of Bamboo Filled Polyester Composite

2014 ◽  
Vol 879 ◽  
pp. 90-95 ◽  
Author(s):  
Abdul Rahman Noor Leha ◽  
Nor Amalina Nordin
Keyword(s):  
Mechanical Properties ◽  
Flexural Strength ◽  
Impact Test ◽  
Compression Molding ◽  
Engineering Applications ◽  
Maximum Value ◽  
Polyester Composite ◽  
Bamboo Powder ◽  
Flexural Tests ◽  
The Impact

Biocomposite from bamboo powder was fabricated by compression molding technique. The objective of this study was to investigate the mechanical properties of bamboo compounded with epoxy with different ratio. Tensile and flexural tests were done to characterize its mechanical properties. It was observed that the strength of bamboo-polyester was increased with increasing amount of bamboo powder. The tensile and flexural strength shows the highest value at 25 wt.% bamboo. However, the impact test shows the maximum value at 20 wt.% bamboo powder. These results exhibit the bamboo-polyester can be a good candidate to be used in many engineering applications

scholarly journals Mechanical Performance of Unstitched and Silk Fiber-Stitched Woven Kenaf Fiber-Reinforced Epoxy Composites

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4801
Author(s):  
Yasir Khaleel Kirmasha ◽  
Mohaiman J. Sharba ◽  
Zulkiflle Leman ◽  
Mohamed Thariq Hameed Sultan
Keyword(s):  
Mechanical Properties ◽  
Flexural Strength ◽  
Mechanical Performance ◽  
Mechanical Test ◽  
Natural Fibers ◽  
Silk Fiber ◽  
Epoxy Composites ◽  
Test Results ◽  
The Impact ◽  
Woven Kenaf

Fiber composites are known to have poor through-thickness mechanical properties due to the absence of a Z-direction binder. This issue is more critical with the use of natural fibers due to their low strength compared to synthetic fibers. Stitching is a through-thickness toughening method that is used to introduce fibers in the Z-direction, which will result in better through-thickness mechanical properties. This research was carried out to determine the mechanical properties of unstitched and silk fiber-stitched woven kenaf-reinforced epoxy composites. The woven kenaf mat was stitched with silk fiber using a commercial sewing machine. The specimens were fabricated using a hand lay-up method. Three specimens were fabricated, one unstitched and two silk-stitched with deferent stitching orientations. The results show that the stitched specimens have comparable in-plane mechanical properties to the unstitched specimens. For the tensile mechanical test, stitched specimens show similar and 17.1% higher tensile strength compared to the unstitched specimens. The flexural mechanical test results show around a 9% decrease in the flexural strength for the stitched specimens. On the other hand, the Izod impact mechanical test results show a significant improvement of 33% for the stitched specimens, which means that stitching has successfully improved the out-of-plane mechanical properties. The outcome of this research indicates that the stitched specimens have better mechanical performance compared to the unstitched specimens and that the decrease in the flexural strength is insignificant in contrast with the remarkable enhancement in the impact strength.

Effect of layer thickness on irreversible thermal expansion and interlayer strength in fused deposition modeling

2017 ◽  
Vol 23 (5) ◽  
pp. 943-953 ◽  
Author(s):  
Anthony A. D’Amico ◽  
Analise Debaie ◽  
Amy M. Peterson
Keyword(s):  
Mechanical Properties ◽  
Thermal Expansion ◽  
Flexural Strength ◽  
Layer Thickness ◽  
Fused Deposition Modeling ◽  
Thermal Strain ◽  
Content Type ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
The Impact

Purpose The aim of this paper is to examine the impact of layer thickness on irreversible thermal expansion, residual stress and mechanical properties of additively manufactured parts. Design/methodology/approach Samples were printed at several layer thicknesses, and their irreversible thermal expansion, tensile strength and flexural strength were determined. Findings Irreversible thermal strain increases with decreasing layer thickness, up to 22 per cent strain. Tensile and flexural strengths exhibited a peak at a layer thickness of 200 μm although the maximum was not statistically significant at a 95 per cent confidence interval. Tensile strength was 54 to 97 per cent of reported values for injection molded acrylonitrile butadiene styrene (ABS) and 29 to 73 per cent of those reported for bulk ABS. Flexural strength was 18 to 41 per cent of reported flexural strength for bulk ABS. Practical implications The large irreversible thermal strain exhibited that corresponding residual stresses could lead to failure of additively manufactured parts over time. Additionally, the observed irreversible thermal strains could enable thermally responsive shape in additively manufactured parts. Variation in mechanical properties with layer thickness will also affect manufactured parts. Originality/value Tailorable irreversible thermal strain of this magnitude has not been previously reported for additively manufactured parts. This strain occurs in parts made with both high-end and consumer grade fused deposition modeling machines. Additionally, the impact of layer thickness on tensile and flexural properties of additively manufactured parts has received limited attention in the literature.

Preparing of SMC Artificial Marble and its Mechanical Properties

2011 ◽  
Vol 55-57 ◽  
pp. 447-450 ◽  
Author(s):  
Jian Li ◽  
Zheng Qun Huang ◽  
Yan Qin
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flexural Strength ◽  
Fiber Length ◽  
Filler Content ◽  
Fiber Content ◽  
Molding Temperature ◽  
Overall Performance ◽  
The Impact

In this article, a kind of SMC artificial marble was prepared. In order to enhance the mechanical properties and prolong the using life of SMC artificial marble, some effects such as fiber content, filler content and molding temperature etc. on the mechanical properties were carefully studied, too. Results showed that the increase of fiber content could improve the impact strength of SMC artificial marble when the fiber length was 10mm and the increase of filler content would decrease the flexural strength of SMC artificial marble. And the molding temperature at the range of 130°C ~ 160°C had little influence on the mechanical properties of SMC artificial marble. Comparing with natural marble and casting marble, SMC artificial marble owed superior overall performance and it was much more suitable for industry production.

Electrical and Mechanical Properties of Carbon Aerogels / Phenolic Resin for Nanocomposites

2011 ◽  
Vol 236-238 ◽  
pp. 1725-1730 ◽  
Author(s):  
Wei Jen Chen ◽  
Ming Yuan Shen ◽  
Yi Luen Li ◽  
Chin Lung Chiang ◽  
Ming Chuen Yip
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Phenolic Resin ◽  
Surface Conductivity ◽  
Carbon Aerogels ◽  
Polymer Resin ◽  
The Impact ◽  
Humidity Environment

This study used carbon aerogels (CA) and phenolic resin in fixed proportations to produce nano high polymer resin, and used poly ehtylene oxide (PEO) as the modifying agent for phenolic resin to improve the mechanical properties of phenolic resin and promote the surface conductivity. The prepared nano high polymer resin and carbon cloth were made into nano-prepreg by using ultrasonic impregnation method, and a nano-prepreg composite material was prepared by using hot compacting and cut to test pieces to measure its mechanical properties and surface conductivity as well as the influence of temperature-humidity environment (85°C/168hr and 85°C/85%RH/168hr) on mechanical properties. The result showed that the surface conductivity increased by 64.55%, the tensile strength at room temperature increased by 35.7%, the flexural strength increased by 18.4%, and the impact strength increased by 101%. In hot environment (85°C/168hr), the tensile strength decreased by 23.8%, the flexural strength increased by 3.1%, and the impact strength increased by 84.6%. In high temperature-high humidity environment (85°C/85% RH/168hr), the tensile strength decreased by 29.6%, the flexural strength decreased by 17%, and the impact strength increased by 95.7%.Introduction

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