scholarly journals 1-Benzyl-2-(thien-2-yl)-4,5-dihydro-1H-imidazole

Molbank ◽  
10.3390/m1137 ◽  
2020 ◽  
Vol 2020 (2) ◽  
pp. M1137
Author(s):  
Alexandra S. Golubenkova ◽  
Nikita E. Golantsov ◽  
Alexey A. Festa ◽  
Leonid G. Voskressensky
Keyword(s):  
Organic Compounds ◽  
Title Compound ◽  
Chiral Ligands ◽  
Imidazoline Receptors ◽  
Metal Catalysis ◽  
Synthetic Intermediates

Imidazolines are a valuable class of organic compounds, namely ligands of imidazoline receptors, chiral ligands for metal catalysis, synthetic intermediates. The title compound has been prepared through a modified procedure, employing N-benzylethylenediamine and thiophene-2-carbaldehyde under the action of N-bromosuccinimide (NBS) in dichloromethane (DCM) in a good 78% yield.

Electroreduction of Organic Compounds, 23 [1].Preparation of the Highly Strained 1′,3′-Dichlorodispiro[cyclopropane-1,2′-bicyclo[ 1.1.0lbutane-4′,1″-cyclopropane][2]

1993 ◽  
Vol 48 (9) ◽  
pp. 1288-1290 ◽  
Author(s):  
Thomas Strelow ◽  
Jürgen Voss ◽  
Werner Baum
Keyword(s):  
Electrochemical Reduction ◽  
Quantum Chemical Calculations ◽  
Organic Compounds ◽  
Title Compound ◽  
Quantum Chemical ◽  
Highly Strained

The preparation of the title compound 4 by electrochemical reduction of 4,4,8,8-tetrachloro-dispiro[2.1.2.1]octane 3 is described. The geometry of the compounds is discussed in terms of quantum chemical calculations and spectroscopic results.

Asymmetric desymmetrization of alkene-, alkyne- and allene-tethered cyclohexadienones using transition metal catalysis

2021 ◽  
Author(s):  
Tao Shu ◽  
Janine Cossy
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Transition Metal Catalysis ◽  
Chiral Ligands ◽  
Domino Reactions ◽  
Metal Catalysis ◽  
Catalytic Asymmetric

This review is covering the recent development of catalytic asymmetric domino reactions for the desymmetrization of alkene-, alkyne- and allene-tethered cyclohexadienones using transition metals and chiral ligands.

A twofold interwoven two-dimensional→two-dimensional (2-D→2-D) cluster–organic network based on the [Cu2I2] cluster and the 4,4′-(diazenediyl)dipyridine ligand: poly[[μ2-4,4′-(diazenediyl)dipyridine]-μ2-iodido-copper(I)]

2013 ◽  
Vol 69 (2) ◽  
pp. 123-126 ◽  
Author(s):  
Wenjiang Huang ◽  
Jinfang Zhang ◽  
Jianghua Li ◽  
Chi Zhang
Keyword(s):  
Organic Compounds ◽  
Title Compound ◽  
Two Dimensional ◽  
Tetrahedral Geometry ◽  
Bridging Ligands ◽  
Bond Lengths ◽  
First Time

In the polymeric title compound, [CuI(C10H8N4)]n, the CuIatom is in a four-coordinated tetrahedral geometry, formed by two I atoms and two pyridine N atoms from two different 4,4′-(diazenediyl)dipyridine (4,4′-azpy) ligands. Two μ2-I atoms link two CuIatoms to form a planar rhomboid [Cu2I2] cluster located on an inversion centre, where the distance between two CuIatoms is 2.7781 (15) Å and the Cu—I bond lengths are 2.6290 (13) and 2.7495 (15) Å. The bridging 4,4′-azpy ligands connect the [Cu2I2] clusters into a two-dimensional (2-D) double-layered grid-like network [parallel to the (10\overline{2}) plane], with a (4,4)-connected topology. Two 2-D grid-like networks interweave each other by long 4,4′-azpy bridging ligands to form a dense 2-D double-layered network. To the best of our knowledge, this interwoven 2-D→2-D network is observed for the first time in [Cu2I2]–organic compounds.

ChemInform Abstract: Design of Supramolecular Chiral Ligands for Asymmetric Metal Catalysis

ChemInform ◽  
2015 ◽  
Vol 46 (23) ◽  
pp. no-no
Author(s):  
Kohsuke Ohmatsu ◽  
Takashi Ooi
Keyword(s):  
Chiral Ligands ◽  
Metal Catalysis

The Diversity of Heterocyclic N-oxide Molecules: Highlights on their Potential in Organic Synthesis, Catalysis and Drug Applications

2019 ◽  
Vol 23 (5) ◽  
pp. 616-627 ◽  
Author(s):  
Dongli Li ◽  
Panpan Wu ◽  
Ning Sun ◽  
Yu-Jing Lu ◽  
Wing-Leung Wong ◽  
...  
Keyword(s):  
Drug Development ◽  
Metal Complexes ◽  
Asymmetric Catalysis ◽  
Organic Compounds ◽  
Organic Synthesis ◽  
Medical Application ◽  
Present Review ◽  
The Past ◽  
Application Potential ◽  
Synthetic Intermediates

The synthesis and chemistry of heterocyclic N-oxide derivatives such as those from pyridine and indazole are very well-known due to their usefulness as versatile synthetic intermediates and their biological importance. These classes of organic compounds have been demonstrated in many interesting and amazing functionalities, particularly vital in the areas including metal complexes formation, catalysts design, asymmetric catalysis and synthesis, and medicinal applications (some potent N-oxide compounds with anticancer, antibacterial, anti-inflammatory activity, etc.). Therefore, the heterocyclic N-oxide motif has been successfully employed in a number of recent advanced chemistry and drug development investigations. In the present review, our primary aim was to provide a relevant summary focusing on the topics of organic synthesis and medical application potential of the compounds cited, which could be attractive and give some insights to researchers in the field. Therefore, we mainly highlight the importance of heterocyclic N-oxide derivatives including those synthesized from imidazole, indazole, indole, pyridazine, pyrazine, pyridine, and pyrimidine in organic syntheses and catalysis, and drug applications. Over the past years, a number of reviews have been published on the organic synthesis and catalysis of N-oxides. We thus concentrated on highlighting those rarely mentioned or recently reported systems.

scholarly journals Design of supramolecular chiral ligands for asymmetric metal catalysis

2015 ◽  
Vol 56 (16) ◽  
pp. 2043-2048 ◽  
Author(s):  
Kohsuke Ohmatsu ◽  
Takashi Ooi
Keyword(s):  
Chiral Ligands ◽  
Metal Catalysis
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