scholarly journals Characterization of Raman Spectroscopy System Transfer Functions in Intensity, Wavelength, and Time

Instruments ◽  
2020 ◽  
Vol 4 (3) ◽  
pp. 22
Author(s):  
Yu-Chung Lin ◽  
Joseph V. Sinfield

The emergence of a wide variety of relatively low-cost compact spectrometers has led to an increase in the use of spectroscopic techniques by researchers in a broad array of fields beyond those that have traditionally employed these analytical methods. While the fundamental elements and functions of Raman systems are generally consistent, the specific components that compose a system may vary in number, design, and configuration, and researchers often modify off-the-shelf spectrometers for unique applications. Understanding the effect of instrument design and components on acquired information is thus crucial and provides the prospect to optimize the system to individual needs and to properly compare results obtained with different systems while also reducing the potential for unintended misinterpretation of data. This paper provides a practical treatment of the influences in a typical compact spectroscopy system that can impact the extent to which the output of the system is representative of the observed environment, a relationship that in measurement science is classically termed the system transfer function. For clarity, the transfer function is developed in terms of traditional Raman output parameters, namely intensity, wavelength, and time.

Author(s):  
Terrin Stachiw ◽  
Fidel Khouli ◽  
Robert G. Langlois ◽  
Fred F. Afagh ◽  
Joseph Ricciardi

Abstract Airframe flexibility effects have typically been captured by modal reduction of the airframe. Although efficient, this model may still be prohibitively expensive for preliminary design studies. This paper employs time- and frequency-domain system identification techniques to form a multi-objective optimization problem to identify equivalent transfer functions representing airframe flexibility effects. Pareto-optimal sets are first identified for an equivalent transfer function of a force element between the landing gear attachment point and the centre of gravity of a 150-passenger regional jet, and a second transfer function from the input landing gear force to the cockpit acceleration. The reduced models demonstrate the ability to generally capture flexibility effects with reduced computation times. The combination of time-domain and frequency-domain information ensures the positive time-history matches while the model remains physically realizable as it is rooted to frequency response obtained from the finite element model. It is hypothesized that this physical link allowed the model to be robust to the landing initial conditions.


2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Walter A. Mayorga-Macías ◽  
Luis E. González-Jiménez ◽  
Marco A. Meza-Aguilar ◽  
Luis F. Luque-Vega

A methodology for the experimental modelling of the electric actuators of a multirotor is presented in this work. These actuators are usually brushless DC motors which are driven by electronic speed controllers in an open loop. The duty cycle of a PWM signal, generated by the electronic control unit, is the input of the electronic controller. However, during the control design procedure for the multirotor, it is important to account with a model of the actuators as its dynamical features define the closed-loop performance of the overall aircraft. Hence, a procedure, based on low-cost electronic components, to obtain approximated transfer functions of the actuators of a multirotor is presented. Moreover, as the proposed signal processing algorithms are simple, the computational capabilities of the required embedded system are also low. Given that different control schemes require different information from the actuator, two models were obtained: a duty cycle vs. angular velocity transfer function and a duty cycle vs. consumed current transfer function. The effectivity of the proposal is validated with experimental results on common electric actuators of a multirotor.


Author(s):  
Jailene Hernandez ◽  
Johan Castrillon ◽  
Manuel Jimenez ◽  
Angel De La Torre ◽  
Pedro Escalona ◽  
...  

Author(s):  
Peter Rez

In high resolution microscopy the image amplitude is given by the convolution of the specimen exit surface wave function and the microscope objective lens transfer function. This is usually done by multiplying the wave function and the transfer function in reciprocal space and integrating over the effective aperture. For very thin specimens the scattering can be represented by a weak phase object and the amplitude observed in the image plane is1where fe (Θ) is the electron scattering factor, r is a postition variable, Θ a scattering angle and x(Θ) the lens transfer function. x(Θ) is given by2where Cs is the objective lens spherical aberration coefficient, the wavelength, and f the defocus.We shall consider one dimensional scattering that might arise from a cross sectional specimen containing disordered planes of a heavy element stacked in a regular sequence among planes of lighter elements. In a direction parallel to the disordered planes there will be a continuous distribution of scattering angle.


Author(s):  
Bradley L. Thiel ◽  
Chan Han R. P. ◽  
Kurosky L. C. Hutter ◽  
I. A. Aksay ◽  
Mehmet Sarikaya

The identification of extraneous phases is important in understanding of high Tc superconducting oxides. The spectroscopic techniques commonly used in determining the origin of superconductivity (such as RAMAN, XPS, AES, and EXAFS) are surface-sensitive. Hence a grain boundary phase several nanometers thick could produce irrelevant spectroscopic results and cause erroneous conclusions. The intergranular phases present a major technological consideration for practical applications. In this communication we report the identification of a Cu2O grain boundary phase which forms during the sintering of YBa2Cu3O7-x (1:2:3 compound).Samples are prepared using a mixture of Y2O3. CuO, and BaO2 powders dispersed in ethanol for complete mixing. The pellets pressed at 20,000 psi are heated to 950°C at a rate of 5°C per min, held for 1 hr, and cooled at 1°C per min to room temperature. The samples show a Tc of 91K with a transition width of 2K. In order to prevent damage, a low temperature stage is used in milling to prepare thin foils which are then observed, using a liquid nitrogen holder, in a Philips 430T at 300 kV.


2012 ◽  
Vol 37 (4) ◽  
pp. 447-454
Author(s):  
James W. Beauchamp

Abstract Source/filter models have frequently been used to model sound production of the vocal apparatus and musical instruments. Beginning in 1968, in an effort to measure the transfer function (i.e., transmission response or filter characteristic) of a trombone while being played by expert musicians, sound pressure signals from the mouthpiece and the trombone bell output were recorded in an anechoic room and then subjected to harmonic spectrum analysis. Output/input ratios of the signals’ harmonic amplitudes plotted vs. harmonic frequency then became points on the trombone’s transfer function. The first such recordings were made on analog 1/4 inch stereo magnetic tape. In 2000 digital recordings of trombone mouthpiece and anechoic output signals were made that provide a more accurate measurement of the trombone filter characteristic. Results show that the filter is a high-pass type with a cutoff frequency around 1000 Hz. Whereas the characteristic below cutoff is quite stable, above cutoff it is extremely variable, depending on level. In addition, measurements made using a swept-sine-wave system in 1972 verified the high-pass behavior, but they also showed a series of resonances whose minima correspond to the harmonic frequencies which occur under performance conditions. For frequencies below cutoff the two types of measurements corresponded well, but above cutoff there was a considerable difference. The general effect is that output harmonics above cutoff are greater than would be expected from linear filter theory, and this effect becomes stronger as input pressure increases. In the 1990s and early 2000s this nonlinear effect was verified by theory and measurements which showed that nonlinear propagation takes place in the trombone, causing a wave steepening effect at high amplitudes, thus increasing the relative strengths of the upper harmonics.


2020 ◽  
pp. 3-11
Author(s):  
S.M. Afonin

Structural-parametric models, structural schemes are constructed and the transfer functions of electro-elastic actuators for nanomechanics are determined. The transfer functions of the piezoelectric actuator with the generalized piezoelectric effect are obtained. The changes in the elastic compliance and rigidity of the piezoactuator are determined taking into account the type of control. Keywords electro-elastic actuator, piezo actuator, structural-parametric model, transfer function, parametric structural scheme


2020 ◽  
Vol 16 (8) ◽  
pp. 1130-1139
Author(s):  
Singaram Sathiyanarayanan ◽  
Chidambaram Subramanian Venkatesan ◽  
Senthamaraikannan Kabilan

Background: Regadenoson is an A2A adenosine receptor agonist that is a coronary vasodilator and commonly used as a pharmacologic cardiac stressing agents. Methods: HPLC method was used for the analysis of related substances. The degraded impurities during the process were isolated and characterized by IR, Mass and NMR spectral analysis. Results: Forced degradation study of regadenoson under conditions of hydrolysis (neutral, acidic and alkaline) and oxidations suggested in the ICH Q1A(R2) was accomplished. The drug showed significant degradation under all the above conditions. On the whole, five novel degradation products were found under diverse conditions along with process related impurities which were not reported earlier. Conclusion: All the degradation products were well characterized by using advanced spectroscopic techniques like IR, 1H NMR, 13C NMR and Mass spectra. The identification of these impurities will be productive for the quality control during the production and stability behavior of the regadenoson drug substance.


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