scholarly journals Modeling Anomalous Moisture Transport in Cement-Based Materials with Kinetic Permeability

2020 ◽  
Vol 21 (3) ◽  
pp. 837 ◽  
Author(s):  
Zhidong Zhang ◽  
Ueli Angst
Keyword(s):  
Moisture Transport ◽  
Transport Model ◽  
Weibull Function ◽  
Cement Pastes ◽  
Dimensional Changes ◽  
Proposed Model ◽  
Cement Based Materials ◽  
Moisture State ◽  
Conventional Models ◽  
Good Agreement

The durability of reinforced concrete structures is closely related to moisture state in cement-based materials. Therefore, it is crucial to develop moisture models that can accurately predict moisture state in the materials. However, many studies reported anomalous moisture transport in cement-based materials that cannot be well simulated by the conventional models. Several reasons have been investigated in the literature, such as the complex pore structure, chemical reactions with water, dimensional changes of the tested specimen, etc. Nevertheless, only a few models are able to capture the anomaly of moisture transport. This study viewed the main moisture transport coefficient—permeability—as a kinetic variable that depends on both the degree of moisture saturation and the contact time. The time-dependence was formulated by the decay (for drying) or growth (for wetting) functions. The saturation-dependence was calculated by the van Genuchten–Mualem (VGM) model. These functions were then implemented into a moisture transport model that was developed in previous studies. The proposed model was validated by experimental data and showed a good agreement for cement pastes that were dried or wetted in the hygroscopic range. Numerical simulation results were also compared with the simplified solutions to a fractional derivative model (FDM) of anomalous diffusion and the empirical Weibull function. We found that the solutions to the FDM cannot provide appropriate results. Weibull function performs as well as the proposed model, but the empirical function lacks physical meanings.

scholarly journals A Dual-Permeability Approach to Study Anomalous Moisture Transport Properties of Cement-Based Materials

2020 ◽  
Vol 135 (1) ◽  
pp. 59-78
Author(s):  
Zhidong Zhang ◽  
Ueli Angst
Keyword(s):  
Moisture Transport ◽  
Sorption Isotherms ◽  
Cementitious Materials ◽  
Transport Models ◽  
Pore Region ◽  
Permeability Model ◽  
Vapor Diffusion ◽  
Proposed Model ◽  
Small Pore ◽  
Cement Based Materials

Abstract Anomalous moisture transport in cement-based materials is often reported in the literature, but the conventional single-porosity moisture transport models generally fail to provide accurate simulation results. Previous studies suggested that the anomalous moisture transport could be caused by different moisture transport velocity in large and small pores. Based on this concept, the present study proposes a continuous dual-permeability model for cement-based material. The proposed model includes the transport contribution of both liquid water and water vapor, which are governed by liquid advection and vapor diffusion, respectively. We explicitly consider that moisture transport in the large pore region is faster than the small pore region. The volumetric fraction of each region is determined when fitting the measured sorption isotherms by using a bimodal equation. The validation with experimental data shows that the dual-permeability model can well simulate both the “normal” and the anomalous moisture transport. The applicability of the proposed model implies that the “dual-porosity property” could be one of reasons that cause anomalous moisture transport in cementitious materials. In addition, results show that vapor diffusion can be neglected for moisture transport in both porosities at high relative humidity (RH), while at low RH, vapor diffusion must be considered.

scholarly journals Water Absorption Properties of Cement Pastes: Experimental and Modelling Inspections

2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Ludovica Casnedi ◽  
Ombretta Cocco ◽  
Paola Meloni ◽  
Giorgio Pia
Keyword(s):  
Pore Size Distribution ◽  
Water Absorption ◽  
Pore Size ◽  
Size Distribution ◽  
Cement Pastes ◽  
Water Absorption Coefficient ◽  
Proposed Model ◽  
Porous Microstructure ◽  
Base Units ◽  
Good Agreement

An intermingled fractal units’ model is shown in order to simulate pore microstructures as pore fraction and pore size distribution. This model is aimed at predicting capillary water absorption coefficient and sorptivity values in cement pastes. The results obtained are in good agreement with the experimental ones. For validating this model, a comparison with other procedures has been shown. It is possible to establish that the newly proposed method matches better with the experimental results. That is probably due to the fact that pore size distribution has been considered as a whole. Moreover, even though the proposed model is based on fractal base units, it is able to simulate and predict different properties as well as nonfractal porous microstructure.

scholarly journals Influence of Chemical Osmosis on Solute Transport and Fluid Velocity in Clay Soils

2020 ◽  
Vol 18 (1) ◽  
pp. 232-238
Author(s):  
Zhihong Zhang ◽  
Gailei Tian ◽  
Lin Han
Keyword(s):  
Solute Transport ◽  
Transport Model ◽  
Fluid Velocity ◽  
Diffusion Mechanism ◽  
Clay Material ◽  
Chemical Osmosis ◽  
Advection Diffusion Equation ◽  
Test Study ◽  
Proposed Model ◽  
Membrane Effect

AbstractSolute transport through the clay liner is a significant process in many waste landfills or unmanaged landfills. At present, researchers mainly focus on the test study about semi-membrane property of clay material, however, the influence of chemical osmosis caused by membrane effect on solute transport and fluid velocity is insufficient. In this investigation, based on the classical advection-diffusion equation, a one-dimensional solute transport model for low-permeable clay material has been proposed, in which the coupled fluid velocity related with hydraulic gradient and concentration gradient is introduced, and the semi-membrane effect is embodied in the diffusion mechanism. The influence of chemical osmosis on fluid velocity and solute transport has been analyzed using COMSOL Multiphysics software. The simulated results show that chemical osmosis has a significant retarded action on fluid velocity and pollutant transport. The proposed model can effectively reveal the change in process of coupled fluid velocity under dual gradient and solute transport, which can provide a theoretical guidance for similar fluid movement in engineering.

scholarly journals Compact Modelling of Electrical, Optical and Thermal Properties of Multi-Colour Power LEDs Operating on a Common PCB

Energies ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1286
Author(s):  
Krzysztof Górecki ◽  
Przemysław Ptak
Keyword(s):  
Integrated Circuits ◽  
Optical Model ◽  
Printed Circuit Board ◽  
Circuit Board ◽  
Junction Temperature ◽  
Optical Parameters ◽  
Spice Simulation ◽  
Light Emitting ◽  
Proposed Model ◽  
Good Agreement

This paper concerns the problem of modelling electrical, thermal and optical properties of multi-colour power light-emitting diodes (LEDs) situated on a common PCB (Printed Circuit Board). A new form of electro-thermo-optical model of such power LEDs is proposed in the form of a subcircuit for SPICE (Simulation Program with Integrated Circuits Emphasis). With the use of this model, the currents and voltages of the considered devices, their junction temperature and selected radiometric parameters can be calculated, taking into account self-heating phenomena in each LED and mutual thermal couplings between each pair of the considered devices. The form of the formulated model is described, and a manner of parameter estimation is also proposed. The correctness and usefulness of the proposed model are verified experimentally for six power LEDs emitting light of different colours and mounted on an experimental PCB prepared by the producer of the investigated devices. Verification was performed for the investigated diodes operating alone and together. Good agreement between the results of measurements and computations was obtained. It was also proved that the main thermal and optical parameters of the investigated LEDs depend on a dominant wavelength of the emitted light.

Static and Dynamic Structure of Molecular Monomers and Dimers of the Rare-earth Fluorides

2001 ◽  
Vol 56 (5) ◽  
pp. 381-385
Author(s):  
Z. Akdeniz ◽  
M . Gaune-Escard ◽  
M. P. Tosi
Keyword(s):  
Rare Earth ◽  
Bond Length ◽  
Geometrical Structure ◽  
Vibrational Mode ◽  
Dynamic Structure ◽  
Molecular Shape ◽  
Proposed Model ◽  
Infrared Studies ◽  
Charged Clusters ◽  
Good Agreement

Abstract We determine a model of the ionic interactions in RF3 compounds, where R is a rare-earth element in the series from La to Lu, by an analysis of data on the bond length and the vibrational mode frequencies of the PrF3, GdF3 and HoF3 molecular monomers. All RF3 monomers are predicted to have a pyramidal shape, displaying a progressive flattening of the molecular shape in parallel with the lanthanide contraction of the bond length. The vibrational frequencies of all monomers are calculated, the results being in good agreement with the data from infrared studies of matrix-isolated molecules. We also evaluate the geometrical structure and the vibrational spectrum of the La2F6 and Ce2F6 dimers, as a further test of the proposed model. -PACS 36.40.Wa (Charged clusters)

Moisture Transport in Wood-Based Structural Panels under Transient Hygroscopic Conditions

2020 ◽  
Vol 70 (3) ◽  
pp. 283-292
Author(s):  
Daniel Way ◽  
Frederick A. Kamke ◽  
Arijit Sinha
Keyword(s):  
Moisture Transport ◽  
Transport Model ◽  
Oriented Strand Board ◽  
Primary Objective ◽  
Accelerated Weathering ◽  
Wood Composite ◽  
Transport Parameters ◽  
Moisture Profile ◽  
Cyclic Changes ◽  
Wood Based Composite

Abstract Development of moisture gradients within wood and wood-based composites can result in irreversible moisture-induced damage. Accelerated weathering (AW), generally employing harsh environmental conditions, is a common tool for assessing moisture durability of wood composite products. Use of milder AW conditions, such as cyclic changes in relative humidity (RH), may be of interest to the wood-based composites industry in assessing moisture durability under more realistic conditions. The primary objective of this study was to determine whether moisture profile development in oriented strand board and plywood during cyclic RH changes could be reasonably predicted with a simple moisture transport model, which may be practical for wood-based composite industry members seeking to develop new AW protocols. The diffusion model based on Fick's second law with empirically determined moisture transport parameters fits the experimental data reasonably well for the purpose of screening RH parameters.

scholarly journals Inverse modelling of CF<sub>4</sub> and NF<sub>3</sub> emissions in East Asia

2018 ◽  
Vol 18 (18) ◽  
pp. 13305-13320 ◽  
Author(s):  
Tim Arnold ◽  
Alistair J. Manning ◽  
Jooil Kim ◽  
Shanlan Li ◽  
Helen Webster ◽  
...  
Keyword(s):  
South Korea ◽  
East Asia ◽  
Transport Model ◽  
Atmospheric Transport ◽  
Atmospheric Gases ◽  
Atmospheric Measurements ◽  
Small Uncertainty ◽  
Measurement Location ◽  
Atmospheric Transport Model ◽  
Good Agreement

Abstract. Decadal trends in the atmospheric abundances of carbon tetrafluoride (CF4) and nitrogen trifluoride (NF3) have been well characterised and have provided a time series of global total emissions. Information on locations of emissions contributing to the global total, however, is currently poor. We use a unique set of measurements between 2008 and 2015 from the Gosan station, Jeju Island, South Korea (part of the Advanced Global Atmospheric Gases Experiment network), together with an atmospheric transport model, to make spatially disaggregated emission estimates of these gases in East Asia. Due to the poor availability of good prior information for this study, our emission estimates are largely influenced by the atmospheric measurements. Notably, we are able to highlight emission hotspots of NF3 and CF4 in South Korea due to the measurement location. We calculate emissions of CF4 to be quite constant between the years 2008 and 2015 for both China and South Korea, with 2015 emissions calculated at 4.3±2.7 and 0.36±0.11 Gg yr−1, respectively. Emission estimates of NF3 from South Korea could be made with relatively small uncertainty at 0.6±0.07 Gg yr−1 in 2015, which equates to ∼1.6 % of the country's CO2 emissions. We also apply our method to calculate emissions of CHF3 (HFC-23) between 2008 and 2012, for which our results find good agreement with other studies and which helps support our choice in methodology for CF4 and NF3.

scholarly journals Validation of nine years of MOPITT V5 NIR using MOZAIC/IAGOS measurements: biases and long-term stability

2014 ◽  
Vol 7 (11) ◽  
pp. 3783-3799 ◽  
Author(s):  
A. T. J. de Laat ◽  
I. Aben ◽  
M. Deeter ◽  
P. Nédélec ◽  
H. Eskes ◽  
...  
Keyword(s):  
Near Infrared ◽  
Transport Model ◽  
A Priori ◽  
Validation Data ◽  
Chemistry Transport Model ◽  
Large Variability ◽  
Long Term Stability ◽  
Spatio Temporal ◽  
Good Agreement

Abstract. Validation results from a comparison between Measurement Of Pollution In The Troposphere (MOPITT) V5 Near InfraRed (NIR) carbon monoxide (CO) total column measurements and Measurement of Ozone and Water Vapour on Airbus in-service Aircraft (MOZAIC)/In-Service Aircraft for a Global Observing System (IAGOS) aircraft measurements are presented. A good agreement is found between MOPITT and MOZAIC/IAGOS measurements, consistent with results from earlier studies using different validation data and despite large variability in MOPITT CO total columns along the spatial footprint of the MOZAIC/IAGOS measurements. Validation results improve when taking the large spatial footprint of the MOZAIC/IAGOS data into account. No statistically significant drift was detected in the validation results over the period 2002–2010 at global, continental and local (airport) scales. Furthermore, for those situations where MOZAIC/IAGOS measurements differed from the MOPITT a priori, the MOPITT measurements clearly outperformed the MOPITT a priori data, indicating that MOPITT NIR retrievals add value to the MOPITT a priori. Results from a high spatial resolution simulation of the chemistry-transport model MOCAGE (MOdèle de Chimie Atmosphérique à Grande Echelle) showed that the most likely explanation for the large MOPITT variability along the MOZAIC-IAGOS profile flight path is related to spatio-temporal CO variability, which should be kept in mind when using MOZAIC/IAGOS profile measurements for validating satellite nadir observations.

Moisture Transport Model for Enhancing FHWA HIPERPAV Predictions

2009 ◽  
Vol 2113 (1) ◽  
pp. 1-12 ◽  
Author(s):  
Qinwu Xu ◽  
J. Mauricio Ruiz ◽  
George K. Chang ◽  
Robert O. Rasmussen ◽  
Dan K. Rozycki
Keyword(s):  
Moisture Transport ◽  
Transport Model
Sign in / Sign up

Export Citation Format

Share Document