Giant Water Clusters: Where Are They From?

A new mechanism for the formation and destruction of giant water clusters (ten to hundreds of micrometers) is proposed. Our earlier hypothesis was that the clusters are associates of liquid-crystal spheres (LCS), each of which is formed around a seed particle, a microcrystal of sodium chloride. In this study, we show that the ingress of LCSs into water from the surrounding air is highly likely. We followed the evolution of giant clusters during the evaporation of water. When a certain threshold of the ionic strength of a solution is exceeded, the LCSs begin to “melt”, passing into free water, and the salt crystals dissolve, ensuring re-growth of larger crystals as a precipitate on the substrate. A schematic diagram of the dynamics of phase transitions in water containing LCSs during evaporation is proposed. The results illustrate the salt dust cycle in nature.