scholarly journals Synthesis of a Temperature-Sensitive Matrine-Imprinted Polymer and Its Potential Application for the Selective Extraction of Matrine from Radix Sophorae Tonkinensis

2015 ◽  
Vol 16 (2) ◽  
pp. 3441-3451 ◽  
Author(s):  
Minjie Jiang ◽  
Lisheng Wang ◽  
Xu Liu ◽  
Hua Yang ◽  
Fan Ren ◽  
...  
Keyword(s):  
Potential Application ◽  
Selective Extraction ◽  
Temperature Sensitive ◽  
Imprinted Polymer

scholarly journals A Molecularly Imprinted Polymer for Selective Extraction of Phenolic Acids from Human Urine

2021 ◽  
Vol 11 (4) ◽  
pp. 1577
Author(s):  
Marco Mora-Granados ◽  
David González-Gómez ◽  
Jin Su Jeong ◽  
Alejandrina Gallego-Picó
Keyword(s):  
Phenolic Acids ◽  
Molecularly Imprinted Polymer ◽  
Human Urine ◽  
Limit Of Detection ◽  
Ph Dependence ◽  
Selective Extraction ◽  
Screening Methods ◽  
Specific Method ◽  
Imprinted Polymer ◽  
Molecularly Imprinted

Studies for monitoring the bioavailability of dietary flavonoid compounds generate great interest. Among them, low-molecular-weight phenolic acids, secondary metabolites present in colonic catabolism and urinary excretion, have been proposed as biomarkers of polyphenol intake. Using 4-hydroxyphenylacetic acid as a template, a molecularly imprinted polymer (MIP) was synthesized for selective extraction of these hydroxylated metabolites from human urine samples and posterior analysis in an HPLC-DAD-MS system. Polymers were characterized by Scanning electron microscopy (SEM), Attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), Brunauer-Emmett-Teller (BET) method, and binding experiments. MIP presents specific recognition ability for template and analogues molecules. This capacity of recognition and the pH dependence of the binding strength was also studied. The method was validated over a concentration range of 0.25–40 mg/L, r2 > 0.995. In the optimized conditions, the recovery value was 94% with RSD 1.2%. The Limit of Detection (LOD) and Limit of Quantification (LOQ) were 1.22 and 3.69 mg/L, respectively. In our knowledge, it is the first time that this methodology is applied to analyze urinary catabolites of the polyphenol compound and to provide a specific method and simple analysis alternative. The selective extraction of these metabolites improves the application and results obtained by other less sensitive analysis methods than the validation method. It also facilitates the development of new screening methods.

Design of Temperature Sensitive Imprinted Polymer Hydrogels Based on Multiple-Point Hydrogen Bonding

2004 ◽  
Vol 4 (7) ◽  
pp. 680-684 ◽  
Author(s):  
Xue-Yong Liu ◽  
Ying Guan ◽  
Xiao-Bin Ding ◽  
Yu-Xing Peng ◽  
Xin-Ping Long ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Multiple Point ◽  
Temperature Sensitive ◽  
Imprinted Polymer ◽  
Polymer Hydrogels

Preparation of novel arsenic-imprinted polymer for the selective extraction and enhanced adsorption of toxic As3+ ions from the aqueous environment

2019 ◽  
Vol 77 (10) ◽  
pp. 5261-5279 ◽  
Author(s):  
Muhammad Saqaf Jagirani ◽  
Aamna Balouch ◽  
Sarfaraz Ahmed Mahesar ◽  
Ameet Kumar ◽  
Abdullah ◽  
...  
Keyword(s):  
Selective Extraction ◽  
Aqueous Environment ◽  
Imprinted Polymer ◽  
Enhanced Adsorption

Selective extraction of progesterone hormones from environmental and biological samples using a polypyrrole molecularly imprinted polymer and determination by gas chromatography

2016 ◽  
Vol 8 (8) ◽  
pp. 1813-1827 ◽  
Author(s):  
A. Nezhadali ◽  
Z. Es’haghi ◽  
A. Khatibi
Keyword(s):  
Gas Chromatography ◽  
Molecularly Imprinted Polymer ◽  
Biological Samples ◽  
Selective Extraction ◽  
Chemical Oxidation ◽  
Imprinted Polymer ◽  
Molecularly Imprinted ◽  
Batch Extraction ◽  
Environmental And Biological Samples

A Molecularly Imprinted Polymer (MIP) was chemically prepared for the selective batch extraction of progesterone (PGN) hormones by chemical oxidation of pyrrole using FeCl3.

Selective Transport of Water-Soluble Proteins from Aqueous to Ionic Liquid Phase via a Temperature-Sensitive Phase Change of These Mixtures

2012 ◽  
Vol 65 (11) ◽  
pp. 1548 ◽  
Author(s):  
Yuki Kohno ◽  
Nobuhumi Nakamura ◽  
Hiroyuki Ohno
Keyword(s):  
Phase Change ◽  
Aqueous Phase ◽  
Selective Dissolution ◽  
Selective Extraction ◽  
Soluble Proteins ◽  
Water Soluble ◽  
Temperature Sensitive ◽  
Salting Out ◽  
Key Factor ◽  
The Difference

Mixtures of some ionic liquids (ILs) and water show reversible phase change between a homogeneous mixture and phase-separated state by a small change in temperature. Some water-soluble proteins have been migrated from the aqueous to the IL phase. When tetrabutylphosphonium 2,4,6-trimethylbenzenesulfonate was used as an IL, cytochrome c (Cyt.c) was found to be extracted from the water phase to the IL phase. Conversely, both horseradish peroxidase (HRP) and azurin remained in the aqueous phase. This selective extraction was comprehended to be due to the difference in solubility of these proteins in both phases. The separated aqueous phase contained a small amount of IL, which induced the salting-out of Cyt.c. On the other hand, condensed IL phase promoted the salting-in of Cyt.c. As a result, Cyt.c was preferably dissolved in the hydrated IL phase rather than aqueous phase. In the case of HRP, there was only a salting-out profile upon increasing the concentration of IL, which induced selective dissolution of HRP in the aqueous phase. These results clearly suggest that the profile of salting-out and salting-in for proteins is the key factor to facilitate the selective extraction of proteins from aqueous to the IL phase.

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