scholarly journals Conductive Electrospun Polyaniline/Polyvinylpyrrolidone Nanofibers: Electrical and Morphological Characterization of New Yarns for Electronic Textiles

Fibers ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 24
Author(s):  
Patrícia Perdigão ◽  
Bruno Miguel Morais Faustino ◽  
Jaime Faria ◽  
João Paulo Canejo ◽  
João Paulo Borges ◽  
...  
Keyword(s):  
In Situ Polymerization ◽  
Morphological Characterization ◽  
Electronic Textiles ◽  
Aniline Monomer ◽  
Monomer Ratio ◽  
Electrical Conductivities ◽  
Electrospun Membranes ◽  
Conventional Coating

Advanced functionalities textiles embedding electronic fibers, yarns and fabrics are a demand for innovative smart cloths. Conductive electrospun membranes and yarns based on polyaniline/polyvinylpyrrolidone (PANI/PVP) were investigated using the chemical modification of PANI instead of using conventional coating processes as in-situ polymerization. PANI was synthesized from the aniline monomer and the influence of the oxidant-to-monomer ratio on electrical conductivity was studied. The optimized conductivity of pellets made with pressed PANI powders was 21 S·cm−1. Yarns were then prepared from the t-Boc-PANI/PVP electrospun membranes followed by PANI protonation to enhance their electrical properties. Using this methodology, electrospun membranes and yarns were produced with electrical conductivities of 1.7 × 10−2 and 4.1 × 10−4 S·cm−1.

Thermal and Morphological Characterization of Nanocomposites Prepared by in-Situ Polymerization of High-Density Polyethylene on Carbon Nanotubes

2007 ◽  
Vol 40 (17) ◽  
pp. 6268-6276 ◽  
Author(s):  
M. Trujillo ◽  
M. L. Arnal ◽  
A. J. Müller ◽  
E. Laredo ◽  
St. Bredeau ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
High Density Polyethylene ◽  
In Situ Polymerization ◽  
Morphological Characterization ◽  
High Density

scholarly journals Synthesis and electrical properties of conductive polyaniline/ SWCNT nanocomposites

2019 ◽  
Vol 15 (34) ◽  
pp. 106-113
Author(s):  
Estabraq T. Abdulla
Keyword(s):  
Electrical Properties ◽  
In Situ Polymerization ◽  
Pure Pani ◽  
Electron Interaction ◽  
Aniline Monomer ◽  
Force Microscopy ◽  
Atomic Force ◽  
Afm Analysis ◽  
Electrical Conductivities ◽  
Walled Carbon Nanotubes

The synthesis of conducting polyaniline (PANI) nanocomposites containing various concentrations of functionalized single-walled carbon nanotubes (f-SWCNT) were synthesized by in situ polymerization of aniline monomer. The morphological and electrical properties of pure PANI and PANI/SWCNT nanocomposites were examined by using Fourier transform- infrared spectroscopy (FTIR), and Atomic Force Microscopy (AFM) respectively. The FTIR shows the aniline monomers were polymerized on the surface of SWCNTs, depending on the -* electron interaction between aniline monomers and SWCNTs. AFM analysis showed increasing in the roughness with increasing SWCNT content. The AC, DC electrical conductivities of pure PANI and PANI/SWCNT nanocomposite have been measured in frequency range (50Hz - 600KHz) and in the temperature range from (30 to 160K). The results show the electrical conductivity of the nanocomposite is higher than pure PANI.

Synthesis and Characterization of the PANI/ITO Conducting Nanocomposites

2010 ◽  
Vol 663-665 ◽  
pp. 542-545 ◽  
Author(s):  
Bing Jie Zhu ◽  
Xin Wei Wang ◽  
Mei Fang Zhu ◽  
Qing Hong Zhang ◽  
Yao Gang Li ◽  
...  
Keyword(s):  
Doping Concentration ◽  
In Situ Polymerization ◽  
Synthesis And Characterization ◽  
Conductivity Measurements ◽  
X Ray Diffraction ◽  
X Ray ◽  
Maximum Conductivity ◽  
Scanning Electron

The PANI/ITO conducting nanocomposites have been synthesized by in-situ polymerization. The obtained nanocomposites were characterized by X-ray diffraction pattern, scanning electron microscopy and Fourier transform infrared. Electrical conductivity measurements on the samples pressed into pellets showed that the maximum conductivity attained 2.0 ± 0.05 S/cm for PANI/ITO nanocomposites, at ITO doping concentration of 10 wt%. The results of the present work may provide a simple, rapid and efficient approach for preparing PANI/ITO nanocomposites.

Study on the Synthesis and Characterization of PANi/Nano-CeO2 Composites

2007 ◽  
Vol 124-126 ◽  
pp. 287-290 ◽  
Author(s):  
Fei Liu ◽  
Yong Jun He ◽  
Jeung Soo Huh
Keyword(s):  
In Situ Polymerization ◽  
Solid Phase ◽  
Polymerization Reaction ◽  
Solid Phase Reaction ◽  
Phase Reaction ◽  
Vis Spectroscopy ◽  
Ft Ir ◽  
Average Size

The nano-CeO2 was synthesized by two-step solid-phase reaction. The image of TEM showed that nano-CeO2 with an average size of about 70 nm. The series of polyaniline/nano-CeO2 composites with different PANi: CeO2 ratios were prepared by in-situ polymerization in the presence of hydrochloric acid (HCl) as dopant by adding nano-CeO2 into the polymerization reaction mixture of aniline. The composites obtained were characterized by FT-IR and UV-vis spectroscopy analysis. The FT-IR spectra of nanocomposites indicate different blue-shifts, attributed to C–N stretching mode for benzenoid unit. The UV-vis spectra of nanocomposites display einstein-shifts compared with PANi at 620nm. The conductivity properties of the composites are also changed compare to the pure PANi. These results suggest that the interactions between the polymer matrix and nanoparticles take place in polyaniline/nano- CeO2 composites.

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