scholarly journals Porcelain Enamel Coatings

Encyclopedia ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 388-400
Author(s):  
Francesca Russo ◽  
Stefano Rossi ◽  
Attilio Monzio Compagnoni

Porcelain enamel is an inorganic-type coating, which is applied to metals or glass for both decorative and functional purposes. This coating is a silica-based solidified glass mass obtained by high-temperature firing (temperature can range between 450 and 1200 °C depending on the substrate). Porcelain enamel coatings differ from ceramic coatings mainly by their glass structure and dilatation coefficient, and from organic paints mainly by the inorganic nature of the matrix and the chemical bond that exists between the coating and the substrate.

Author(s):  
K. Kobylanska-Szkaradek ◽  
L. Swadzba

Abstract The paper presents the influence of laser-beam remelting of Al203-Ni ceramic layers spread on creep-resisting alloy by means of plasma spray upon the quality of ceramic coatings, which form thermal barrier and high temperature corrosion shield of these alloys. The examination showed that 0.103.109 W/m2 power density laser-beam scanning ensures good quality of coatings at beam moving rate 1 to 2 m/min. At smaller scanning rate, laser remelted ceramic layer spalls and chips. Better quality of the ceramic coatings can be obtained by diffusive chromoaluminizing applied prior to laser remelting. Laser-beam remelting conditions of such layers, elaborated in the course of examination, ensure pores fading, decrease of remelted layer thickness and increase of base adhesion without cracks, chips and spalls. Additionally remelted zone features either strong break up of structure or the structure is amorphic with unchanged chemical composition as to the matrix chemical composition. Obtained results are the base for the elaboration of thermal barrier technology and the technology of anticorrosion shield for creep - resisting alloys applied in high temperature power engineering.


2020 ◽  
Vol 22 (4) ◽  
pp. 1031-1046
Author(s):  
X. Canute ◽  
M. C. Majumder

AbstractThe need for development of high temperature wear resistant composite materials with superior mechanical properties and tribological properties is increasing significantly. The high temperature wear properties of aluminium boron carbide composites was evaluated in this investigation. The effect of load, sliding velocity, temperature and reinforcement percentage on wear rate was determined by the pin heating method using pin heating arrangement. The size and structure of base alloy particles change considerably with an increase of boron carbide particles. The wettability and interface bonding between the matrix and reinforcement enhanced by the addition of potassium flurotitanate. ANOVA technique was used to study the effect of input parameters on wear rate. The investigation reveals that the load had higher significance than sliding velocity, temperature and weight fraction. The pin surface was studied with a high-resolution scanning electron microscope. Regression analysis revealed an extensive association between control parameters and response. The developed composites can be used in the production of automobile parts requiring high wear, frictional and thermal resistance.


2006 ◽  
Vol 510-511 ◽  
pp. 358-361
Author(s):  
Won Yong Kim ◽  
Han Sol Kim ◽  
In Dong Yeo ◽  
Mok Soon Kim

We report on advanced Ni3Al based high temperature structural alloys with refractory alloying elements such as Zr and Mo to be apllied in the fields of die-casting and high temperature press forming as die materials. The duplex microstructure consisting of L12 structured Ni3Al phase and Ni5Zr intermetallic dispersoids was observed to display the microstructural feature for the present alloys investigated. Depending on alloying elements, the volume fraction of 2nd phase was measured to be different, indicating a difference in solid solubility of alloying elements in the matrix γ’ phase. Lattice parameter of matrix phase increased with increasing content of alloying elements. In the higher temperature region more than 973K, the present alloys appeared to show their higher strength compared to those obtained in conventional superalloys. On the basis of experimental results obtained, it is suggested that refractory alloying elements have an effective role to improve the high temperature strength in terms of enhanced thermal stability and solid solution hardening.


2012 ◽  
Vol 512-515 ◽  
pp. 671-675 ◽  
Author(s):  
Ai Guo Zhou ◽  
Liang Li ◽  
Tai Chao Su ◽  
Shang Sheng Li

Ti3SiC2, a ternary carbide, was proposed at this paper to use as the binder of polycrystalline diamonds to overcome the weaknesses of traditional metal binders and ceramic binders. Ti3SiC2was first reported to be in-situ synthesized under high pressure (4GPa) and at high temperature (1400°C) (HPHT) from the mixtures of Ti, Si and graphite powders or the mixture of Ti, SiC and graphite powders. Ti3SiC2-damond composites were also made at HPHT from the previous mixtures and diamond particles. TiCx, Ti5Si3Cxand TiSi2were main impurities and/or intermediate products of Ti3SiC2samples synthesized at HPHT. Ti3SiC2content increased as synthesized time increased from 10 min to 60 min. For as-synthesized composites, diamond particles were evenly distributed in matrix. The diamond particles are bonded well with the matrix by three types of interface.


2007 ◽  
Vol 336-338 ◽  
pp. 2481-2483 ◽  
Author(s):  
Guo Dong Hao ◽  
Zhao Hua Jiang ◽  
Zhong Ping Yao ◽  
Heng Ze Xian ◽  
Yan Li Jiang

Compound ceramic coatings with the main crystalline of Al2TiO5 (as-coated samples) were prepared on Ti-6Al-4V alloy by pulsed bi-polar micro-plasma oxidation (MPO) in NaAlO2 solution. The coated samples were calcined in Ar and air at 1000oC, respectively. The phase composition, morphology and element content of the coatings were investigated by XRD, SEM and XRF. The samples treated in Ar and the as-coated ones were calcined in air at 1000oC to study the oxidation resistance of the samples. The results showed that Al2TiO5 decomposed and transformed into corundum and rutile TiO2 during the high temperature calcination. Al2TiO5 decomposed very quickly in air and the proportion of Al2O3 to TiO2 was 44:55 after a complete decomposition. On the contrary, Al2TiO5 decomposed very slowly in argon with the final proportion of Al2O3 to TiO2 of 81:18 on the coating surface. The morphology of the ceramic coatings after the calcination was also different. The coatings calcined in argon were fined: the grains and pores were smaller than those of the coatings calcined in air. The weight gains of both coatings changed in the form of parabola law, and the weight gains of the coated samples treated in argon were comparatively lower than that of the as-coated samples. During the high temperature calcination, the samples treated in argon cannot distort easily, compared with the as-coated ones.


MRS Bulletin ◽  
1997 ◽  
Vol 22 (3) ◽  
pp. 25-29 ◽  
Author(s):  
W.J. Choyke ◽  
G. Pensl

While silicon carbide has been an industrial product for over a century, it is only now emerging as the semiconductor of choice for high-power, high-temperature, and high-radiation environments. From electrical switching and sensors for oil drilling technology to all-electric airplanes, SiC is finding a place which is difficult to fill with presently available Si or GaAs technology. In 1824 Jöns Jakob Berzelius published a paper which suggested there might be a chemical bond between the elements carbon and silicon. It is a quirk of history that he was born in 1779 in Linköping, Sweden where he received his early education, and now, 172 years later, Linkoping University is the center of a national program in Sweden to study the properties of SiC as a semiconductor.


Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 364
Author(s):  
Hao Wang ◽  
Jun Xiao ◽  
Hui Wang ◽  
Yong Chen ◽  
Xing Yin ◽  
...  

Liquid metal fast reactors were considered to be the most promising solution to meet the enormous energy demand in the future. However, corrosion phenomenon caused by the liquid metal, especially in high-temperature lead-bismuth coolant, has greatly hindered the commercialization of the advanced Generation-IV nuclear system. This review discussed current research on the corrosion resistance of structural materials (such as EP823, T91, ODS, and authentic steels) in high-temperature liquid metal served as reactor coolants. The current corrosion resistance evaluation has proved that even for the excellent performance of EP823, the structural material selected in pressurized water reactor is not the ideal material for operation in the high-temperature lead-bismuth eutectic (LBE). Furthermore, the latest coating technologies that are expected to be applied to cladding materials for coolant system were extensively discussed, including Al-containing coatings, ceramic coatings, oxide coatings, amorphous coatings and high-entropy alloy coatings. The detailed comparison summarized the corrosion morphology and corrosion products of various coatings in LBE. This review not only provided a systematic understanding of the corrosion phenomena, but also demonstrated that coating technology is an effective method to solve the corrosion issues of the advanced next-generation reactors.


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