scholarly journals Determining the Unit Values of the Allocation of Greenhouse Gas Emissions for the Production of Biofuels in the Life Cycle

Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8394
Author(s):  
Mariusz Niekurzak

Thanks to the allocation methods, i.e., the division of the total GHG emissions between each of the products generated in the production of biofuels, it is possible to reduce the emissions of these gases by up to 35% in relation to the production and combustion of fuels derived from crude oil. As part of this study, the biodiesel production process was analyzed in terms of greenhouse gas (GHG) emissions. On the basis of the obtained results, the key factors influencing the emissions level of the biodiesel production process were identified. In order to assess the sensitivity of the results of the adopted allocation method, this study included calculations of GHG emissions with an allocation method based on mass, energy, and financial shares. The article reviews recent advances that have the potential to enable a sustainable energy transition, a green economy, and carbon neutrality in the biofuels sector. The paper shows that the technology used for the production of biodiesel is of great importance for sustainable development. The possibility of using renewable raw materials for the production of fuels leads to a reduction in the consumption of fossil fuels and lower emission of pollutants. It showed that during the combustion of biodiesel, the percentages of released gas components, with the exception of nitrogen oxides, which increased by 13%, were significantly lower: CO2—78%, CO—43%, SO2—100%, PM10—32%, and volatile hydrocarbons—63%. Moreover, it was found that biodiesel undergoes five times faster biodegradation in the environment than diesel oil.

2013 ◽  
Vol 152 (2) ◽  
pp. 263-273 ◽  
Author(s):  
C. E. VLACHOS ◽  
N. A. MARIOLIS ◽  
G. N. SKARACIS

SUMMARYSunflower (Helianthus annuus L.) and rapeseed (Brassica napus L.) are considered as the most suitable crops for biodiesel production in the Mediterranean basin. Soybean (Glycine max L.) could also be used, under certain conditions. In Greece, the farming practice adopted in each region varies significantly, leading to significant differences in the levels of emitted greenhouse gases (GHG). Greenhouse gas emissions were estimated during the cultivation phase as grams of carbon dioxide equivalents (g CO2e) per megajoule (MJ), followed by emission savings (%) estimation when fossil fuels are replaced by biodiesel. Crop and region comparisons provided important information towards promoting sustainability. Overall, sunflower demonstrated the lowest average emissions, 53·8 g CO2e/MJ, followed by rapeseed and soybean. Furthermore, rapeseed achieved the lowest emission saving level required by European legislation in most cases studied, with an average value of 37%. Irrigation and nitrogen fertilization were the operations mostly contributing to the total quantity of GHG emissions. More specifically, the highest GHG emissions were found for soybean irrigation (34%) and rapeseed nitrogen fertilization (68%).


Author(s):  
K. Malins ◽  
V. Kampars ◽  
R. Kampare ◽  
T. Rusakova

The transesterification of vegetable oil using various kinds of alcohols is a simple and efficient renewable fuel synthesis technique. Products obtained by modifying natural triglycerides in transesterification reaction substitute fossil fuels and mineral oils. Currently the most significant is the biodiesel, a mixture of fatty acid methyl esters, which is obtained in a reaction with methanol, which in turn is obtained from fossil raw materials. In biodiesel production it would be more appropriate to use alcohols which can be obtained from renewable local raw materials. Ethanol rouses interest as a possible reagent, however, its production locally is based on the use of grain and therefore competes with food production so it would implicitly cause increase in food prices. Another raw material option is alcohols that can be obtained from furfurole. Furfurole is obtained in dehydration process from pentose sugars which can be extracted from crop straw, husk and other residues of agricultural production. From furfurole the tetrahydrofurfuryl alcohol (THFA), a raw material for biodiesel, can be produced. By transesterifying rapeseed oil with THFA it would be possible to obtain completely renewable biodiesel with properties very close to diesel [2-4]. With the purpose of developing the synthesis of such fuel, in this work a three-stage synthesis of rapeseed oil tetrahydrofurfurylesters (ROTHFE) in sulphuric acid presence has been performed, achieving product with purity over 98%. The most important qualitative factors of ROTHFE have been determined - cold filter plugging point, cetane number, water content, Iodine value, phosphorus content, density, viscosity and oxidative stability.


Significance LNG is cleaner than most fossil fuels but still incompatible with net zero emissions. India, China and other Asian economies see LNG imports as a ready and economically viable means of displacing coal and oil use. Natural gas and then LNG demand will eventually peak as the energy transition accelerates over the next 20 years. Impacts LNG market growth will embed fossil fuel use and infrastructure in developing economies’ energy mixes. Recent market volatility and record spot LNG prices may reverse the trend of greater reliance on spot transactions than long-term contracts. Although the greenhouse gas (GHG) benefits of LNG use in transport are far from clear, it will gain market share in the next few years. LNG project developers will seek to cut GHG emissions from their projects to prolong LNG's attractiveness in the energy transition.


2012 ◽  
Vol 1 (2) ◽  
pp. 57-60 ◽  
Author(s):  
Widayat Widayat ◽  
S Suherman

One promise source of alternative energy is biodiesel from rubber seed oil, because the raw materials available in plentiful quantities and can be renewed. In addition, the rubber seed is still lack of utilization, and Indonesia is one of the largest rubbers producing country in the world. The objective of this research is to studied on biodiesel production by esterification process. Parameters used in this study are the ratio of catalyst and temperature and its influence on the characteristics of the resulting biodiesel product. Characterization of rubber seed include acid content number analysis, saponification numbers, density, viscosity, iodine number, type of free fatty acids and triglyceride oils. The results of analysis showed that rubber seed oil content obtained is 50.5%. The results of the GCMS analysis showed that a free fatty acid level in rubber seed is very high. Conversion into bio-diesel oil is obtained by at most 59.91% and lowest 48.24%.


2009 ◽  
Vol 20 (4) ◽  
pp. 533-551 ◽  
Author(s):  
R Saidur ◽  
MA Sattar ◽  
H.H. Masjuki ◽  
M.Y. Jamaluddin

This paper presents an analysis of the greenhouse gas (GHG) emissions from refrigeration equipment. The refrigeration equipments use refrigerants such as chlorofluorocarbons (CFCs) and hydrofluorocarbons HFCs, which are believed to contribute the ozone depletion and global warming. Refrigeration equipment thus contributes indirectly through emission due to electricity consumption and directly due to the emission of refrigerants. Greenhouse gas emissions resulting from the burning of fossil fuels are quantified and presented in this paper. The calculation was carried out based on emissions per unit electricity generated and the type of fuel used. The direct emission of refrigerant was calculated based on emission factor and according to the procedure of Environmental Protection Agency (EPA), USA. A study was conducted to evaluate the refrigerant losses to the atmosphere and the CO2 emission from fossil fuels to generate power to run the refrigeration and air-conditioning systems. In this paper, total appliance annual energy consumption by refrigerator-freezer and air conditioner as well as emission has been estimated for a period of 19 years (1997–2015) using the survey data. Energy savings and emission reductions achievable by raising thermostat set point temperature have been calculated for a period of 10 (i.e. 2005–2015) years.


2020 ◽  
Vol 108 (5-6) ◽  
pp. 502
Author(s):  
Jean-Pierre Birat

After overusing the expression Sustainable Development, some action plan was needed to switch from rhetorical to transformational change. One of the answers was to propose the word Transition as a roadmap leading to the necessary level of change. A Transition is a passage from one stable regime to another, with a step that is neither instantaneous nor dangerous, like a Revolution, but is fast enough, anyway. The first Transition in the 2010s was the Energy Transition, i.e. a move towards less fossil fuels and more renewables. It started everywhere more or less at the same time, but Germany and its Energiewende was among the first contenders. The implicit objective was as much to control excessive anthropogenic GHG emissions as it was to possibly start a new period of growth based on green technologies. Very soon, however, the Fukushima disaster convinced Mrs. Merkel to change tack and veer towards “zero nuclear power”, thus aligning with the program of the Green movements. At that point, the Energiewende had become a complex, multi-objectives program for change, not a simple Transition as described at the onset of the paper. The rest of the world turned to Globish and spoke of the Energy Transition (EnT). Each country added a layer of complexity to its own version of the EnT and told a series of narratives, quite different from each other. This is analyzed in the present article on the basis of the documents prepared by the “energy-community”, which assembles hard scientists and economists, a group that the soft scientists of SSH call STEM. EnT, in its most recent and mature version, hardly speaks of energy any more but of GHG emissions. Therefore, EnT drifted towards the expression Ecological Transition (EcT). Both expressions are almost synonymous today. From then on, myriads similar expressions sprang up: Environmental Transition, Demographic, Epidemiological and Environmental Risk Transition, Societal Transitions, Global Transitions, Economic Transition, Sustainability Transition, Socio-Ecological Transitions, Technology Transitions, Nutrition Transition, Agro-Ecological Transition, Digital Transition, Sanitary Transition as well as various practices like Energy Democracy or Theory of Transition. Focusing only on EnT and EcT, a first step consists in comparing energy technologies from the standpoint of their impact on public health: thus, coal is 2 or 3 orders of magnitude worse than renewable energy, not to speak of nuclear. A second step looks at the materials requirement of Renewables, what has been called the materials paradox. They are more materials-intensive and also call on much larger TMRs (Total Materials Requirement). On the other hand, the matter of critical materials has been blown out of proportion and is probably less out of control than initially depicted. A third step is accomplished by Historians, who show that History is full of energy transitions, which did not always go in one direction and did not always match the storytelling of progress that the present EnT is heavily relying on. Moreover, they flatly reject the long-term storytelling of History depicted as a continuous string of energy transitions, from biomass, to coal, oil, gas, nuclear and nowadays renewables. Just as interesting is the opinion of the Energy-SSH community. They complain that the organizations that control research funds and decision makers listen mainly to the STEM-energy community rather than to them. And they go on to explain, sometimes demonstrate, that this restricts the perspective, over-focuses on certain technologies and confines SSH to an ancillary role in support of projects, the strategy of which is decided without their input: the keyword is asymmetry of information, which therefore leads to distortion of decision-making. They also stress the need for a plurality of views and interpretations, a possible solution to the societal deadlocks often encountered in Europe. As important and strategic as energy issues are in our present world, the hubris of both STEM and SSH communities may be excessive. Some level of success in making them work together may be a way to resolve this situation!


Author(s):  
Marian PROOROCU ◽  
Sorin DEACONU ◽  
Mihaela SMARANDACHE

As a Party to the United Nations Framework Convention on Climate Change (UNFCCC), and its Kyoto Protocol, Romania is required to elaborate, regularly update and submit the national GHG Inventory. In compliance with the reporting requirements, Romania submitted in 2010 its ninth version of the National Inventory Report (NIR) covering the national inventories of GHG emissions/removals for the period 1989-2008. The inventories cover all sectors: Energy, Industrial Processes, Solvent and other product use, Agriculture, LULUCF and Waste. The direct GHGs included in the national inventory are: Carbon dioxide (CO2); Methane (CH4); Nitrous oxide (N2O); Hydrofluorocarbons (HFCs); Perfluorocarbons (PFCs); Sulphur hexafluoride (SF6). The emissions trend over the 1989-2008 period reflects the changes characterized by a process of transition to a market economy. With the entire economy in transition, some energy intensive industries reduced their activities and this is reflected in the GHG emissions reduction. Energy represents the most important sector in Romania, accounting for about 69% of the total national GHG emissions in 2008. The most significant anthropogenic greenhouse gas is the carbon dioxide. The decrease of CO2 emissions is caused by the decline of the amount of fossil fuels burnt in the energy sector, as a consequence of activity decline. According to the figures, there is a great probability for Romania to meet the Kyoto Protocol commitments on the limitation of the GHG emissions in the 2008-2012 commitment period.


2020 ◽  
Vol 15 (3) ◽  
pp. 67-82
Author(s):  
David A. Ness ◽  
Ke Xing

ABSTRACT In accordance with international protocols and directions, the APEC Energy Working Group has concentrated on constraining operational energy use and greenhouse gas (GHG) emissions in cities across the Asia Pacific, especially from the widespread consumption of fossil fuels. In addition to economy level policies and recognising the different characteristics within the region, APEC has sought to take action at the town/city level via the Low-Carbon Model Town (LCMT) project, including the development of self-assessment tools and indicator systems. However, the “low carbon” landscape is changing. There is increasing recognition of embodied carbon, accompanied by the emergence of methods for its measurement, while the C40 Cities Climate Leadership Group has recently highlighted the significance of consumption-based carbon. Similarly, the Greenhouse Gas Protocol for Cities (GPC) is likely to extend its ambit from Scope 1 GHG emissions, derived from energy use within a city boundaries, and Scope 2 emissions from grid-supplied electricity, heating and / or cooling, to Scope 3 emissions derived from materials and goods produced outside the boundaries of a city but associated with construction within that city. After describing these emerging approaches and the current landscape, the paper examines the significance and implications of these changes for APEC approaches, especially in relation to the LCMT project, its indicators and the varying characteristics of towns and cities within the Asia-Pacific region. Special attention is given to the built environment, which is known to be a major contributor to operational and embodied emissions. Consistent with the theme of the Asia-Pacific Energy Sustainable Development Forum covering “sustainable development of energy and the city,” a case is put forward for the current APEC approach to be extended to encompass both embodied and consumption-based emissions.


Author(s):  
Daniela Y. Sugai ◽  
José V. C. Vargas ◽  
Wellington Balmant ◽  
Priscila P. Dario ◽  
Leonardo C. Martinez ◽  
...  

Abstract Waste cooking oil and microalgae oil could become alternative raw materials for biodiesel production in the global quest for energetic sustainability. However, the technical and economic viability of the biodiesel production process from these alternative sources has not been fully investigated yet, within the knowledge of the authors. Therefore, the main objective of this study is to carry out an exergetic and economical analysis of the biodiesel production process from blends of waste cooking oil and microalgae oil. Initially, the mass, energy and exergy balances of the process of the biodiesel production was conducted. Then, an optimization procedure was executed with the selected objective functions. The results showed that it is possible to optimize the process as a function of the ratio of destroyed exergy system by the amount of ester produced, generating a profit of $ 29.50 per second, for an ratio of oil/ethanol of 3.7/1. In conclusion, the proposed model can also be used in the future for performing the exergoeconomic optimization of biodiesel production processes from blends of waste cooking oil and microalgae oil, aiming at achieving process sustainability.


2007 ◽  
Vol 01 (03) ◽  
pp. 05-10
Author(s):  
_ Talent & Technology

Feature - In late June, 2007 SPE President Abdul-Jaleel Al-Khalifa hosted an executive industry wide summit with 75 global leaders to advance cross-sector collaboration on two critical issues facing the oil and gas industry. Talent scarcity has been a pressing and recurring item on company agendas for several years. On the technology front, the heightened focus on climate change and greenhouse-gas (GHG) emissions from fossil fuels is expected to influence many areas including media, legislation, and policymaking. The oil and gas industry has been actively involved in various technology projects to promote carbon sequestration. The summit provided a venue to frame and boost an industry position on this critical and widely publicized subject.


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